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5-Pyrazolones, 3-amino— from acids

First, 1 2 metal complexes of (mainly mono-) azo dyes, without sulfonic or carboxylic acid groups, and trivalent metals (see Section 3.11). The metals are preferably chromium and cobalt nickel, manganese, iron, or aluminum are of lesser importance. Diazo components are mainly chloro- and nitroaminophenols or amino-phenol sulfonamides coupling components are (3-naphthol, resorcinol, and 1-phe-nyl-3-methyl-5-pyrazolone. Formation of a complex from an azo dye and a metal salt generally takes place in the presence of organic solvents, such as alcohols, pyridine, or formamide. An example is C.I. Solvent Red 8, 12715 [33270-70-1] (1). [Pg.296]

In the stepwise synthesis of the unsymmetrical complex dye 13 [ 70236-60-1] [10], the azo dye made from diazotized l-amino-2-hydroxy-5-nitrobenzene and 1-phenyl-3-methyl-5-pyrazolone and the 1 1 chromium complex obtained from 6-nitro-l-diazo-2-hydroxynaphthalene-4-sulfonic acid and 2-naphthol are heated together at 80 °C for 5 h. The adduct is salted out with NaCl. A black powder is obtained that dyes wool and leather in dark brown shades. The resulting colors are fast, particularly on shrink-resistant wool. [Pg.308]

Sulfonation of pritnuline-like color bases by the baking process yields sulfonic acids whose azo dye derivatives are more fast to light than those from sulfonic acids prepared in the ordinary way. It is assumed that in the baking process, the sulfo group enters ortho to the amino group, and that this increases the light fastness. This same principle was mentioned in connection with the pyrazolone dyes. [Pg.436]

In mordant dyes, phenols, naphthols, and enolizable carbonyl compounds, such as pyrazolones, are generally the couplers. As a rule, 2 1 metal complexes are formed in the afterchroming process. A typical example of a mordant dye is Eriochrome Black T (18b) which is made from the important dyestuff intermediate nitro-l,2,4-acid, 4-amino-3-hydroxy-7-nitro-l-naphthalenesulfonic acid [6259-63-8]. Eriochrome Red B [3618-63-1] (49) (Cl Mordant Red 7 Cl 18760) (1,2,4-acid — l-phenyl-3-methyl-5-pyrazolone) is another example. The equilibrium of the two tautomeric forms depends on the nature of the solvent. [Pg.437]


See other pages where 5-Pyrazolones, 3-amino— from acids is mentioned: [Pg.205]    [Pg.162]    [Pg.36]    [Pg.416]    [Pg.1408]    [Pg.473]    [Pg.335]    [Pg.709]   
See also in sourсe #XX -- [ Pg.13 , Pg.271 ]




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