Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reliability theory dependability

The thermodynamic theory of solutions is complete in the sense that the exact relations among thermodynamic coefficients are all known, the Gibbs-Helmholtz equation for example. However in practice it commonly is necessary to make predictions on the basis of incomplete data, therefore to make extrapolations and other approximations. Reliable approximations depend upon a knowledge of the solution structure. [Pg.548]

Depends on a large database and reliable theory Requires a few creative experts... [Pg.230]

There have been several other theoretical studies by different authors [144, 145,156,163] where the frequency-dependent friction was modeled by using the modified version of the generalized hydrodynamic expression [23, 165]. These theories failed to reproduce the experimental results at certain limits. Barbara and coworkers attributed this failure of the G-H theory to the nonavailability of a reliable frequency-dependent friction and called for the use of a friction better than the hydrodynamic friction. [Pg.188]

In theory, inkjet is simple. A print head ejects tiny drops of ink onto a substrate. In practice, implementation of the technology is complex and requires multidisciplinary skills. Reliable operation depends on careful design, implementation, and operation of a complete system where no element is trivial. [Pg.3]

The main characteristic of DFT is to consider the electron density as the principal variable rather than the wave function. The reliability of this theory depends on the goodness of the functionals used to describe the exchange-correlation energy. [Pg.94]

Thus we have argued that the engineer has to make use of propositions, of theories and data, which are highly variable in their testability and dependability. The next question is, obviously, how can we use the ideas presented in this chapter to help the engineer measure this variable dependability, even if the measurement has to be subjective There is no accepted answer to this question today, but one purpose of the work described in Chapters 6 and 10 is to begin to provide a theoretical basis for such measurements. Firstly we have to be convinced that the present methods of reliability theory based on probability theory are inadequate. In fact it will be argued in Chapter 5 that the present use of reliability theory confuses the four aspects of testability discussed earlier. We will demonstrate the limitations of probability theory as a measure of the testability or dependability of a theory. In Chapter 6 we will discuss the theoretical developments which may eventually lead us to measures of the various aspects of testability and dependability, and we will return to a discussion of this in Chapter 10. [Pg.45]

If we need to be able to deal with all types of uncertainty, can mathematics as a formal language help us It is the purpose of this chapter to review briefly and qualitatively the basic ideas of mathematics, in particular logic and set theory, on which probability theory depends. The nature of probability and its application in reliability theory as applied to structural design, and the problems of applying it to estimate system uncertainty are then discussed. It is not intended to cover the techniques associated with the theories, only the ideas behind them. Many texts are available on all the subjects touched here, to which reference will have to be made if techniques for handling the ideas are required. The purpose of the following discussion is to attempt to clarify the basis on which we work... [Pg.258]

Most of the reliability theory literature focuses on binary systems, i.e., systems with only two states functioning or failed. See e.g., (Barlow Proschan, 1981). In many real life applications, however, systems have more than two states. A typical example is a network flow system where the state of the system may be defined as the flow capacity of the system. Depending on the number of functioning links in the system, this capacity varies between full capacity and zero capacity, but with several intermediate states as well. [Pg.652]

Estimations of probability defined with help of cumulative distribution function can be applied for investigation within some area where maximum a and minimum b values of analyzed factor are established. In this case as hazardous parameter assess an interval probability Pab of karst forms development. Accuracy of estimation with using interval probability Pab depends on the sizes of study area and homogeneity of natural conditions within its borders. Let s notice, such approach to assessment of probability is widely applies in reliability theory of systems. [Pg.870]

The benefits of administrational redundancy, like those of any other form of redundancy, come with the caveat that redundant components must be independent. Engineering reliability theory explicitly assumes that redundant components in engineering systems are independent of one another. Systems engineers recognize that components are often not truly independent and refer to this situation as component dependence. But they typically assume independence to simplify calculations of system reliability and then make design decisions with the goal of decreasing component dependence. [Pg.87]

Aerospace Corporation, 92-3, 94 coordination neglect, 84-5, 90, 91, 92, 95 dependence, 85-95 high reliability, 82-4 managerial implications, 95 McDonald s observations, 342 recommendations for NASA, 94-5 the space between defined, 82 reliability, see high-reliability organizations (HROs) High Reliability Theory rescue mission possibility, 216 see also recovery window research-operations balance, see RHD-operations balance... [Pg.382]

With so many molecules now being observed in interstellar clouds, chemical reaction models which can explain how these molecules are produced and destroyed are becoming increasingly more valuable. The most modern chemical reaction networks that have been proposed involve following the concentration of several hundred atomic and molecular species as a function of time, and reliable temperature-dependent rate coefficients for several thousand reactions are a vital requirement in such simulations. The role of ion-molecule reactions has been shown to be of particular Importance in these networks as these reactions can have very large rate coefficients at the low temperatures of interstellar clouds [2]. Furthermore, a more limited number of neutral species, particularly radicals and open-shell atoms, can have large rate coefficients at low temperatures [3]. Since only a relatively small number of reactions have been studied in the laboratory at the temperatures relevant to Interstellar chemistry, theory plays an Important role in producing many of the required rate coefficients. [Pg.1]

As mentioned above, experimental protocols are challenging in order to directly probe isolated polyelectrolyte chains, such as their sizes, counterion distributions, and electric potential variations inside and outside the coils. These quantities are sometimes deduced from measurements of other quantities, such as the electrophoretic mobility. The interpretation of data in these indirect measurements also depends heavily on reliable theories. The theoretical... [Pg.92]

The reliability theory is heavily dependent on statistics and probability, but was developed apart from mainstream statistics and probability to help insurance companies in the nineteenth century. It also heavily relies on the theory of interference. Part fimctional reliability will be discussed below in terms of safety margins and Weibull analysis. [Pg.224]

In recent years, these methods have been greatly expanded and have reached a degree of reliability where they now offer some of the most accurate tools for studying excited and ionized states. In particular, the use of time-dependent variational principles have allowed the much more rigorous development of equations for energy differences and nonlinear response properties [81]. In addition, the extension of the EOM theory to include coupled-cluster reference fiuictioiis [ ] now allows one to compute excitation and ionization energies using some of the most accurate ab initio tools. [Pg.2188]

In these ways, then, concentration factors of up to five orders of magnitude may be developed, depending upon the circumstances. Despite much work in this area, theory has not yet developed to the stage where accurate predictions can be made reliably, but the state of the art is such that semi-quantitative assessments can be of considerable value in interpreting occurrences. [Pg.843]

A central problem in studying ion-molecule reactions is the dependence of the microscopic cross-section, a or the rate constant k upon the relative velocity of the ion and the molecule. Only from reliable, established data on this dependence can one choose among the various theoretical models advanced to account for the kinetics of these processes such as the polarization theory of Gioumousis and Stevenson (10) or the more recent phase-space treatment of Light (26). [Pg.137]


See other pages where Reliability theory dependability is mentioned: [Pg.206]    [Pg.200]    [Pg.356]    [Pg.410]    [Pg.85]    [Pg.186]    [Pg.476]    [Pg.66]    [Pg.89]    [Pg.164]    [Pg.166]    [Pg.173]    [Pg.1912]    [Pg.275]    [Pg.328]    [Pg.57]    [Pg.10]    [Pg.247]    [Pg.558]    [Pg.324]    [Pg.97]    [Pg.438]    [Pg.306]    [Pg.47]    [Pg.1034]    [Pg.391]    [Pg.441]    [Pg.2]    [Pg.46]    [Pg.441]    [Pg.233]   
See also in sourсe #XX -- [ Pg.488 ]




SEARCH



Reliability theory

© 2024 chempedia.info