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Reactant in chemical reactions

Because electrons are neither products nor reactants in chemical reactions, the two processes are interdependent and neither can occur alone. The zinc metal dissolution must furnish electrons for the copper metal plating. The reaction of zinc and copper sulfate solution is a spontaneous reaction involving a transfer of electrons, i.e., is a spontaneous redox process. The spontaneity of the reaction is commonly explained by saying that zinc loses electrons more readily than copper or, alternatively, that Cu2+ ions gain electrons more readily than Zn2+ ions. [Pg.625]

The term substrate in biological reaction is equivalent to the term reactant in chemical reaction. [Pg.9]

Stoichiometry is the quantitative study of products and reactants in chemical reactions. Stoichiometric calculations are best done by expressing both the known and unknown quantities in terms of moles and then converting to other units if necessary. A limiting reagent is the reactant that is present in the smallest stoichiometric amount. It limits the amount of product that can be formed. The amount of product obtained in a reaction (the actual yield) may be less than the maximum possible amount (the theoretical yield). The ratio of the two is expressed as the percent yield. [Pg.98]

Numbers of atoms, use of subscripts, 257 Numbers of reactants in chemical reactions, 264 Numerals... [Pg.229]

Stoichiometry is the quantitative study of products and reactants in chemical reactions. Stoichiometric calculations are best done by expressing both the known and unknown quantities in terms of moles and then converting to other units if necessary. [Pg.61]

Another, purely experimental possibility to obtain a better estimate of the friction coefficient for rotational motion in chemical reactions consists of measuring rotational relaxation times of reactants and calculating it according to equation (A3,6,35) as y. =... [Pg.820]

A number of different experimental methods may be used to energize the unimolecular reactant A. For example, energization can take place by the potential energy release in chemical reaction, i.e. [Pg.1007]

This idea—that each molecular substance has a characteristic heat content—provides a good explanation of the heat effects found in chemical reactions. Chemists symbolize heat content by H. Since the heat effect in a reaction is the difference between the U s of the products and the H s of the reactants, the heat of reaction is called AH, the Greek letter A (delta) signifying difference. We can see what AH means in terms of an example. Consider reaction (/) ... [Pg.110]

Just as mass and energy must be conserved, so also must electrical charge. Yet free electrons are not found stable in nature under the conditions of chentistry on earth, so caimot appear as reactants or products in representations of chemical reactions. Example 11 is a half-equation , something that represents a common pattern in chemical reactions, but only occms when coupled to another suitable half-equation (i.e., this reduction process must be paired with an oxidation process that releases electrons), e.g. [Pg.93]

Equation (1.24) is arguably the most important result in chemical reaction engineering. It shows that the concentration of a reactant being consumed by a first-order batch reaction decreases exponentially. Dividing through by Oq gives the fraction unreacted,... [Pg.12]

Some of the most important information about a mechanism comes from experiments that determine how fast a chemical reaction occurs under various conditions. In chemical reactions, amounts of reactants and products change, so reaction rates are given in units of amount per unit time for example, molecules per second. Amounts also can be expressed as concentrations, so rates can be measured in units of concentration per unit time for example, molar per minute. [Pg.1054]

The alternative method is continuous-flow , in which the reactants flow through the detection coil during data acquisition. Continuous-flow NMR techniques have been used for the direct observation of short-lived species in chemical reactions [4—6]. The main difference between stopped- and continuous-flow NMR is that in the latter the sample remains inside the detection coil only for a short time period, termed the residence time, x [7], which is determined by the volume of the detection cell and the flow rate. The residence time alters the effective relaxation times according to the relationship in Eq. (2.5.1) ... [Pg.124]

The role of reactant vibrational energy in bimolecular reactions is one of the oldest and most fundamental topics in chemical reaction dynamics.161,162 For simple three-atom systems, the concept of early and... [Pg.268]

Thus, free valence persists whenever an atom or a radical undergoes a unimolecular reaction or interacts with valence-saturated molecules (possessing an even number of electrons). This is a natural consequence of conservation of the number of electrons in chemical reactions. Therefore, free valence cannot persist when a radical reacts with a radical. Both reactants have an odd numbers of electrons, and the product formed has an even number of electrons, for example,... [Pg.53]

Concept Solvent molecules associate with reactants, intermediates, and products as well as transition structures in chemical reactions. A high reaction rate and desired selectivity are accessible only in a suitable environment that facilitates the selective formation of a... [Pg.14]

For turbulent reacting flows, we are usually interested in chemical reactions involving multiple scalars. As for a single scalar, a histogram can be constructed from multiple scalar fields (Fig. 1.9). For example, if there are two reactants A and B, the samples will be bi-variate ... [Pg.39]


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