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Specific resolution, definition

Pielke, R. A. (1991). A recommended specific definition of resolution, Bull. Amer. Meteor. Soc. 72, 1914. [Pg.195]

Check for potential conflicts in the specification of the goal state, and provide resolution for its consistent definition. [Pg.70]

Peedc-to-peak resolution in SEC can be calculated by the ratio of peak separation at the peak maxiaut to the sum of the baseline peak widths. This general definition of resolution is less useful in SEC, where a measure of the ability of the column to separate solutes of different molecular weight is required. For this purposes, we define a new term, the specific resolution factor, R, which relates peak resolution to sample molecular weight, assuming all measurements are made within the linear region of the molecular weight calibration curve, equation (4.41)... [Pg.739]

Trying to determine which column is ideal for a specific analysis can be difficult with over 1000 different columns on the market [74]. A proper choice implies a definition of parameters such as column material, stationary phase (polarity), i.d., film thickness and column length. Guides to column selection are available [74,75]. The most important consideration is the stationary phase. When selecting an i.d., sample concentration and instrumentation must be considered. If the concentration of the sample exceeds the column s capacity, then loss of resolution, poor reproducibility and peak distortion will result. Film thickness has a direct effect on retention and the elution temperature for each sample compound. Longer columns provide more resolving probe, increase analysis times and cost. [Pg.185]

A comprehensive approach to a states response to a chemical terrorism includes having a plan not only for the crisis and consequence management phases of the incident, but also for all elements required for complete resolution of the event. This may include the necessity to definitively establish whether chemical agents were used, to provide supporting evidence to confirm other analyses, or to provide the forensic proof required to support a criminal prosecution. The collection and analysis of biomedical samples - blood, urine or other tissue from affected humans or animals - is one of the means for providing such information. Although current capabilities such as urinary thiodyglycol excretion or plasma cholinesterase activity can be performed, there is scope for far more sensitive and specific assessments that overcome the limitations of these approaches. [Pg.123]

The term resolution essentially describes the same the small difference being that its definition is based on the resulting signals. The resolution R is defined as the ratio of the mass of interest, m, to the difference in mass. Am, as defined by the width of a peak at a specific fraction of the peak height. [1]... [Pg.96]

The TINS methodology, by definition, requires immobilized protein to allow flow-through screening of ligands. Clearly, the choice of the surface upon which the protein will be immobilized and the choice of the immobilization chemistry have to be made within the limitations of the TINS equipment. The general requirements for immobilization compatible with high-resolution NMR have been discussed, so here we focus on issues specifically related to membrane proteins. [Pg.146]

Now that the range of likely shapes has been defined by experiments on related molecules and by energy calculations, we focus on the details of specific structures that have been observed for real, crystalline cellulose molecules, primarily by x-ray, neutron, and electron diffraction studies. A number of landmark concepts have been established with electron microscopy, as well. Infrared (IR), Raman, and nuclear magnetic resonance (NMR) spectroscopy have all also been important in the quest for understanding cellulose structure. Such data, while so far not able to provide complete definitive structures themselves, constitutes additional criteria that any proposed structure must be able to explain. In addition, unlike crystallography, the resolution of spectroscopic methods is not directly affected by the dimensions of the... [Pg.50]


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See also in sourсe #XX -- [ Pg.172 ]




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