Bis platinate

Platin Bis-f1-propinyl]-bis-[triethyl-arsauo]-iodo-trifluoromethyl-Xlll/9a, 843 (F,C — 1 + L2PlR2)... [Pg.702]

Platin Bis-[triethylpliosphan]-bromo-(4-lluoro-phenyl)- XH1/ 9a. 792 (4-F - l-Br-benzol 1 L2Pt)... [Pg.724]

Platin Bis-[dimethyl-phcnyl-phosphan]-diethinyl-iodo-trifluoromethyl- XIII/9a. 844 (F,G —1 — L2PtR,)... [Pg.727]

Platin Bis-[d phenyl-methyl-phosphan]-chloro-trifluoro-mcthyl- XII l/9a, 710 (FjC-CO-PtLj-CI, A)... [Pg.731]

Platin Bis-[diphcnyl-melhyl-phos-phan]-chloro-lrifluoroacetyl-Xlll/9a. 798 (F3c-ro-ci + Pii.4)... [Pg.732]

Platin Bis-[diphenyl-methyl-phos-phan]-chloro-pcntafluoroethyl-XIII/9a. 710... [Pg.732]

C4.H39F3P2PtSn Platin Bis-[triphcnylphosphan]-trifluoroelhenyl-trimethyl-stannyl- XHI/9a. 747 (F2C = CF-SnR3 + PtL3)... [Pg.733]

Platin Bis-[tricyclohexylphosphan]-hydrido-pcntafluoroplienyl-XIII/9a. 791 (C6F5H + I.2Pt)... [Pg.733]

Platin Bis-[trimethylarsan]-chloro-(l-chlor-1-propenyl)- XlII/9a,... [Pg.686]

Platinates, bis(oxalato)-, 139 cadmium complexes superstructure, 142 cobalt complexes, 140 electrical conductivity, 14] superstructure, 141 thermopower, 141 divalent cation salts, 140 iron complexes structure, 142 lead complexes superstructure, 142 magnesium complexes, 140 electrical conduction, 142 structure, 142 thermopower, 142 modulated superstructure, 139 monovalent cation salts, 139 nickel complexes structure, 141 partially oxidized, 139 Platinates, tetracyano-, 136 anion-deficient salts, 136 electrical conduction, 138 optical properties, 138 cation-deficient salts, 138 oxidation states, 136 partially oxidized, 138 semiconductors, 134 Platinum colloidal... [Pg.7210]

Thiono-l,3-dithioIan wird an Platin (—1,4 bis —1,6 V) zum Dianion III unter Athy-len-Abspaltung reduziert, das z.B. mit Methyljodid zum /,2-Bis-[methylthio-thiocarbo-nylthio]-athan (IV) bzw. mit 1,2-Dibrom- Oder 1,2-Dijod-athan zum 1,4,6,9-Tetrathia-spiro[4.4]nonan V in DMF/[(C4H9)4N]Br weiterreagiert5 ... [Pg.677]

Diphenyl-diazomethan liefert bei der Elektrolyse an Platin in DMF/Tetrabutylammo-niumperchlorat Diphenylmethan, Amino-diphenyl-methan und Benzophenon-azin. Bei hohcn negativen Potentialen (—1,9 bis —2,2 V) und niedriger Ausgangskonzentration iiberwiegt Diphenylmethan (bis 51% d.Th.) das Azin dominiert erwartungsgemaB bei... [Pg.678]

Die Elektrolyse von Benzyl-trimethyl-ammonium-nitrat an Platin liefert in Kohlendio-xid-gesattigter DMF-Losung neben Toluol bis zu 53% d.Th. Phenylessigsaure3. [Pg.679]

Die kathodische Reduktion von N,N-Dichlor-tosylamid fiihrt zum entsprechenden Ni-tren, in Gegenwart von 1,4-Dioxan entsteht neben Tosylamid (Graphit-Kathode, max. 90% d.Th.) bis zu 32% d.Th. (Platin) 2-Tosylamino-J,4-dioxan (in Acetonitril/Lithium-perchlorat)3. [Pg.697]

In Aceton/Tetrabutylammoniumperchlorat wird Bis-[dithiocarbamato]-ruthenium(III) an Platin (-0,5 V) zum Bis- dithiocarbamato]-ruthenium(II) reduziert4. Tris-[2,2 -bi-py-ridyl]-ruthenium(II) kann bei -1,42 Volt sclektiv zum entsprechenden Ruthenium(I)-, bei —1,65 zum Ruthenium(0)-Komplex reduziert werden5. [Pg.703]

Petry OA, Podlovchenko BI, Frumkin AN, Lai H. 1965. The behaviour of platinized-platinum and platinum-mthenium electrodes in methanol solutions. J Electroanal Chem 10 253. [Pg.503]

The crystal structure of the sodium salt of 30 (NAMI) is shown in Fig. 9, where Na(I) bridges two molecules of 30 via oxygens of S-bound DMSO and water. This complex may be readily reduced in vivo (E1/2, -0.001 V) (166), whereas the bis-imidazole complex 28 has a lower redox potential and is more difficult to reduce. The reduction potential of 28 is strongly pH dependent (AE = —118 mV/pH unit near pH 7), reduction being more favorable at acidic pH values (167). This complex hydrolyses at a similar rate to cisplatin (ty ca. 3 h at 310 K) and, like cis-platin, aquation appears to be necessary for DNA binding (168). [Pg.211]

Bis(trimethylphosphine)nickel(0)-acetylene complex, 3093 Potassium bis(phenylethynyl)palladate(2—), 3699 Potassium bis(phenylethynyl)platinate(2—), 3700 Potassium bis(propynyl)palladate, 2308... [Pg.93]

Potassium bis(propynyl)platinate, 2309 Potassium diethynylpalladate(2—), 1394 Potassium diethynylplatinate(2—), 1395 Potassium hexaethynylcobaltate(4—), 3446 Potassium hexaethynylmanganate(3—), 3448 Potassium tetraethynylnickelate(2—), 2896 Potassium tetraethynylnickelate(4—), 2897 Potassium tetrakis(propynyl)nickelate(4—), 3513... [Pg.93]

In addition to the partially oxidized tetracyanoplatinates, bis(oxalato)platinate-(II) can be nonstoichiometrically oxidized by chemical oxidants13 to form highly lustrous needlelike crystals containing platinum in the 2.36 oxidation state. These complexes have not been characterized to the extent of the tetracyano-platinate complexes however, the oxalato complexes are reported to be highly conducting.13 The starting material is bis(oxalato)platinate(II), which can be prepared in 30% yields from hexachloroplatinate(lV) and potassium oxalate.9... [Pg.16]

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