Plutonium processing markets

The fission product and encapsulation plant (FPCE) to be built by Isochem, Inc.y in Washington state will produce fully encapsulated fission products for the commercial market. Among these, all of which are extractable from Hanford s plutonium process residues, is cesium-137, a 600-kv. gamma emitter of interest to the process irradiation industry. Isochem will offer cesium in large production quantities and low cost to irradiators of foods, woods, chemicals, etc. Its 30-year half-life promises economies in source array replenishment to compensate for decay. Cesium thus becomes an economic contender for current and planned irradiation applications. 

By-Products. The PUREX process is efficient at separating uranium and plutonium from everything else in the spent fuel. Within the high level waste stream are a number of components which have, from time to time, been sufficiendy interesting to warrant their recovery. The decision to recover a particular isotope is usually based on a combination of market incentives and desired waste reduction. 

In 1985, after the Electricitee d France (EDF) decision to recycle its plutonium in their 900-MW pressurized water reactor (PWR) plants, it appeared that a large commercial market was building up for MOX fabrication for light water reactors (LWRs). Therefore, Belgonucleaire simultaneously decided to increase its production capacity up to 35 t of heavy metals (HM)/year and also to change its fabrication process in order to meet the commercial and technical requirements of the customers. 

Some countries, e.g., France, Japan, Russia, and the United Kingdom have chosen to reprocess their spent nuclear fuel to recycle uranium and plutonium as nuclear fuel and to obtain a high active waste (HAW) firaction that is less radiotoxic than the spent fuel itself. In this process, very high separation factors are necessary. The fission product activity has to be reduced by a factor of > 10 and the separation factor between uranium and plutonium must be at least 2 x lO. All full-scale reprocessing processes are based on solvent extraction, and today the plutonium uranium redox extraction (PUREX) process dominates the market completely. 

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