Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Point statistics

Assumption 4 There is no systematic association of the random error for any one data point with the random error for any other data point. Statistically this is expressed as Correlation ( , 8 ) = 0. For u, V = 1, 2,. . . n, u V,... [Pg.175]

LDV is the traditional method using tracer particles to measure velocity and one-point statistics of turbulent properties [2]. It is still a very useful technique and has the advantage that it can measure closer to walls compared to PIV. An inherent problem with LDV is that it does not measure at a specific point but rather at places... [Pg.332]

Table 5.9 summarises the main features of FTIR spectroscopy as applied to extracts (separated or not). Since many additives have quite different absorbance profiles FTIR is an excellent tool for recognition. Qualitative identification is relatively straightforward for the different classes of additives. Library searching entails a sequential, point-by-point, statistical correlation analysis of the unknown spectrum with each of the spectra in the library. Fully automated analysis of... [Pg.315]

History. Starting from the ID point statistics of Zernike and Prins [116] J. J. Hermans [128] designs various ID statistics of black and white rods. He applies these models to the SAXS curves of cellulose. Polydispersity of rod lengths is introduced by distribution functions, / , (,r)108. Hermans describes the loss of correlation along the series of rods by a convolution polynomial . One of Hermans lattice statistics is namedparacrystalby Hosemann [5,117]. Hosemann shows that the field of distorted structure is concisely treated by the methods of complex analysis. A controversial subject is Hosemann s extension of ID statistics to 3D [63,131,227,228],... [Pg.190]

As can be seen from Table 1, the estimated coefficients b[0] are not equal to zero for different samples, whereas the estimated coefficients b[l] are close to 1 within confidence interval. That means that coefficients b[0] estimated for different points of the territory are generalized relative characteristics of elements abundance at the chosen sampling points. Statistical analysis has confirmed that hypotheses Hi and H2 are true with 95% confidence level for the data obtained by any of the analytical groups involved. This conclusion allowed us to verify hypothesis H3 considering that the estimated average variances of the correlation equation (1) are homogeneous for all snow samples in each analytical group. Hypothesis H3... [Pg.143]

Chapter 2 reviews the statistical theory of turbulent flows. The emphasis, however, is on collecting in one place all of the necessary concepts and formulae needed in subsequent chapters. The discussion of these concepts is necessarily brief, and the reader is referred to Pope (2000) for further details. It is, nonetheless, essential that the reader become familiar with the basic scaling arguments and length/time scales needed to describe high-Reynolds-number turbulent flows. Likewise, the transport equations for important one-point statistics in inhomogeneous turbulent flows are derived in Chapter 2 for future reference. [Pg.15]

Note that evaluating the correlation functions at r = 0 yields the corresponding one-point statistics. For example, Rap(0, t) is equal to the scalar covariance W,/prp). [Pg.89]

Owing to the complexity of multi-point descriptions, almost all scalar transport models for complex flows are based on one-point statistics. As shown in Section 2.1, one-point turbulence statistics are found by integrating over the velocity sample space. Likewise,... [Pg.99]

In general, given /u, (V, Ve x, f), transport equations for one-point statistics can be easily derived. This is the approach used in transported PDF methods as discussed in Chapter 6. In this section, as in Section 2.2, we will employ Reynolds averaging to derive the one-point transport equations for turbulent reacting flows. [Pg.100]

In contrast to moment closures, the models used to close the conditional fluxes typically involve random processes. The choice of the models will directly affect the evolution of the shape of the PDF, and thus indirectly affect the moments of the PDF. For example, once closures have been selected, all one-point statistics involving U and 0 can be computed by deriving moment transport equations starting from the transported PDF equation. Thus, in Section 6.4, we will look at the relationship between (6.19) and RANS transport equations. However, we will first consider the composition PDF transport equation. [Pg.268]

The transported PDF equation contains more information than an RANS turbulence model, and can be used to derive the latter. We give two example derivations U) and (uuT below, but the same procedure can be carried out to find any one-point statistic of the velocity and/or composition fields.25... [Pg.271]

A more precise definition would include conditioning on the random initial velocity and compositions /li, , x Uo,. o.Y Vb XIY), V o, y 0- However, only the conditioning on initial location is needed in order to relate the Lagrangian and Eulerian PDFs. Nevertheless, the initial conditions (Uo, o) for a notional particle must have the same one-point statistics as the random variables U(Y, to) and (V. to). [Pg.307]

Statistics for the secondary or planted forests (about 180,(HK) grid points), Statistics for the 29 monitoring stations. [Pg.507]

This third body amplitude" hypothesis is strengthened by a study that confirms the agreement between point statistics and the model even when o > 1 and is under further investigation. Consequently, it is advisable that the model only be applied to a chromatogram in which the baseline o < 1. The quantity o = m/n is, however, a priori an unknown since the mean component... [Pg.25]

The results of Tables I, II and III confirm the general applicability of the peak overlap model, developed from point statistics, to randomly generated chromatograms. Individual exceptions to the model will undoubtedly be found as experimental testing Is conducted, but, overall, we anticipate modestly good predictions of m from high resolution chromatographic separations when the components are distributed randomly-... [Pg.26]

History. Starting from the ID point statistics of Zernike and Prins [116] J. J. Hermans [128] designs various ID statistics of black and white rods. He applies these models to the SAXS curves of cellulose. Polydispersity of rod lengths is introduced by distribution functions, Hermans describes the loss of corre-... [Pg.175]

Note that evaluating the correlation functions at r = 0 yields the corresponding one-point statistics. For example, Rap(0, t) is equal to the scalar covariance Like the velocity spatial correlation function discussed in Section 2.1, the scalar spatial correlation function provides length-scale information about the underlying scalar field. For a homogeneous, isotropic scalar field, the spatial correlation function will depend onlyonr = r, i.e., R,p(r, t). The scalar integral scale and the scalar Taylor microscale... [Pg.70]

Only for an isothermal, first-order reaction where Sa = —k a will the chemical source term in (3.102) be closed, i.e., ++(<+ = h (u,(pa). Indeed, for more complex chemistry, closure of the chemical source term in the scalar-flux transport equation is a major challenge. However, note that, unlike the scalar-flux dissipation term, which involves the correlation between gradients (and hence two-point statistical information), the chemical source term is given in terms of u(x, t) and 0(x, t). Thus, given the one-point joint velocity, composition PDF /u,chemical source term is closed, and can be computed from... [Pg.84]

If 0 x, t) were known, then all one-point statistics of U and 0 would also be... [Pg.242]

For most researchers, the ethics approval process is a daunting path. The successful ethics application starts with a well-written protocol and document control. ICH E6 Section 6 recommends a list of topics that are fundamental for most research (ICH, 1996). A well-written protocol following a template snch as background, trial objective, trial design, end-point, statistics and ethics will make the completion of an ethics application form effortless. [Pg.103]


See other pages where Point statistics is mentioned: [Pg.129]    [Pg.425]    [Pg.196]    [Pg.48]    [Pg.51]    [Pg.63]    [Pg.75]    [Pg.103]    [Pg.171]    [Pg.261]    [Pg.314]    [Pg.48]    [Pg.99]    [Pg.261]    [Pg.2593]    [Pg.32]    [Pg.44]    [Pg.56]    [Pg.152]    [Pg.418]    [Pg.73]    [Pg.379]   
See also in sourсe #XX -- [ Pg.27 ]




SEARCH



Point defects statistical thermodynamics

Point estimation, statistics

Population, statistical data points

Spatial point statistics

Statistics data points

The Statistical Point of View on Solid Phase Reactions

© 2024 chempedia.info