Screen-printed process

Other small molecule species decompose and volatilise. The glass frit fuses, wetting the surface of the functional phase, providing adhesion and sealing of the composite to the substrate. Because of the screen printing process, resolution is modest. Fired film thicknesses, which range from 10 to 50 p.m (0.4 to 2.0 mils), are large compared to thin-fHm microelectronics. Some photosensitive pastes are also ia use. 

FIGURE 6-23 Steps involved in the screen-printing process (a) deposit the graphite suspension onto the screen (b) load the screen mesh with the graphite (c) force the graphite onto the substrate. (Reproduced with permission from reference 83.)... 

Bender, G., Zawodzinski, T. A., and Saab, A. P. Fabrication of high-precision PEFG membrane electrode assemblies. Journal of Power Sources 2003 124 114—117. Ihm, J. W., Ryu, H., Bae, J. S., Ghoo, W. K., and Ghoi, D. K. High performance of electrode with low Pt loading prepared by simplified direct screen printing process in PEM fuel cells. Journal of Materials Science 2004 39 4647--4649. 

The screen printing process uses a rubber squeegee to force ink through a tightly stretched, finely woven mesh onto various substrates. The basic concept has been refined to the point where large semi- and fully automatic lines are relatively common. Typical products are display printing, industrial and container printing, and printed circuit production. ... 

However, problems associated with the reproducibility between electrodes derived from the screen-printing process and the partial electrode fouling have compromised the sensitivity of the biosensors. Work is in progress to improve both the reproducibility and the limits of detection by the use of new types of electrodes. The toxin overestimation observed with the amperometric biosensor, in the case of the microcystin analysis, suggests the use in parallel to other analytical techniques in order to minimise the risk of false-positive results. Nevertheless, the electrochemical strategy is appropriate to discriminate between toxic/non-toxic samples. 

The use of novel electrode materials should, in principle, improve the reproducibility of the biosensor, since the screen-printing process is thought to be responsible for the standard deviation of the electrochemical measurements. The developed biosensor can also be applied to the analysis of water. In this case, the matrix is expected to produce fewer effects. Finally, the use of molecularly engineered supersensitive enzymes and the combination with signal amplification systems can contribute to increase the sensitivity of the biosensor. 

The multilayer sensor structure consists of cermet and polymer based layers sequentially deposited on a 96% alumina ceramic substrate using a thick film screen printing process. The cermet layers are of ceramic-metal composition which require firing at a temperature of 850°C and the polymer layers are cured at temperatures below 100°C. Layout of this multilayer sensor structure is shown in Figure 1. 

Fig 1 Scheme of the screen-printed process a typical thick-film screen consists of a finely woven mesh of stainless steel, nylon or polyester, mounted under tension on a metal frame, normally aluminium. The screen defines the pattern of the printed film and also determines the amount of paste which is deposited. The mesh is coated with a ultraviolet sensitive emulsion (usually a polyvinyl acetate or polyvinyl alcohol sensitized with a dichromate solution) onto which the circuit pattern can be formed photographically. The ink is placed at one side of the screen and a squeegee crosses the screen under pressure, thereby bringing it into contact with the substrate and also forcing the ink through the open areas of the mesh. The required circuit pattern is thus left on the substrate... 

FIGURE 7.12 The screen-printing process involved in preparation of carbon track electrodes on polymer substrates. 

Figure 3.10 A schematic representation of the screen printing process.

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