Pigments, surface properties

Incorporation of less than a stoichiometric amount of alkyl sulfonamides of copper phthalocyanines into copper phthalocyanine improves the pigment s properties in rotogravure inks (67). Monomeric and polymeric phthalocyanine derivatives with basic substituents adsorb strongly to the pigment surface and promote the adsorption of binder molecules (68—72). 

Pigments Aftertreatments. The surfaces of pigment particles can have different properties and composition than the particle centers. This disparity can be caused by the absorption of ions during wet milling, eg, the —OH groups, on the surface. In some cases, surfaces are modified intentionaHy to improve the pigments appHcation properties, interaction with the organic matrix, and weather resistance. 

The exceUent adhesion to primed films of polyester combined with good dielectric properties and good surface properties makes the vinyhdene chloride copolymers very suitable as binders for iron oxide pigmented coatings for magnetic tapes (168—170). They perform very weU in audio, video, and computer tapes. 

Another source of error in the investigation of the surface properties of titanium dioxide is its tendency to adsorb acids or ions. Phosphate ions are very strongly adsorbed (see Table XIX) as well as sulfuric acid. Commercial pigments often have considerable sulfate contents. When titania is precipitated from sulfate solution, sulfate ions are strongly adsorbed (308). They are carried through all further stages of pigment manufacture. 

Typical liquid systems require doses between 10 and 50 kGy. They consist of binders (prepolymers) with acrylic (H2C=CH-CO-0-) double bonds in the main chain (polymaleates and polyfumarates) and of monomers, usually acrylates used as reactive thinners. Other ingredients added to the formulation may be pigments, dyes, fillers, flatting agents, and additives to improve film and surface properties and attain the required performance criferia. ... 

Another reason for the widespread use of adsorption techniques is the importance now attached to the characterization of the surface properties and texture of fine powders such as pigments, fillers and cements. Similarly, adsorption measurements are undertaken in many academic and industrial laboratories on porous materials... 

FIGURE 10.1 The volume of suspension for a pigment (Isol Benzidine Yellow, GA-PR, 9500). Primes are used to distinguish surface properties. (O) = long time suspension ( ) = suspension for shorter times ( ) = reaction. 

The fabrication of the super alloys of today and those of the future requires improved molds, cores, and binders. Chemical processes and oil refining require catalysts with improved activity, selectivity, and mechanical properties. Classic ceramics and the new ceramics for electronic microcircuits (microelectronics) require purer and more reliable precursors and processes. Chromatographic processes require substrates with improved physical, mechanical, and surface properties. And there is an ever-increasing need of better absorbents, binders, and pigments. 

---