Mixing reactors

The heat integration characteristics of reactors depend both on the decisions made for the removal or addition of heat and the reactor mixing characteristics. In the first instance, adiabatic operation is considered, since this gives the simplest design. 

Applications One typical apphcation in heat transfer with batch operations is the heating of a reactor mix, maintaining temperature during a reaction period, and then cooling the products after the reaction is complete. This subsection is concerned with the heating and cooling of such systems in either unknown or specified periods. 

Whenever reaction rates are of the same magnitude as, or faster than, the mixing rate in a stirred reactor, mixing will have a... 

Segregrated flow model The fluid in a flow reactor is assumed to behave as a macrofluid. Each clump functions as a miniature batch reactor. Mixing of molecules of different ages occurs as late as possible. 

TABLE I. REACTOR MIXING MODELS The derivations of the equations are given by Treybig (32)... 

Summarizing, the output of the reactor is an integral over time and over the entire reaction space with all interconnections between different zones of the reactor. Mixing and heat- and mass-transfer conditions are usually different in various zones and the pattern of these differences as well as proportions between size of zones vary with scale. Obviously, the histories of concentrations and temperatures in the zones differ. Whether the integral outputs of laboratory and full-scale reactors differ from each other, depends on the sensitivity of the process to mixing and heat- and mass-transfer conditions. If the sensitivity is low only minor... 

In this chapter the simulation examples are described. As seen from the Table of Contents, the examples are organised according to twelve application areas Batch Reactors, Continuous Tank Reactors, Tubular Reactors, Semi-Continuous Reactors, Mixing Models, Tank Flow Examples, Process Control, Mass Transfer Processes, Distillation Processes, Heat Transfer, and Dynamic Numerical Examples. There are aspects of some examples which relate them to more than one application area, which is usually apparent from the titles of the examples. Within each section, the examples are listed in order of their degree of difficulty. 

In this model of non-ideal reactor mixing, a fraction, fi, of the volumetric feed rate, F, completely by-passes the mixing in the reactor. In addition, a fraction, f2, of the reactor volume, V, exists as dead space. F3 is the volumetric rate of exchange between the perfectly mixed volume Vi and the dead zone volume V2 of the reactor. 

SPBEDRTD - Spouted Bed Reactor Mixing Model System... 

Bioremediation of Soil Particles 591 Spouted Bed Reactor Mixing Model 390 Steady-State, Two-Pass Heat Exchanger 515 Multicomponent, Semi-Batch Steam Distillation 508 Space-Time-Yield and Safety in a Semi-Continuous Reactor 365... 

Premixer Catalytic Post-catalyst reactor mixing... 

Differential (flow) reactor Integral (plug flow) reactor Mixed flow reactor Batch reactor for both gas and solid... 

Dispersion is another reactor mixing topic that will be discussed in Chapter 6. Dispersion normally is used when cross-sectional mean concentrations and velocities are being computed. A cross-sectional mean concentration is useful for a pipe, stripping tower, river, or groundwater transport. 

Solving the diffusion equation in environmental transport can be challenging because only specihc boundary conditions result in an analytical solution. We may want to consider our system of interest as a reactor, with clearly defined mixing, which is more amenable to time dependent boundary conditions. The ability to do this depends on how well the conditions of the system match the assumptions of reactor mixing. In addition, the system is typically assumed as one dimensional. The common reactor mixing assumptions are as follows ... 

---