Scratches, removal

Scratching (removing loose rust with a wire brush or fine steel wool). 

Concentrated nitric acid renders the metal passive , i.e. chemically unreactive, due to formation of a thin oxide surface film (which can be removed by scratching or heating in hydrogen). 

Dissolve 0-2 g. of fructose in 10 ml. of water, add 0-6 g. of cw-methyl-phenylhydrazine and sufficient rectified spirit to give a clear solution. Since the fructose may not be quite pure, warm the mixture slightly, allow to stand, preferably overnight, so that any insoluble hydrazones may separate if present, remove them by filtration. Add 4 ml. of 50 per cent, acetic acid to the filtrate it will become yellow in colour. Heat the solution on a water bath for 5-10 minutes, and allow to stand in the dark until crystalUsation is complete it may be necessary to scratch the walls of the vessel to induce crystalUsation. Filter the crystals and wash with water, followed by a little ether. RecrystaUise the orange-coloured methylphenylosazone from benzene m.p. 152°. 

Buffiag may be only to remove surface blemishes such as iasect bites or minor healed scratches, or the buffing may be to make a suede surface. Newbuck is a light suedeiag of the grain of catde hide leather. Sheepskin suede is usually buffed on the flesh side of the skin. SpHts may be buffed to make buck shoe leather or heavy garment leather, often called ranch hide. The variations depend on the desires of the customer. 

Strong acids and strong alkaUes can severely bum the skin, chromium compounds can produce skin rashes, and repeated exposure to solvents causes removal of natural oils from the skin. Infection is always a concern for damaged skin. Absorption through the skin is possible for materials that are appreciably soluble iu both water and oil, eg, nitrobenzene, aniline, and tetraethyllead. Other materials can be absorbed if first dissolved iu extremely good solvents, eg, dimethyl sulfoxide. Subcutaneous iujection can occur accidentally by direct exposure of the circulatory system to a chemical by means of a cut or scratch or iuadvertent penetration of the skin with a hypodermic needle. 

Scratch resistance of polymer from DADC is improved by novel mixtures of peroxide initiators such as 5% isopropyl percarbonate with 3.5% benzoyl peroxide (16). In order to force completion of polymerization and attain the best scratch resistance in lenses, uv radiation is appHed (17). Eyeglass lenses can be made by prepolymerization in molds followed by removal for final thermal cross-linking (18). 

The solid is separated by filtration and the filtrate is extracted with three 150-ml. portions of ether. Caution Gloves should be worn when handling this solution because of the large amount of cyanide it contains.) The solid is dissolved in ether and this solution is combined with the extracts. The combined ethereal solutions are washed with water and dried over 5 g. of sodium sulfate. Removal of the solvent by distillation leaves crude ferrocenyl-acetonitrile as a solid or as an oil that crystalli/.es on being scratched. I he nitrile is dissolved in about 200 ml. of boiling... 

A careful inspection of both shaft ends must be made to ensure that no burrs, nicks, or scratches are present that will damage the hubs. Potentially damaging conditions must be corrected before coupling installation. Emery cloth should be used to remove any burrs, scratches, or oxidation that may be present. A light film of oil should be applied to the shafts prior to installation. Keys and key-ways (discussed in Section 59.3) also should be checked for similar defects and to ensure that the keys fit properly. Properly sized key stock must be used with all keyways do not use bar stock or other material. 

Table 15.13. This specification follows good industrial practice, with additional safeguards in rinsing to remove residues to treatment solutions. Nonaccelerated treatments must be followed by a single rinse which may contain chromate accelerated treatments must be followed by three rinses—cold water, hot water and a final chromate rinse. Table 15.14 shows the salt-spray test requirements for phosphate coatings with various finishes without formation of rust the paints and lacquer have the additional requirement that no rust shall be visible beyond 0-2 in (5 mm) from the deliberate scratches and no blistering, lifting or flaking beyond 0-05 in (1-27 mm) from the original boundaries of the scratches.

Hardness is closely related to strength, stiffness, scratch resistance, wear resistance, and brittleness. The opposite characteristic, softness, is associated with ductility. There are different kinds of hardness that measure a number of different properties (Fig. 5-5). The usual hardness tests are listed in three categories (a) to measure the resistance of a material to indentation by an indentor some measure indentation with the load applied, some the residual indentation after it is removed, such as tests using Brinell hardness,... 

The mechanism of micro/nano friction and wear/ scratch is still not well known. There are several questions that need to be answered (a) How are the materials removed at very low load as nano Newton scale. Is it similar to that at macro scale Can we explain the material loss according to the traditional wear mechanisms (b) What is the connection between micro and macro friction and wear ... 

Abrasive cleaners are often needed for laboratory jobs, such as removing pencil markings from etched spots on glassware. No glassware should be put away with such markings. Liquid cleaners of this type may not be as effective as powders, but their gentler abrasives are less likely to cause scratching. 

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