Reaction injection-molded

The sandwich-type stmcture of polyurethanes with a smooth integral skin produced by the reaction injection molding process provides a high degree of stiffness as weU as exceUent thermal and acoustical properties necessary for its use in housing and load-bearing stmctural components for the automotive, business machine, electrical, furniture, and materials-handling industry. 

Reaction Injection Molding. RIM uses the anionic polymeri2ation of nylon-6 to carry out polymeri2ation in the mold. A commercial process involves the production of block copolymers of nylon-6 and a polyether by mixing molten caprolactam, catalyst, and polyether prepolymer, and reacting in a mold (27,28). 

The major uses of aniline are in the manufacture of polymers, mbber, agricultural chemicals, dyes and pigments, pharmaceuticals, and photographic chemicals. Approximately 67% of the wodd production of aniline is used in the manufacture of rigid polyurethanes and reaction-injection-molded (RIM) parts for the constmction, automotive, and durable goods industries. 

Fig. 19. Typical injection molding and reaction injection molding (RIM) machines (a) injection molding machine for thermoplastics (b) reaction injection molding machine, showing A, the closed position, where reagents circulate, and B, the open position, where reagents are mixed and dispensed to mold.

The largest segment of the CASE family of polyurethanes are elastomers. Cast polyurethane elastomers reached a new dimension when high pressure impingement mixing led to reaction injection molding (RIM). This technology is used widely in the automotive industry, and reinforced versions (RRIM) and stmctural molded parts (SRIM) have been added in more recent years. 

Poly(dicyclopentadiene). The development of polydicyclopentadiene [25038-78-2] for reaction injection molding is an area which has generated much interest. The polyDCPD is obtained via metathesis polymerization of high purity (usually greater than 98%) DCPD. Excellent reviews (61—62) of the chemistry and properties of polyDCPD have been pubHshed. The patent Hterature of polyDCPD synthesis, catalysts, modifiers, and appHcations is dominated by Hercules (44 patents) and B. F. Goodrich (43 patents) in the U.S. Other participants are Orkem, SheU, Nippon Zeon, and Teijin. 

Reaction-Injection Molding and Reactive Casting. Reaction-iajection molding (RIM) (22) and reactive casting (23) have been demonstrated on nylon-6, which is polymerized by catalytic ring opening and linear recondensation of S-caprolactam (qv) (24). 

C. W. Macosko, Fundamentals of Reaction Injection Molding, Hanser, New York (1989). 

Reaction injection molding (RIM) describes [27-29] the process whereby two liquid reactants are rapidly mixed... 

C. F. Johnson, Resin Transfer Molding and Structural Reaction Injection Molding in Engineering Materials Handbook, Vol. 2, ASM, International, USA (1988). 

F. R. Jones, Reinforced Reaction Injection Molding, Handbook of Polymer Fibre Composites, (F. R. James, ed.). Polymer Science and Technology Science, New York (1994). 

F. M. Sweeney, Introduction to Reaction Injection Molding, 2nd Ed., Technomic Publishers, Westport (1990). 

Injection Molding Extrusion Blow Molding Thermoforming Reaction Injection Molding Rotational Molding Compression and Transfer Molding Matched Mold Spray-up... 

Important are behaviors associated and interrelated with plastic materials (thermoplastics, thermosets, elastomers, reinforced plastics, etc.) and fabricating processes (extrusion, injection molding, blow molding, forming, foaming, reaction injection molding, etc.). They are presented so that the technical or non-technical reader can readily understand the interrelationships. 

Open-cast molding Fiber spinning Blow molding Injection molding Extrusion/pultrusion Reaction injection molding... 

RCM. See Ring-closing metathesis (RCM) Reaction by-products, removing, 83 Reaction extrusion, 204 Reaction index, 237 Reaction injection molding (RIM), 205 Reaction-in-mold (RIM) nylon, 149 Reaction kinetics, 76, 77 Reaction mechanisms, polyesterification, 66-69... 

Rigid insulation foam, 206 Rigid isocyanurate foams, 226 RIM. See Reaction injection molding (RIM)... 

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