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Reaction phenol hydrogenation

Because phenols are not converted to aryl halides by reaction with hydrogen halides reac tion proceeds no further than shown m the preceding general equation For example... [Pg.1010]

Toxic or malodorous pollutants can be removed from industrial gas streams by reaction with hydrogen peroxide (174,175). Many Hquid-phase methods have been patented for the removal of NO gases (138,142,174,176—178), sulfur dioxide, reduced sulfur compounds, amines (154,171,172), and phenols (169). Other effluent treatments include the reduction of biological oxygen demand (BOD) and COD, color, odor (142,179,180), and chlorine concentration. [Pg.481]

Caprolactam [105-60-2] (2-oxohexamethyleiiiiriiQe, liexaliydro-2J -a2epin-2-one) is one of the most widely used chemical intermediates. However, almost all of the aimual production of 3.0 x 10 t is consumed as the monomer for nylon-6 fibers and plastics (see Fibers survey Polyamides, plastics). Cyclohexanone, which is the most common organic precursor of caprolactam, is made from benzene by either phenol hydrogenation or cyclohexane oxidation (see Cyclohexanoland cyclohexanone). Reaction with ammonia-derived hydroxjlamine forms cyclohexanone oxime, which undergoes molecular rearrangement to the seven-membered ring S-caprolactam. [Pg.426]

The first type includes vulcanising agents, such as sulphur, selenium and sulphur monochloride, for diene rubbers formaldehyde for phenolics diisocyanates for reaction with hydrogen atoms in polyesters and polyethers and polyamines in fluoroelastomers and epoxide resins. Perhaps the most well-known cross-linking initiators are peroxides, which initiate a double-bond... [Pg.153]

The assumed transition state of this reaction is shown in Scheme 5.3. Yb(OTf)3, (J )-(-h)-BINOL, and DBU form a complex with two hydrogen bonds, and the axial chirality of (J )-(-h)-BINOL is transferred via the hydrogen bonds to the amine parts. The additive would interact with the phenolic hydrogen of the imine, which is fixed by bidentate coordination to Yb(III). Because the top face of the imine is shielded by the amine, the dienophiles approach from the bottom face to achieve high levels of selectivity. [Pg.191]

This study shows that the optimization of process conditions could be achieved rapidly by a judicious use of statistics and parallel reactors. A two-level factorial method with two center points was used to limit the total number of experiments to ten. Using two identical high-pressure reactors in parallel further shortened the time required to conduct these experiments. For the model reaction of phenol hydrogenation over a commercially available Pd/C, it was experimentally determined that the optimal yield was 73% at 135 °C, 22.5 bar, and 615 ppm w/w NaOH... [Pg.200]

Phenolic compounds may enhance the rate of decomposition of aromatic ether, because the phenoxy radical may be stabilized by solvation (18) or hydrogen bonding (19) with phenolic compounds and may result in the subsequent hydrogen transfer reaction from hydrogen donating solvent or phenols (20). [Pg.292]

In ethereal solution diazomethane can he preserved for a long time. Information about its numerous reactions (with hydrogen cyanide, acetylene, quinone, etc.) can he found in the special literature of the subject. As has already been mentioned, it is an important methylating agent, especially for phenols. With them it reacts in such a way that the two nitrogen atoms are eliminated as elementary nitrogen, and the two valencies which thus become free are occupied by H and OR. [Pg.274]

Figure 6.9 Abstraction of a phenolic hydroxyl proton by a hydroxyl radical generated by Fenton s reaction with hydrogen peroxide. Figure 6.9 Abstraction of a phenolic hydroxyl proton by a hydroxyl radical generated by Fenton s reaction with hydrogen peroxide.
The thermolysis of 2-methoxyphenol in the presence of cumene as a radical scavenger occurs via two possible pathways. A homolytic cleavage of the methoxyl 0-C bond leads to methane and 1,2-dihydroxybenzene whereas an induced route starting with abstraction of the phenolic hydrogen by cumyl radicals leads, after a cascade of reactions, to phenol, 2-hydroxybenzaldehyde, and 2-hydroxybenzyl alcohol. ... [Pg.194]

When an aqueous solution containing hexachlorobenzene (150 nM) and a nonionic surfactant micelle (0.50 M Brij 58, a polyoxyethylene cetyl ether) was illuminated by a photo-reactor equipped with 253.7-nm monochromatic UV lamps, significant concentrations of pentachlorobenzene, all tetra-, tri-, and dichlorobenzenes, chlorobenzene, benzene, phenol, hydrogen, and chloride ions were formed. Two compounds, namely 1,2-dichlorobenzene and 1,2,3,4-tetrachlorobenzene, formed in minor amounts (<40 ppb). The half-life for this reaction, based on... [Pg.633]

Catalytic Reactions. Phenol hydroxylation was carried out in a batch reactor using 30% aqueous H2O2 in acetone at reflux conditions at a temperature of 80 C. Hydrogen peroxide was introduced slowly via a syringe pump. The products were... [Pg.274]

The reaction of hydrogen peroxide with copper(I) salts produces a Fenton-like hydroxylating system involving reactive hydroxyl radical intermediates (equation 265).486,491 Hydroxylation of benzene to phenol can be achieved by air in the presence of copper(I) salts in an acidic aqueous solution.592 593 This reaction is not catalytic (phenol yields are ca. 8% based on copper(I) salts) and stops when all copper(I) has been oxidized to copper(II). A catalytic transformation of benzene to phenol can occur when copper(II) is electrolytically reduced to copper(I) (equation 266).594,595... [Pg.391]

With Binaphthol/M(OTf)3 Complexes (M = Yb, Sc) A chiral ytterbium triflate, derived from Yb(OTf)3, (R)-binaphthol, and a tertiary amine, has been applied to the enantioselective Diels-Alder reaction of cyclopentadiene with crotonoy 1 oxazolidinones. Among various tertiary amines, c/s-1,2,6-trimethyl piperidine was found to be highly effective [44] (Eq. 8 A.23). The unique structure of such chiral Yb catalysts is characterized by hydrogen bonding between the phenolic hydrogens of (R)-binaphthol and the nitrogens of tertiary amines. [Pg.477]

When coniferyl alcohol is dehydrogenated, it loses its phenolic hydrogen atom to form first an aroxyl radical Ra (XI), which is in eflFect also present as the mesomeric radicals Rb (XII), Rc (XIII), and Rd (XIV). Of these limiting structures, Rb is the most favored. The existence of the radicals in these forms is recognized by their reaction products. In very dilute dioxane-water solution (1 1 vol.), the half-life of the radicals is about 45 seconds 13). [Pg.18]


See other pages where Reaction phenol hydrogenation is mentioned: [Pg.324]    [Pg.324]    [Pg.158]    [Pg.506]    [Pg.425]    [Pg.188]    [Pg.126]    [Pg.148]    [Pg.492]    [Pg.349]    [Pg.729]    [Pg.195]    [Pg.241]    [Pg.517]    [Pg.489]    [Pg.1083]    [Pg.338]    [Pg.845]    [Pg.909]    [Pg.29]    [Pg.136]    [Pg.845]    [Pg.909]    [Pg.490]    [Pg.449]    [Pg.58]    [Pg.257]    [Pg.62]   
See also in sourсe #XX -- [ Pg.132 , Pg.138 ]




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