Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Polarisation elliptical

Figure 2.58 Schematic representation of the generation of elliptically polarised tight riu the reflect ion of plane-polarised light from a reflective surface. Figure 2.58 Schematic representation of the generation of elliptically polarised tight riu the reflect ion of plane-polarised light from a reflective surface.
Figure 2.59 The path followed by the tip of the electric vector of elliptically polarised light. ES, (1 and ,. ref show the directions of the planes of the S-potarised and P-polarised light. For... Figure 2.59 The path followed by the tip of the electric vector of elliptically polarised light. ES, (1 and ,. ref show the directions of the planes of the S-potarised and P-polarised light. For...
The spectmm from an undulator is very different, and numerous peaks result from interference effects within the undulator. When the electron acceleration is confined to the orbit plane and the emission angle very low, the radiation is strongly elliptically polarised and, in the orbit plane itself, it is to within a few per cent linearly polarised. Use of a sequence of permanent magnets with magnetisation arranged in a spiral sequence enables circularly polarised radiation to be extracted from such a helical undulator and this radiation is particularly important for magnetic studies. [Pg.236]

H[ is the operator of the relative kinetic energy of the nuclei, H is a correction to the kinetic energy of the electrons, is a mass polarisation correction and // denotes the reduced mass of the nuclei. The explicit expression for H R) in terms of elliptic coordinates is given in Ref(Kolos and Wolniewicz, 1964). In the BO approximation the term is neglected. [Pg.176]

For each sample two sets of measurements were performed, using geometry 1 and 2, respectively. Only measurements made in geometry 1 will be described here [21]. The time resolved rotation (or ellipticity) and reflectivity signals were simultaneously recorded for different orientations of the pump quarter wave plate. In this paper, only the polarisation response on time scales of a few hundreds of femtoseconds is discussed. The rise of a transient reflectivity response with much longer relaxation time was used here only to verify the zero time delay position. [Pg.211]

Plane-polarised radiation is obtained when the phase factor a is equal to 0 or n and E = E. When a = 0, Ex and Ez are in phase, whilst for a = n they are out-of-phase by n. The special case illustrated in figure 1.2 corresponds to E = 0. Other forms of polarisation can be obtained from equations (1.6). For elliptically-polarised radiation we set a = n/2 so that equations (1.6) become... [Pg.5]

The anisotropy itself may be linear or circular, or a combination of both. In linear anisotropy the refractive index depends on the direction of polarised light. It is found in solid polymers under tension and in viscous polymeric liquids during flow (shear and elongation). The refractive index can also depend on the chirality of polarised light in this case one speaks of circular or elliptic anisotropy. Thus the so-called "optical activity" is circular birefringence its extinction analogue is circular dichroism. [Pg.289]

A nematic liquid crystal of negative dielectric anisotropy is aligned with the director aligned orthogonal to the cell walls by means of a surfactant orientation layer, see Figure 3.4. One or two linear, elliptical or circular polarisers are... [Pg.54]

In order to suppress the formation of elliptically polarised light rather than plane polarised light in a TN-LCD, it is necessary to control the cell thickness, d, and the birefringence of the nematic medium. An, with respect to the wavelength of light in a vacuum, X, according to the equation ... [Pg.62]

The super birefringent effect (SBE-LCD) reported by Scheffer and Nehring from Brown Boveri in Baden, Switzerland, uses the optical interference of two normal, elliptically polarised modes of transmitted light generated by a high-tilt, highly-twisted nematic structure viewed between two polarisers set in an unusual way, i.e. the input polarisation direction is not parallel to the nematic director at either substrate surface and the polarisers are not crossed at 90°, see Figure 3.10. [Pg.88]

The major difference between the configuration of the OMI sandwich cell and other STN-LCDs is that the optical path difference (5 = And 1 pm) is much lower. There is no requirement for a significant pretilt (0 < 0 < 5°), the twist angle of the chiral nematic layer is lower (180°), the front polariser is parallel to the nematic director (a = 0°) and the polariser and analyser are crossed (P = 90°). The 180° twist gives rise to strong interference between the two elliptically polarised rays. If the optical path difference is small, e.g. 0.4 m, a bright, white, non-dispersive off-state is produced. The chiral nematic mixture should be of positive dielectric anisotropy, low birefringence and exhibit a low cell gap to pitch ratio dip 0.3). [Pg.91]

A consequence of this is that drcularly polarised light becomes elliptically polarised as two components of differing intensity are combined (Figure 7-16). This effect is called circular dichroism and it is represented by the elliptirity 0, which is defined as... [Pg.258]

Modern CD instrumentation measures the difference in absorbance of right-add left-handed circularly polarised light directly, so CD spectra are often reported as As, with units the same as for s itself. Sometimes, however, for historical reasons, the circular dichroism of a sample is recorded as ellipticity. The origin of the term lies in the fact that if one of the circularly polarised beams emerging from the sample is attenuated relative to the other, on recombination the two circularly polarised beams form elliptically polarised light, not plane polarised light. The ellipticity 0, is tan (Z / ) where b is the minor and a the major axis of the ellipse. The conventional molar ellipticity [9]... [Pg.191]

Due to the difference between the absorption coefficients a+(i/) and a (v), we have an ellipticity angle for initially plane-polarised radiation Due to the difference between the refractive indices +(v) and (v), we have a rotation angle of plane-polarised radiation ... [Pg.125]

Decomposition of spectrum into 5 components (fig. 6) has been carried out since XRD analysis allows to identify 5 different locations of P atoms. Moreover the low intensity peak B near -23 ppm is highly enhanced by cross polarisation which is obviously due to the proximity of protons as hydroxyl groups or water molecules. XRD pattern analysis allowed us to locate water dimers within the elliptical channels as shown in fig. 7. The broad peak A at = -20 to - 23 ppm was observed to be part of the spectrum and was assigned to an amorphous AIPO4 phase. [Pg.34]

Elliptical multipole wiggler, producing circularly polarised X-rays. [Pg.115]

Ellipticity can be induced in a linearly polarised state either by trans-... [Pg.428]

Fig. 1. The electric vector of light passing through a bi-refringent material, with n, = 1.10 and ny = 1.15. The light is initially polarised at 45° to the x,y directions. The two perspective views show the progressive induction of ellipticity within the material. Fig. 1. The electric vector of light passing through a bi-refringent material, with n, = 1.10 and ny = 1.15. The light is initially polarised at 45° to the x,y directions. The two perspective views show the progressive induction of ellipticity within the material.

See other pages where Polarisation elliptical is mentioned: [Pg.33]    [Pg.72]    [Pg.521]    [Pg.874]    [Pg.204]    [Pg.206]    [Pg.206]    [Pg.210]    [Pg.220]    [Pg.220]    [Pg.319]    [Pg.62]    [Pg.87]    [Pg.87]    [Pg.89]    [Pg.90]    [Pg.112]    [Pg.114]    [Pg.407]    [Pg.339]    [Pg.40]    [Pg.46]    [Pg.254]    [Pg.319]    [Pg.79]    [Pg.623]    [Pg.487]    [Pg.843]    [Pg.131]    [Pg.400]    [Pg.428]   
See also in sourсe #XX -- [ Pg.57 ]




SEARCH



Elliptic

Ellipticity

Polarisability

Polarisable

Polarisation

Polariser

© 2024 chempedia.info