Reducing smelting

Reducing smelting furnaces that produce a high-sulfidity, kraft-like green liquor are now employed at sodium-based sulfite mills. U.S. EPA anticipates that it would be necessary to replace the existing recovery boilers at ammonia-based mills if chemical substitution to a sodium base were employed. Additionally, it is likely that, because the heat value of sodium spent liquor is lower than ammonia spent liquor, evaporator modification may he required if excess capacity does not already exist. 

The smelting process temperature is designed to be in the region 1000°C - 1050 C and a mildly reducing smelting regime will be utilised. The design mass balance for the process is shown in Table V. 

The bismuth oxide concentrate are rarely little on the ore production, so the materials of the reducing smelt are the bismuth oxide dross attained from the oxidizing smelt of the lead or copper anode slime[19,20,21],the bismuth oxychloride enriched from the blast fumace[22], the copper converter flue dust[23], and so on. 

Of our special interest is the thickness measurement of powder coatings. While the sound velocity of the electrostatic applied powder/air mixture is estimated to be two times the velocity in air it is also an estimation that thickness powder / air layer is reduced by a factor of 5 by smelting (burning in process, hardening). 

The process of extraction requires first smelting (to obtain the crude metal) and then refining. In smelting, iron ore (usually an oxide) is mixed with coke and limestone and heated, and hot air (often enriched with oxygen) is blown in from beneath (in a blast furnace). At the lower, hotter part of the furnace, carbon monoxide is produced and this is the essential reducing agent. The reduction reactions occurring may be represented for simplicity as ... 

Ironmaking refers to those processes which reduce iron oxides to iron. By the nature of the processes, the iron produced usually contains carbon and/or other impurities which are removed in downstream processing. There are three principal categories of ironmaking processes, in order of commercial importance blast furnace, direct reduction, and direct smelting. 

From this relationship it can be seen that a reduction level of 95% compares with a metallisation level of 92.5%. A reduction level of 33.33% or less has a metallisation level of 0%. DRI normally has at least 90% reduction or 85% metallisation. Processes producing soHd, partially reduced iron, ie, <90% reduced or <85% metallised, are classified as prereduction processes. The partially reduced product, called prereduced iron, is not acceptable for steelmaking but can be used as a feed for iron smelting. 

Other Le d Smeltings Processes. Stricter regulations concerning lead emissions and ambient lead in ak levels (see Airpollution), and the necessity to reduce capital and operating costs have encouraged the development of alternative lead smelting processes to replace the sinter plant—blast furnace combination. 

The essential operations of an extractive metallurgy flow sheet are the decomposition of a metallic compound to yield the metal followed by the physical separation of the reduced metal from the residue. This is usually achieved by a simple reduction or by controlled oxidation of the nonmetal and simultaneous reduction of the metal. This may be accompHshed by the matte smelting and converting processes. 

In primary smelting, carbon (in the form of coal or fuel oil) is the reducing agent. During heat-up, carbon monoxide is formed by reaction with... 

Metafile arsenic can be obtained by the direct smelting of the minerals arsenopyrite or loeUingite. The arsenic vapor is sublimed when these minerals are heated to about 650—700°C in the absence of air. The metal can also be prepared commercially by the reduction of arsenic trioxide with charcoal. The oxide and charcoal are mixed and placed into a horizontal steel retort jacketed with fire-brick which is then gas-fired. The reduced arsenic vapor is collected in a water-cooled condenser (5). In a process used by Bofiden Aktiebolag (6), the steel retort, heated to 700—800°C in an electric furnace, is equipped with a demountable air-cooled condenser. The off-gases are cleaned in a sembber system. The yield of metallic arsenic from the reduction of arsenic trioxide with carbon and carbon monoxide has been studied (7) and a process has been patented describing the gaseous reduction of arsenic trioxide to metal (8). 

The washed slime is dried and melted to produce slag and metal. The slag is usually purified by selective reduction and smelted to produce antimonial lead. The metal is treated ia the molten state by selective oxidation for the removal of arsenic, antimony, and some of the lead. It is then transferred to a cupel furnace, where the oxidation is continued until only the silver—gold alloy (dorn) remains. The bismuth-rich cupel slags are cmshed, mixed with a small amount of sulfur, and reduced with carbon to a copper matte and impure bismuth metal the latter is transferred to the bismuth refining plant. 

---