Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Physical constants specific heat capacity

Here, erfcjc is the eiTor function complement of jc and ierfc is its inverse. The physical properties are represented by a, the thermal dijfusivity, which is equal to lejpCp, where k is the drermal conductivity, p is the density and Cp, the specific heat capacity at constant pressure. The surface temperature during this iiTadiation, Tg, at jc = 0, is therefore... [Pg.78]

The use of the differential is important in the physical sciences because fundamental theorems are sometimes expressed in differential form. In chemistry, for example, the laws of thermodynamics are nearly always expressed in terms of differentials. For example, it is common to work with the following formula as a means of expressing how the molar specific heat capacity at constant pressure, Cp, of a substance varies with temperature, T ... [Pg.112]

The process of heat propagation in a flat homogeneous medium G with constant thermal-physical properties (p is density, c is specific heat capacity, and K is the coefficient of heat conductivity p,C,K = const > 0) is described by... [Pg.308]

If the tube walls are at an approximately constant temperature of 393 K and the inlet temperature of the water is 293 K, estimate the outlet temperature. Physical properties of water density = 1000 kg/m3, viscosity = 1 mNs/m2, thermal conductivity = 0.6 W/m K, specific heat capacity = 4.2 kJ/kg K. [Pg.307]

Polymerization entropies can be determined in several ways via the temperature dependence of the equilibrium concentrations of the monomer, via the heat capacity, via the activation constants for polymerization and depolymerization, or via an incremental calculation method. The heat capacity serves to determine the entropy of polymerization because the quotient of specific entropy and specific heat capacity, (A5 /c ) is about unity at 298 K for polymers irrespective of their constitution. False results occur if, for example, monomer association in the vapor phase occurs, or if, with polymers, there is a physical transition in the temperature range between calorimetric measurement and equilibrium measurement. [Pg.91]

The solid flow only covers zone D and some mesh elements there are blocked to the solid flow to fit the thickness of iron ore fines layer which are illustrated in Figure 1. Conservation equations of the steady, incompressible solid flow could be defined using the general equation is Eq. (6). In Eq. (6), physical solid velocity is applied. Species of the solid phase include metal iron (Fe), iron oxide (Fc203) and gangue. Terms to represent, T and 5 for the solid flow are listed in Table n. Specific heat capacity, thermal conductivity and viscosity of the solid phase are constant. They are 680 J/(kg K), 0.8 W m/K and 1.0 Pa s respectively. Boundary conditions for solid flow are Sides of the flowing down channels and the perforated plates are considered as non-slip wall conditions for the solid flow and are adiabatic to the solid phase up-surfeces of the solid layers on the perforated plates are considered to be free surfaces at the solid inlet, temperature, volume flow rate and composition of the ore fines are set depending on the simulation case At the solid outlet, a fiilly developed solid flow is assumed. [Pg.405]

The heat evolution rate per unit mass, the vent capacity per unit area, physical properties (e.g.. latent heat of liquid, specific heat, and vapor/liqnid specific volumes) are constant. It allows for total vapor-liqnid disengagement of fluids that are not natural" surface active foamers. ... [Pg.974]

The aforementioned macroscopic physical constants of solvents have usually been determined experimentally. However, various attempts have been made to calculate bulk properties of Hquids from pure theory. By means of quantum chemical methods, it is possible to calculate some thermodynamic properties e.g. molar heat capacities and viscosities) of simple molecular Hquids without specific solvent/solvent interactions [207]. A quantitative structure-property relationship treatment of normal boiling points, using the so-called CODESS A technique i.e. comprehensive descriptors for structural and statistical analysis), leads to a four-parameter equation with physically significant molecular descriptors, allowing rather accurate predictions of the normal boiling points of structurally diverse organic liquids [208]. Based solely on the molecular structure of solvent molecules, a non-empirical solvent polarity index, called the first-order valence molecular connectivity index, has been proposed [137]. These purely calculated solvent polarity parameters correlate fairly well with some corresponding physical properties of the solvents [137]. [Pg.69]

The physical property database of ICPP contains easily accessed values of molecular weights, specific gravities, phase transition points, critical constants, vapor pressures, heat capacities, and latent heats for many species that duplicate the values found in Appendix B of the text. The values retrieved from the database may be incorporated into process calculations performed using E-Z Solve. [Pg.713]

Generally, therefore, these additional functions are connected with the departures from additivity shown by the volume F, the heat capacity and the chemical constant i and the enthalpy H on dilution of the solution. They find their tangible expression in volume contractions, heat effects and anomalous behavior of specific heats. Physically they should be attributed to an excess or deficiency in attraction between the molecules of solvent and solute over the cohesion of identical molecules. Hildebrand has termed solutions in which additional entropy terms such as 2, 3 and 4 are missing, regular solutions (see p. 222). In them the excess and deficiency attractions may be related quantitatively to the heat of dilution, since in the insertion of molecules of one component between those of the other, a heat effect other than zero results because the energy necessary for the separation of identical molecules differs from that obtained in bringing together dissimilar particles. [Pg.238]


See other pages where Physical constants specific heat capacity is mentioned: [Pg.17]    [Pg.248]    [Pg.248]    [Pg.422]    [Pg.425]    [Pg.2165]    [Pg.248]    [Pg.47]    [Pg.47]    [Pg.151]    [Pg.155]    [Pg.443]    [Pg.478]    [Pg.149]    [Pg.6]    [Pg.326]    [Pg.159]    [Pg.119]    [Pg.375]    [Pg.153]    [Pg.232]    [Pg.159]    [Pg.1040]    [Pg.424]    [Pg.1383]    [Pg.62]    [Pg.211]    [Pg.171]    [Pg.758]    [Pg.1382]    [Pg.1221]    [Pg.62]    [Pg.112]    [Pg.1156]    [Pg.22]    [Pg.159]   
See also in sourсe #XX -- [ Pg.15 , Pg.20 ]




SEARCH



Constant heat capacities

Heating specific heat

Physical constants

Physical heat capacity

Specific capacity

Specific heat

Specific heat constants

Specificity constant

© 2024 chempedia.info