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Resonance resonances

Write an essay of approximately 2000 words on the history and the various definitions of the concept of resonance, resonance energy, and aromaticity. [Pg.219]

Consider next the limit of weak dipole coupling of the initial state with the continuum and/or long-lived resonances, where the direct amplitudes are small as compared to the resonance-mediated ones in the vicinity of a resonance. Returning to Eq. (43) and neglecting the direct-direct and direct-resonant interferences as compared to the resonant-resonant interference at E E j., we have... [Pg.168]

Keywords Carbon nanotubes, chemical and biological sensors, microwave resonance, resonant cavities... [Pg.351]

One of the exciting new directions is the control of activated rate processes using external fields. Addition of an external field opens the way for a wide variety of new phenomena such as stochastic resonance, resonance activation, directed transport, control of the hopping distribution in surface diffusion and more. Even the addition of a constant force to the problem leads to interesting additional phenomena such as the locked to running transition, which remains a topic of ongoing research. " Quantum mechanics in the presence of external fields may differ significantly from the classical. [Pg.35]

Alomic nuclear Innei electronic 1 1 rotation 1 sPjft 1 resonance resonance i... [Pg.13]

Dashed-dotted frames identical Dotted frames upfield shift of the CH3-I8 methyl side-chain methyl resonances resonances suggest the absence of a hydroxy... [Pg.119]

NMR titrations. How do pH changes affect NMR resonances Resonances of H nuclei close enough to a proton with a pK in the pH region under study will experience a shift, which may be either upheld or down-field when the proton dissociates. The resonance of... [Pg.147]

To summarize, for our model Hamiltonian, resonances appear after a bound-virtual and a virtual-virtual resonance transition. There is no method to obtain virtual energies using a square-integrable basis set, even in the complex-rotated formalism. Then, at this point we can ask if FSS is a useful method to study this kind of resonance. As we will show in the next subsection, the answer is yes FSS is a method to obtain near-threshold properties, and with FSS we can characterize the near-threshold resonances by solving the Hermitian (not complex-rotated) Hamiltonian using a real square-integrable basis-set expansion. Moreover, the critical point of the virtual resonance-resonance transition, Xr, could also be obtained using FSS. [Pg.58]

It is important to emphasize that the n = 4 virtual-virtual resonance and resonance curves in Fig. 25 cannot be obtained by using basis-set expansion. Note that the resonance is broad therefore it cannot be calculated even by using stabilization methods [169]. However, the FSS method gives the localization of the virtual resonance-resonance transition. [Pg.64]

The p value for the of the neutral imidate is estimated to be unity as the nitrogen atom is one atom removed from the benzene ring. The p value of 1.7 found for the dissociation of the protonated imidate is possibly due to the delocalisation of the positive charge into the benzene ring by resonance. Resonance interaction is negligible for the dissociation of the neutral imidate (Scheme 2). [Pg.212]

The strong resonance behavior of dyes may interact with the metal substrate resonances and bring about a behavior which is not a simple superposition of either of the two. Pockrand et have shown the orienting effect of a surface on the organization in the dye layer, which affected the formation of dimers or monomers, and also the polarization properties of the dye absorption. In this case, due to the wide absorption bands of the dyes, no resonance-resonance effects were seen. [Pg.344]

Discuss the concept of resonance, being certain to define the terms resonance, resonance form, and resonance hybrid. [Pg.118]

Pumping Power, No Vibration, Power to Vibrating Resonance Resonance, hv,... [Pg.78]


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