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Rydberg constant, calculation

Rydberg constant, calculated exactly using Bohr theory or the Schrodinger equation... [Pg.5]

Rydberg constant, calculated exactly using Bohr theory or the Schrodinger equation Z = atomic number, equal to 1 for hydrogen n = principal quantum number... [Pg.9]

Calculate the Rydberg constant from the values of the fundamental constants [see... [Pg.80]

Muonium, atom number zero , is composed of a positron and an electron. Calculate foe Rydberg constant for this species. [Pg.80]

Which of the following setups would be used to calculate the wavelength (cm) of a photon emitted by a hydrogen atom when the electron moves from the n = 5 state to the n = 2 state (The Rydberg constant is R = 2.18 x 10 18 J. Planck s constant is... [Pg.90]

An atomic unit of length used in quantum mechanical calculations of electronic wavefunctions. It is symbolized by o and is equivalent to the Bohr radius, the radius of the smallest orbit of the least energetic electron in a Bohr hydrogen atom. The bohr is equal to where a is the fine-structure constant, n is the ratio of the circumference of a circle to its diameter, and is the Rydberg constant. The parameter a includes h, as well as the electron s rest mass and elementary charge, and the permittivity of a vacuum. One bohr equals 5.29177249 x 10 meter (or, about 0.529 angstroms). [Pg.95]

In numerical calculations below we will use the most precise modern values of the fundamental physical constants as obtained in [1]. The value of the Rydberg constant is... [Pg.233]

Due to the suppression factor the difference of the leading Dirac and recoil contribution of the RHS in (12.10) may be calculated with high accuracy, and practically does not depend on the exact value of the Rydberg constant. Then the precise magnitude of the linear combination of the Lamb shifts on the RHS extracted from the experimentally measured frequencies on the LHS and calculated difference of the leading Dirac and recoil contribution of... [Pg.240]

Show that they fit eqn 4.11 with nt = 1, and n2 = 2, 3, and 4, respectively. Derive an accurate value for the Rydberg constant for hydrogen, and use it to calculate the ionization energy of hydrogen. Give your answer in electron volts and in kilojoules per mole. [Pg.69]

Use the values for fundamental constants (with m equal to the mass of an electron) in eqn 4.16 to calculate a value for the Rydberg constant. What correction is necessary to give the value for hydrogen ... [Pg.69]

The Rydberg constant for deuterium (2H or 2D) is 109,707 cm-1. Calculate (a) the shortest wavelength in the absorption spectrum of deuterium, (b) the ionization energy of deuterium, and (c) the radii of the first three Bohr shells (orbits). [Pg.122]

Recently we have used the femtosecond technology to measure the transition frequency of the cesium Di line [45]. This line provides an important link for a new determination of the fine structure constant a. Because a scales all electromagnetic interactions, it can be determined by a variety of independent physical methods. Different values measured with comparable accuracy disagree with each other by up to 3.5 standard deviations and the derivation of the currently most accurate value of a from the electron g — 2 experiment relies on extensive QED calculations [46], The 1999 CODATA value [47] or1 = 137.035 999 76(50) (3.7 x 10-9) follows from the g — 2 results. To resolve this unsatisfactory situation it is most desirable to determine a value for the fine structure constant that is comparable in accuracy with the value from the g — 2 experiment but does not depend heavily on QED calculations. A promising way is to use the accurately known Rydberg constant i oc according to ... [Pg.140]

The two-photon 243 nm lS S-i/2 transition and other transitions in the hydrogen atom have recently been included in a new list of approved radiations for the practical realisation of the metre [2]. The particular interest of these transitions lies in the fact that, uniquely among present optical frequency standards, they may be calculated in terms of the Rydberg constant with an accuracy approaching that with which they have been measured. The latest measurement of... [Pg.664]

The Rydberg constant is the scale factor that connects all theoretical calculations and experimental measurements of energy levels in any system involving electrons. This includes all atoms, molecules and condensed matter. In simple systems, such as hydrogen, positronium, muonium, and possibly helium, the theoretical accuracy is comparable to that of experiments. In this case, experimenters can be said to measure the Rydberg constant, if not to test theory. [Pg.847]

Laser spectroscopy, at the moment, is the method par excellanoe to measure R. Measurement of the Rydberg constant R is a simple matter. One measures the wavelength or frequency (the velocity of light is defined to be 299 792 1)58 m/sec) in a system, such as hydrogen, where theoretical calculations are expected to be accurate to within the experimental error. One then compares this measurement (in Hz or cm-1) with the theoretical calculation (in atomic units), thereby finding the atomic unit in Hz or cm-1. Half of the atomic unit is the Rydberg... [Pg.847]

The Rydberg constant is a constant that meets all the criteria established for being deemed fundamental. In addition, the Rydberg constant connects all theoretical calculations and experimental measurements of the energy states of any atom. [Pg.199]

In the hydrogen atom spectrum, calculate 0 if m = 1 and n = 3 using the equation given in the text. Take the value of the Rydberg constant, R, from Appendix 4. [Pg.40]

X 10- ) follows from the g — 2 results. To resolve this unsatisfactory situation it is most desirable to determine a value for the fine structure constant that is comparable in accuracy with the value from the g — 2 experiment but does not depend heavily on QED calculations. A promising way is to use the accurately known Rydberg constant 7 oo according to ... [Pg.140]

The Is-2s transition energy is primarily due to the (electron) Rydberg constant, where the antiproton mass contributes via the reduced mass only of the order of 10 . For the theoretical calculations an uncertainty exists at the level of 5 X 10 [17] (finite size corrections) due to the experimental error in the determination of the proton radius, even if only the more rehable Mainz value of = 0.862 0.012 fm [18] is used (for a detailed discussion of the pro-... [Pg.534]


See other pages where Rydberg constant, calculation is mentioned: [Pg.188]    [Pg.182]    [Pg.243]    [Pg.241]    [Pg.350]    [Pg.69]    [Pg.28]    [Pg.185]    [Pg.534]    [Pg.637]    [Pg.637]    [Pg.670]    [Pg.688]    [Pg.848]    [Pg.878]    [Pg.65]    [Pg.214]    [Pg.188]    [Pg.1]    [Pg.37]    [Pg.165]    [Pg.9]    [Pg.21]    [Pg.185]    [Pg.637]    [Pg.637]    [Pg.670]    [Pg.688]    [Pg.58]   
See also in sourсe #XX -- [ Pg.109 ]




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