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Reductive lithiation of alkyl phenyl sulfide

The first step in the reductive lithiation of alkyl phenyl sulfides (Screttas-Cohen process) consists of preparing the reducing reagent in stoichiometric amounts. Lithium naphthalenide, for example, is made from lithium and naphthalene. The sulfide is added drop wise to this reducing reagent. The mechanism of reduction corresponds step by step to the one outlined in Figure 17.44, except that the dissolved radical anion is the source of the electrons, as opposed... [Pg.782]


See other pages where Reductive lithiation of alkyl phenyl sulfide is mentioned: [Pg.82]    [Pg.783]    [Pg.579]   
See also in sourсe #XX -- [ Pg.782 ]




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Alkyl phenyl

Alkyl phenyl sulfides

Alkyl reduction

Alkyl sulfides

Alkylate, 2-phenyl

Phenyl sulfide

Reductants sulfide

Reduction alkylation

Reduction reductive alkylation

Reduction-sulfidation

Reductive alkylation

Reductive lithiation

Reductive lithiation of phenyl sulfides

Reductive phenylation

Sulfide reduction

Sulfides alkylated

Sulfides alkylation

Sulfides reductive lithiation

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