Recrystallization deformed

Considerable geochemical and isotopic evidence has accumulated supporting the concept that many parts of the mantle have experienced a complex history of partial melting, melt emplacement, crystallization, recrystallization, deformation, and metasomatism. A result of this complex history is that the mantle is chemically and isotopically heterogeneous. 

Effect of Thermal History. Many of the impurities present in commercial copper are in concentrations above the soHd solubihty at low (eg, 300°C) temperatures. Other impurities oxidize in oxygen-bearing copper to form stable oxides at lower temperatures. Hence, because the recrystallization kinetics are influenced primarily by solute atoms in the crystal lattice, the recrystallization temperature is extremely dependent on the thermal treatment prior to cold deformation. 

In one of the most significant observations, small amounts of recrystallized material were observed in rutile at shock pressure of 16 GPa and 500 °C. Earlier studies in which shock-modified rutile were annealed showed that recovery was preferred to recrystallization. Such recrystallization is characteristic of heavily deformed ceramics. There has been speculation that, as the dislocation density increases, amorphous materials would be produced by shock deformation. Apparently, the behavior actually observed is that of recrystallization there is no evidence in any of the work for the formation of amorphous materials due to shock modification. Similar recrystallization behavior has also been observed in shock-modified zirconia. 

Several Intermetallics, for example Ni3Al, are ordered right up to the melting temperature showing only minor variation of order parameter with temperature. In the present paper LRO-kinetics is studied in CusAu, where a Ti of about 390°C allows a considerable variation of the degree of LRO until its complete dissolution. We report on results of recrystallized material as well as samples deformed in the disordered and the ordered state. Part of this work was already presented at an earlier conference. ... 

Samples were deformed by rolling at room temperature after disordering and quenching (40% and 80% reduction in thickness) and after ordering by a 19h annealing at 300°C (30% reduction). Completely recrystallized samples were prepared by annealing 48h at 600°C. Resistivity measurement was done by the potentiometric method in liquid N2 relative to a dummy specimen (accuracy 3x10" ). 

The samples deformed in the disordered state show a behaviour different for the two degrees of deformation The sample cold-rolled to 40% at 260°C starts to decrease continuously to the completely recrystallized value, whereas the more highly deformed sample (80%) increases slightly (18%) until 390°C where a drastic decrease in hardness starts. 

From a comparison of the evolution of hardness of all samples during isochronal armealing it can be concluded that for high deformation in the disordered state and deformation in the ordered state, recovery and recrystallization is prevented up to T, in the sample deformed to 40% reduction in the disordered state recovery and recrystallization processes seem to start as soon as atomic mobility is enabled (260°C). 

It is observed that in all deformed samples hardness above T, is considerably higher than the recrystallized value, which is reached for all samples at 600°C. 

Figure 2. Resistivity change versus temperature for isochronal annealing (AT=I0K, At=l 5min) of Au-5at%Fe in the recrystallized (7) and deformed state ( ) (cold-rolled to about 80% thickness reduction).

Qualitatively, the process of re-ordering proceeds similar in deformed and homogenised samples. Yet, two differences between deformed and recrystallized samples are observed ... 

M. MigscUtz and W Pfeiler, Short-range order kinetics in a-AuFe after deformation and recrystallization,... 

The crystal of 2 OPr recrystallized from EtOH/H20 solution, and the mixed crystal of the same ethyl and propyl cinnamate derivatives (2 OEt and 2 OPr), on photoirradiation for 2h at room temperature with a 500 W super-high-pressure Hg lamp, afforded the highly strained tricyclic [2.2] paracyclophane (2 OEt-2 OPr-cyclo) crystal quantitatively (Maekawa et ai, 1991b). A crystal structure analysis was carried out of a single crystal of the complex of 2 OEt-2 OPr-cyclo with HFIP (recrystallization solvent) in a 1 2 molar ratio. Fig. 13 shows the molecular structure of 2 OEt-2 OPr-cyclo viewed along the phenylene planes. The short non-bonded distances and deformation of the benzene rings, as seen in Fig. 13, are common to those of [2.2] paracyclophanes, as previously reported (Hope et ai, 1972a,b). 

Galena, tetrahedrite-tennantite, mawsonite and native silver occur in the copper rich ores but not in ordinary pyritic ores and copper rich ores most commonly occur as offshoots, tongues and veins in the deformed deposits. This suggests that these minor minerals formed during the metamorphic deformation stage accompanied by recrystallization. 

Plastic deformation, unlike elastic deformation, is not accurately predicted from atomic or molecular properties. Rather, plastic deformation is determined by the presence of crystal defects such as dislocations and grain boundaries. While it is not the purpose of this chapter to discuss this in detail, it is important to realize that dislocations and grain boundaries are influenced by things such as the rate of crystallization, particle size, the presence of impurities, and the type of recrystallization solvent used. Processes that influence these can be expected to influence the plastic deformation properties of materials, and hence the processing properties. 

As an additional example of high practical significance, we refer here to copper depKJsits when used in microelectronics, mirrors, and other optical applications. Those deposits have been observed to soften in time even when stored at room temperature for only 4 to 6 weeks. Also, mirrors and other precision objects made of copper will undergo surface deformation after a few months. This type of degradation can be counterbalanced by a suitable metal overcoating. Another, not always practical way is heat treatment to about 300°C. These phenomena are the direct results of microstructural instabilities, often referred to as recrystallization in the copper. It is worth stressing that recrystallization is not limited to copper (5). 

Annealing in metals can first lead to stress relaxation in which stored internal strain energy due to plastic deformation is relieved by thermally activated dislocation motion (see Figure 5.18). Because there is enhanced atomic mobility at elevated temperatures, dislocation density can decrease during the recovery process. At still higher temperatures, a process known as recrystallization is possible, in which a new set of... 

Dislocations multiply in a facile manner during a plastic deformation process, and several mechanisms for this have been observed by electron miscroscopy. Dislocations are destroyed by the processes of recovery and recrystallization during annealing after plastic deformation. Since dislocations cause low-yield stresses in metals and other solids, solid strengthening is accomplished either by eliminating dislocations or by immobilizing them. 

The white crystals (mp 174-176 °C) are soluble in dichloromethane, acetone, benzene, and chloroform and insoluble in ethanol, methanol, and hexane. Both solid and solution are air stable, and recrystallization is from dichloromethane-ethanol. The IR spectrum (Nujol mull between KBr plates) shows strong bands at 2070 and 1895 cm-1 due to Os—H stretching vibrations, a band at 1233 cm -1 due to C—S stretching, and weak bands at 800 and 775cm-1 due to Os—H deformation. HNMR (CDC13, 37°C) shows multiplets centered at d — 10.43 and — 7.32. 

Recrystallization occurs when a crystalline material is plastically deformed at a relatively low temperature and then heated [1]. The as-deformed material possesses excess bulk free energy resulting from a high density of dislocations and point-defect debris produced by the plastic... 

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