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Poly film support

These blends can take a number of different forms. The added resin may be reacted with the epoxy resin, or it may be included as an unreacted modifier. The modifier may be blended into a continuous phase with the epoxy resin (epoxy alloys) or precipitated out as a discrete phase within the epoxy resin matrix (as is generally done in the case of toughening modifiers). Epoxy hybrid adhesives are often used as film (supported and unsupported) or tape because of the ease with which formulated systems can be dissolved into solvent and applied to a carrier or deposited as a freestanding film. Some systems, notably epoxyurethanes and epoxy-poly sulfides, can be employed as a liquid or paste formulation because of the low-viscosity characteristics of the components. [Pg.123]

One can see from Figure 5.7 that depressions of the Tg of approximately 35 K have been reported for the supported films. It is important to note, however, that in other systems, such as poly(methyl methacrylate) (PMMA), when the polymer and substrate have strong interactions, the Tg value increases. Figure 5.8 shows results for the Tg of PMMA and PS films supported on substrates having different interaction... [Pg.200]

The thiophene family of conducting polymers offers unique flexibility for tailoring of polymer properties as a result of the ease of functionalization of the parent monomer, i.e., an ester-functionalized organic solvent-soluble polythiophene [poly-octanoic acid 2-thiophen-3-yi-ethyi ester) changing the properties of PTh and resulting from post-polymerization hydrolysis of the ester linkage. The polymer films supported the proliferation and differentiation of both primary and... [Pg.248]

Nanofiltration is closely related to RO in that both technologies are used to separate ions from solution. Both NF and RO primarily use thin-film composite, polyamide membranes with a thin polyamide skin atop a poly-sulfone support (see Chapter 4.2.2.2). [Pg.390]

Chlorine-resistant aromatic polyamide-based reverse-osmosis films are manufactured by treatment of polysulfone film supports with a solution of chlorosulfonic acid in acetic anhydride for 2-10 hours, followed by soaking the film in polyamide and poly (acid chloride) solutions, and finally baking at 100... [Pg.249]

In 2002, the effect of film thickness on the physical aging rate of spin-cast poly (iso-butyl methacrylate) (PiBMA) films supported on silicon substrates was... [Pg.60]

While the v-a plots for ionized monolayers often show no distinguishing features, it is entirely possible for such to be present and, in fact, for actual phase transitions to be observed. This was the case for films of poly(4-vinylpyri-dinium) bromide at the air-aqueous electrolyte interface [118]. In addition, electrostatic interactions play a large role in the stabilization of solid-supported lipid monolayers [119] as well as in the interactions between bilayers [120]. [Pg.556]

The aim of this paper is to report the bonding of heparin on poly(ethylene terephthalate) films containing an acrylic hydrogel (pHEMA), the method of preparation of the support material and some of its properties. [Pg.230]

We now report that in the region of the absorption band the flow linear dichroism of a solution of 1 is positive (Fig. 3). Assuming that the nature of the flow orientation is of the usual kind, i.e., that the polymer chains in a random coil conformation which dominates in solution (34) tend to align with the flow direction, this observation provides additional support for the absolute assignment of the transition moment direction along the chain direction, even in solution. Similar conclusions based on polarization studies on a stretched film of poly(di-n-hexyl silane) have recently been reported (36). [Pg.66]

Figure 4 shows the application (6) of potentials to the Pt and Au electrodes of the sandwich (vs. a reference electrode elsewhere in the contacting electrolyte solution) so that they span the E° of the poly-[Co(II/I)TPP] couple (Fig. 4B). There is a consequent redistribution of the concentrations of the sites in the two oxidation states to achieve the steady state linear gradients shown in the inset. Figure 4C represents surface profilometry of a different film sample in order to determine the film thickness from that the actual porphyrin site concentration (0.85M). The flow of self exchange-supported current is experimentally parameterized by applying Fick s first law to the concentration-distance diagram in Fig. 4B ... Figure 4 shows the application (6) of potentials to the Pt and Au electrodes of the sandwich (vs. a reference electrode elsewhere in the contacting electrolyte solution) so that they span the E° of the poly-[Co(II/I)TPP] couple (Fig. 4B). There is a consequent redistribution of the concentrations of the sites in the two oxidation states to achieve the steady state linear gradients shown in the inset. Figure 4C represents surface profilometry of a different film sample in order to determine the film thickness from that the actual porphyrin site concentration (0.85M). The flow of self exchange-supported current is experimentally parameterized by applying Fick s first law to the concentration-distance diagram in Fig. 4B ...
The formation of IBVE-aMeSt block polymers was further supported by results of film-casting experiments (12). These data also show that the starting quasiliving poly(IBVE) dication is sufficiently reactive to initiate effectively subsequent aMeSt polymerization. [Pg.226]

Cast with water soluble polymer from an aqueous solution. Poly(vinyl alcohol) is a suitable inert matrix for supporting bilayer membranes [37], Water solubility of the films composed with poly(vinyl alcohol) can be lowered by coating with celluloseacetate [38] and closs-linking of polymer [39]. [Pg.76]

Porat et al. performed TEM (zero-loss bright field) studies of very thin Nation films that were cast from ethanol/water solutions, and some of the conclusions are as follows. It was suggested that the backbone had a planar zigzag conformation in large orthorhombic crystallites as in polyethylene, in contrast with the helical conformation found in poly(tetra-fluoroethylene). This is an interesting result, although there are no other studies that support this view. Sulfur imaging indicated the presence of sulfonate clusters that are 5 nm in size. [Pg.317]


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See also in sourсe #XX -- [ Pg.369 ]




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