Sensitivity Correlations

G. H. Bu-Abbud, N. M. Bashara, and J. A. Woollam. Thin Solid Films. 138,27, 1986. Description of Marquardt algorithm and parameter sensitivity correlation in ellipsometry. 

The data from H NMR studies of 63, which included double quantum filtered phase sensitive correlated spectroscopy (DQF-COSY) and rotating frame nuclear Overhauser effect spectroscopy (ROESY) experiments (Figure 12), are collected in Table 17. 

Nitro compounds may add to carbon-centered radicals and thus also with the majority of the DNA radicals (Chap. 6.3 only the very strongly reducing radicals such as eaq and C02 reduce the nitro sensitizers to (unstable) hydroxyl-amines McClelland et al. 1984). Originally, the nitro compounds and 02 have just been taken as oxidants irrespective of their mode of action, especially as the efficiency of the sensitizers correlates with their reduction potential (Adams and Cooke 1969 Tallentire et al. 1972 Simic and Powers 1974 Adams et al. 1976a, 1981). This concept is expressed in relationship (88), where C is the sensitizer concentration required to achieve a constant sensitizing response (e.g. an enhancement ratio of 1.6) and E7 the one-electron reduction potential of the sensitizer at pH 7. 

V. W. Manner, B. C. Tappan, B. L. Scott, D. N. Preston, G. W. Brown, Crystal Structure, Packing Analysis, and Structural-Sensitivity Correlations of Erythritol Tetranitrate, Cryst. Growth Des. 2014, 14, 6154-6160. 

In this chapter, we shall present an overview of some of these sensitivity correlations. We shall try, as much as possible, to relate them to a conceptual framework. 

Three major criteria are used for determining the location of the temperature control point (301, 332, 400) sensitivity, correlation with product(s), and dynamic response. Sensitivity is the most important dsmamic response is least important. 

Z = 20 is obtained for both samples A and B giving M / M = 1.05 which is within the range expected for a nearly monodisperse sample as those falling between Z = ZO and 120 extracted from the G t) and G uj) curves over the terminal region (Chapter 10). The Z parameter mainly correlates with the line shape over the portions of Jp t) with compliance > 5 X 10 cm /dyne but not with their time scales, with which the K value is sensitively correlated. Possible small uncertainties in Z virtually have no effect on the obtained K value. 

Among the three variables Aq, (3, and s, Aq is basically dictated by the glassy modulus, the reciprocal of the glassy compliance Jq, and (3 is determined by the Jp t) line shape over the small-compliance region, < 10 cm /dyne. The determination of s (Eq. (14.5)), which sensitively correlates with the if-normalized time scales of the Jp t) curve in the 10 5 X 10 cm /dyne region and is effectively decoupled from how... 

In principle it is rigorous attention scopes. The second only on geometrical scopes) but also on the positrons must particularly sensit correlated with the In practice one can... 

Newly developing multidimensional NMR might become a powerful tool in the future for obtaining valuable information on the chemical structure of humic substances. Two-dimensional phase-sensitive correlation spectra has also been successfully applied for substructure elucidation in size-fractionated humic substances. 

An alternative, less-expensive method to produce disposable sample supports has been described by Owen et al. [80], in which blank stainless-steel plates were coated with Teflon and Scotchgard hydrophobic coatings. An enhancement in detection sensitivity correlated with reduced spot sizes when using the hydrophobic coatings, which could be removed by cleaning and re-applied between uses [80]. 

To assess whether the results obtained with Ho33342 related to some innate feature of cellular chromatin, namely accessibility, permeabilised cells were exposed to a low level of DNase II (under conditions which produced a linear relationship between enzyme concentration and break frequency) and accessibility monitored as the frequency of enzyme-induced DNA strand-breaks. The results (Table 1) show that nuclease sensitivity correlated with the frequency of ligand-induced breaks. 

Politzer P, Murray JS (2003) Sensitivity Correlations. In Politzer PA, Murray JS (eds) Energetic Materials, Part 2 Detonation, Combustion, Theoretical and Computational Chemistry. Elsevier Science, Amsterdam, p 5... 

We have, however, obtained a good correlation with shock sensitivity (correlation coefficient = 0.94) by (a) explicitly taking into account each N-NO2 bond, and... 

In literature, there are several attempts described to predict and calculate the impact sensitivity of energetic materials. Most of these papers deal only with nitro- and nitrate ester compounds, whereas the impact sensitivity of azides has not been the subject of detailed calculations so far, apart from recently published structure-sensitivity correlations on inorganic azides. ... 

In the present chapter a complete treatment of point-defect details in as-grown and annealed crystals is not possible. For this the author refers to the above-mentioned reviews with numerous related references therein. Here, only selected examples, showing their sensitive correlation to the crystallization conditions, will be touched upon. 

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