Rocket hydrogen

Concentrated hydrogen peroxide was widely used during World War II as an oxidant in a mixture with hydrazine hydrate, for the propulsion of Y2 rockets. Hydrogen peroxide mixed with hydrazine reacts spontaneously according to the equation ... 

Liquid hydrogen peroxide has been used as a propellant for rockets. Hydrogen peroxide decomposes into oxygen and water, giving off heat energy equal to 686 Btu per pound of... 

Helium is extensively used for filling balloons as it is a much safer gas than hydrogen. One of the recent largest uses for helium has been for pressuring liquid fuel rockets. A Saturn booster, like the type used on the Apollo lunar missions, required about 13 million fts of helium for a firing, plus more for checkouts. 

RocketPropella.nts, Liquid propellants have long been used to obtain maximum controUabiUty of rocket performance and, where required, maximum impulse. Three classes of rocket monopropellants exist that differ ia the chemical reactions that release energy (/) those consisting of, eg, hydrogen peroxide, ethylene oxide, C2H4O and nitroethane, CH2CH2NO2 that can undergo internal oxidation—reduction reactions (2) those... 

Propellants and Explosives. Hydrazine fuels include anhydrous hydrazine (AH), monomethyUiydrazine (MMH), and unsymmetrical dimethyUiydrazine (UDMH) for military and space programs. These compounds are used mainly as bipropeUant fuels, ie, with oxidizers, in rockets such as the Titan, MX missile, and the Ariane (UDA4H7X30. Using oxygen or fluorine as the oxidizer, hydrazine is exceeded only by hydrogen in specific impulse, ie, kilograms of thmst developed for each kilogram of fuel consumed per second (196). 

The reaction with fluorine occurs spontaneously and explosively, even in the dark at low temperatures. This hydrogen—fluorine reaction is of interest in rocket propellant systems (99—102) (see Explosives and propellants, propellants). The reactions with chlorine and bromine are radical-chain reactions initiated by heat or radiation (103—105). The hydrogen-iodine reaction can be carried out thermally or catalyticaHy (106). 

Fig. 12. Schematic of a nuclear rocket (74). Liquid hydrogen is heated by a reactor and expelled as a gas through the no22le.

Metallacarboranes. These are used in homogeneous catalysis (222), including hydrogenation, hydrosilylation, isomerization, hydrosilanolysis, phase transfer, bum rate modifiers in gun and rocket propellants, neutron capture therapy (254), medical imaging (255), processing of radioactive waste (192), analytical reagents, and as ceramic precursors. 

Reider et al. (1965) describe the incident at Los Alamos Laboratory in Jackass Flats, Nevada. An experiment was conducted on January 9, 1964, to test a rocket nozzle, primarily to measure the acoustic sound levels in the test-cell area which occurred during the release of gaseous hydrogen at high flow rates. Hydrogen discharges were normally flared, but, in order to isolate the effect of combustion... 

Although modern chemistry allows development of even more effective rocket propellants, energy efficiency is not the only consideration factor. For example, fluorine and its derivatives arc better oxidizers than oxygen, but their extreme toxicity make them environmentally dangerous. The same concerns prevent the use of beryllium hydride—an excellent fuel that combines high density with the energy efficiency comparable to liquid hydrogen. 

C04-0142. One set of reactants for rocket fuel is hydrazine and hydrogen peroxide, which react vigorously when mixed N2 H4(/) +H2 02(/) N2(g) + H2 0(g) (unbalanced) The density of liquid hydrazine is 1.44 g/mL, and that of hydrogen peroxide is 1.01 g/mL. What volume ratio of these two liquids should be used if both fuels are to be used up at the same time ... 

Fossil fuels are nonrenewable, and combustion products contaminate the atmosphere. Consequently, scientists are searching for new sources of energy. One possibility is molecular hydrogen, which releases energy when it reacts with oxygen 2 H2(g) + 02(g) 2H2 0(/) + Energy Hydrogen powers the rockets of the space shuttle,... 

---