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Phosphine Reactions with Conjugated Systems

Phosphines may react with certain conjugated systems. This reaction may be conducted deliberately [25] to selectively remove an alkyldiarylphosphine in the presence of a triarylphosphine. Phosphines may react similarly with a, -conjugated carbonyl reaction byproducts such as methacrolein or ethylpropylacrolein. A further concern is reaction with the conjugated system of a feedstream. This chemistry is undesirable when it consumes reagents. Additional harm arises when the reaction product promotes further side reactions, which consume the product.[26]... [Pg.25]


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Conjugate reaction

Conjugate system

Conjugated reaction

Conjugated system conjugation)

Conjugated systems

Conjugative reactions

Phosphine systems

Phosphines reaction

Reaction with phosphines

Reactions phosphination

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