Poly injection moulding

The main application of poly (vinyl formal) is as a wire enamel in conjunction with a phenolic resin. For this purpose, polymers with low hydroxyl (5-6%) and acetate (9.5-13%) content are used. Similar grades are used in structural adhesive (e.g. Redux) which are also used in conjunction with phenolic resin. Poly(vinyl formal) finds some use as a can coating and with wash primers. Injection mouldings have no commercial significance since they have no features justifying their use at current commercial prices. 

Poly(vinyl acetal) itself is now of little commercial importance. The material may be injection moulded but has no particular properties which merit its use. It is occasionally used in conjunction with nitrocellulose in lacquers, as a vehicle for wash primers and as a stiffener for fabrics. 

The average molecular weight of most bulk polymerised poly(methyl methacrylates) is too high to give a material which has adequate flow properties for injection moulding and extrusion. 

The properties of three types of poly(methyl methacrylate) (sheet based on high molecular weight polymer, lower molecular weight injection moulding material and a one-time commercial copolymer) are given in Table 15.1. 

Unlike other water-soluble resins the poly(ethylene oxide)s may be injection moulded, extruded and calendered without difficulty. The viscosity is highly dependent on shear rate and to a lesser extent on temperature. Processing temperatures in the range 90-130°C may be used for polymers with an intrinsic viscosity of about 2.5. (The intrinsic viscosity is used as a measure of molecular weight.)... 

The hydrophilic/hydrophobic SIN composition of PDMS with poly(HEMA) and poly(AAC) were proposed as a potential apphcation for high-permeability soft contact lenses. Other sUicone-containing IPNs for contact lenses include polymerization of MMA in the presence of polymerized methacryloxypropyl trimethoxysilane, the cross-linking of a polymeric hydrogel of a copolymer of NVP during the final compression or injection-moulding process. 

Torres, N., Robin, J. J. and Boutevin, B., Study of thermal and mechanical properties of virgin and recycled poly(ethylene terephthalate) before and after injection moulding, Eur. Polym. J., 36, 2075-2080 (2000). 

To facilitate and accelerate folding and crystallization of polymer chains, internal plasticizers are often added to PET to serve as crystallation promoters. Such additives are usually based on poly(ether ester)s. These plasticizers are liquids that are typically added at levels of 2-4 wt%. They reduce cycle time in injection moulding operations by increasing the rate of crystalline formation. They also plasticize the resin and act as processing aids by virtue of their lubricating action in the melt. On a molecular level, these plasticizers reduce the intermolecular... 

Poly(butylene terephthalate) (PBT) is a semicrystalline, thermoplastic polyester which is completely analogous to PET except that it has a longer, more flexible butylene chain linkage which imparts a rapid crystallization rate, thus making PBT well suited to injection moulding processes. This polyester is used widely for electrical and electronic components due to its high temperature resistance and good electrical properties (Chapter 8). 

ISO 580 1990 Injection-moulded unplasticized poly(vinyl chloride) (PVC-U) fittings -Oven test - Test method and basic specifications ISO 727-1 2002 Fittings made from unplasticized poly(vinyl chloride) (PVC-U), chlorinated poly (vinyl chloride) (PVC-C) or acrylonitrile/butadiene/styrene (ABS) with plain sockets for pipes under pressure - Part 1 Metric series ISO 727-2 2002 Fittings made from unplasticized poly(vinyl chloride) (PVC-U), chlorinated poly (vinyl chloride) (PVC-C) or acrylonitrile/butadiene/styrene (ABS) with plain sockets for pipes under pressure - Part 2 Inch-based series ISO 1163-1 1995 Plastics - Unplasticized poly(vinyl chloride) (PVC-U) moulding and extrusion materials - Part 1 Designation system and basis for specifications ISO 1163-2 1995 Plastics - Unplasticized poly(vinyl chloride) (PVC-U) moulding and extrusion materials - Part 2 Preparation of test specimens and determination of properties ISO 1265 1979 Plastics - Polyvinyl chloride resins - Determination of number of impurities and foreign particles... 

ISO 8361-2 1991 Thermoplastics pipes and fittings - Water absorption - Part 2 Test conditions for unplasticized poly(vinyl chloride) (PVC-U) pipes and fittings ISO 9393-2 1997 Thermoplastics valves - Pressure test methods and requirements - Part 2 Test conditions and basic requirements for PE, PP, PVC-U and PVDF valves ISO 9852 1995 Unplasticized poly(vinyl chloride) (PVC-U) pipes - Dichloromethane resistance at specified temperature (DCMT) - Test method ISO 9853 1991 Injection-moulded unplasticized poly(vinyl chloride) (PVC-U) fittings for pressure pipe systems - Crushing test... 

Working with a solution is needed for polymers which above their melting point would degrade (example aromatic polyamide fibres such as Kevlar and Twaron). For fibres the removal of the solvent is not too problematic. In e.g. injection moulding applications solvents caimot be used here thermotropic LCP s have to be used. Since these would degrade during processing, they are diluted by copolymerisation (example poly-hydroxy-benzoic acid - co - PETP)... 

Fig. 13.11. Injection-moulded poly(methylmethacrylate) PMMA( pmma = 4.5 GPa) with spherical PMMA-rabber inclusions ( rubber <0.1 GPa) (a, c) AFM (b, d) UFM different scan sizes (Porfyrakis et al. 2001).

The dithiocarbamates have the pentacoordinate binuclear structure (44). The diamyl- and diethyl-dithiocarbamate complexes have been found to inhibit the hardening of asphalt, but the effect appears too weak to be useful.127 The latter complex is an effective antioxidant for polyethylene,128 polypropylene,129 polystyrene,130 poly(methyl methacrylate)130 and an isoprene-styrene copolymer.131 The di-n-butyldithiocarbamate complex is important in the vulcanization and injection moulding of rubber,132 as a stabilizer against photolytic and thermal degradation. 

Unplasticized poly(vinyl chloride) compositions can be extruded in transparent, translucent, or opaque forms—to give (as examples), film, flat or corrugated sheet, and profiles such as gutters, downpipes, and troughs. For uses such as pipework the extruded products may be fixed or joined with fittings injection moulded from the same or similar material. 

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