Photovoltaic cell fabrication

Besides ruthenium complexes, rhenium complexes were also used as the photosensitizers in photovoltaic cells. Bulk heterojunction photovoltaic cells fabricated from sublimable rhenium complexes exhibited a power conversion efficiency of 1.7%.75,76 The same rhenium complex moiety was incorporated into conjugated polymer chains such as polymer 16a c (Scheme 9). Fabrication of devices based on conjugated rhenium containing polymers 17a c and SPAN by the LbL deposition method was reported.77 The efficiencies of the devices are on the order of 10 4%. 

G. J. Vendura, Improved Thermal Control for a-Si H Photovoltaic Cells Fabricated on Polymeric Substrates, presented at 26th IEEE Photovoltaic Specialists Conference, Los Angeles, CA, USA, 1997. 

Since the first photovoltaic (PV) cells were fabricated for the U.S. space program in 1958, PV technology has evolved from once being a very high cost but essential and effective space power source to later becoming a small but diversified and enduring worldwide industry (1 6). Led by firms based in the United States, Japan, and Germany, this industry serves multiple markets (see Photovoltaic cells). 

In nonbiological applications, mixed ruthenium complexes of bipyridyl ligands and substituted pteridine diones have been used as components of photovoltaic cells <2002JPH167>. When fabricated into sol-gel processed titanium oxide electrodes, these complexes achieved photocurrent conversion efficiency in the range 20 8%. 

So-called wet solar cells show promise, particularly because of their relative ease of fabrication. In this type of photovoltaic cell, the junction is formed, between a semiconductor and a liquid electrolyte. No doping is required because a junction forms spontaneously when a suitable semiconductor, such as GaAs, is contacted with a suitable electrolyte, Three knotty problems (accelerated oxidation of surface of semiconductor exchange of ions between semiconductor and electrolyte forming a blocking layer and deposition of ions of impurities on the surface of the semiconductor) all have been solved and thus the concept now appears technically viable,... 

Nanostructure Fabrication Processes Photovoltaic Cells Nanostructured Coatings Semiconductors Nanotechnology Memory... 

Despite the extensive application of ruthenium complexes in DSSC, transition metal containing polymers have received relatively little attention in the fabrication of polymeric photovoltaic cells. Most of the early works on ruthenium containing polymers were focused on the light-emitting properties.58-60 Several examples of ruthenium terpyridine/bipyridine containing conjugated polymers and their photoconducting/electroluminescent properties were reported.61,62... 

Photovoltaic cells with the simple device structure ITO/polymer/C6o/Al were fabricated. The power conversion efficiencies of the devices fabricated... 

Photovoltaic devices based on pure 29 and 29 PCBM blend as the active layer is fabricated. It was interesting to observe that a device with pure 29 showed a higher power conversion efficiency (0.05%) compared to that consisting of a 29/PCBM blend (0.0.0024% to 0.041%). The good performance in the photovoltaic cells with 29 only was attributed to the efficient charge separation process and that the material exhibits efficient hole and electron transport. The C6o moieties facilitated that electron transport, while the holes are transported via the hopping between Pt2-thiophene units. 

The very recent breakthrough in this area focused on the fabrication of highly efficient organometallic photovoltaic cells based on 76.105 The bulk... 

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