Polymer Portland cement concrete curing

PIC is a precast and cured portland cement concrete that has been impregnated with a monomer that is subsequently polymerized in situ. This type of cement composite is the most developed of polymer-concrete products. PCC, on the other hand, is a modified concrete in which a part (10%-15% by weight) of the cement binder is replaced by a synthetic organic polymer. It is produced by incorporating a monomer, prepolymer-monomer mixture, or a dispersed polymer (latex) into a cement-concrete mix. To effect the polymerization of the monomer or prepolymer-monomer, a catalyst (initiator) is added to the mixture. The process technology used is very similar to that of conventional concrete. So, unlike PIC which has to be used as a precast structure, PCC can be cast-in-place in field applications. PC can be described as a composite that contains polymer as a binder instead of the conventional portland cement. 

Other tertiary recycling processes that have been developed include a Freeman Chemical Corp. process to convert PET bottles and film to aromatic polyols used for manufacture of urethane and isocyanurates. Glycolized PET, preferably from film, since it is often lower in cost than bottles, can be reacted with unsaturated dibasic acids or anhydrides to form unsaturated polyesters. These can then be used in applications such as glass-fiber-reinforced bath tubs, shower stalls, and boat huUs. United States companies that have been involved include Ashland Chemical, Alpha Corp., Ruco Polymer Corp., and Plexmar. Unsaturated polyesters have also been used in polymer concrete, where the very fast cure times facilitate repair of concrete structures. Basing polymer concrete materials, for repair or precast applications, on recycled PET reportedly leads to 5 to 10 percent cost savings and comparable properties to polymer concrete based on virgin materials. However, they are still approximately 10 times the cost of portland cement concrete. There appears to be little commercial application of these processes at present. 

Polymer concrete is a composite material formed by polymerising a monomer and aggregate mixture. There is no other cementitious material present in it. PPCC (or LMC) is a Portland cement concrete produced usually by replacing a specified portion of the mixing water with a latex (polymer emulsion). It can also be produced by adding a monomer to fresh concrete with subsequent in situ curing and polymerisation. PIC is a hardened Portland cement concrete with impregnated monomer which is polymerised in situ. 

PPCC mixtures are Portland cement concrete mixtures to which polymer latexes have been added during the mixing process. Hardening of the polymer occurs simultaneously with the curing of concrete thus forming a continuous polymer network throughout the concrete [11, 16]. 

Polymer concretes are those in which polymers are either impregnated in hardened concrete, incorporated in the mix, or replace portland cement. Impregnated polymers can double compressive strength and elastic modulus, decrease creep, and improve resistance to freezing and thawing. They are used in concrete road surfaces. Polymers added to the mix are used for resurfacing roads. They hasten cure time. Polymer concretes in which a... 

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