Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Photon frequency

The argument is sometimes given that equation (Al.6,29) implies that the ratio of spontaneous to stimulated emission goes as the cube of the emitted photon frequency. This argument must be used with some care recall that for light at thennal equilibrium, goes as BP, and hence the rate of stimulated emission has a factor... [Pg.224]

In absorption spectroscopy, the attenuation of light as it passes tln-ough a sample is measured as a function of wavelength. The attenuation is due to rovibrational or electronic transitions occurring in the sample. Mapping out the attenuation versus photon frequency gives a description of the molecule or molecules responsible for the absorption. The attenuation at a particular frequency follows the Beer-Lambert law,... [Pg.805]

This problem asks if red and blue photons can cause potassium metal to lose electrons. We must analyze the energy requirements for ejection of an electron. No electrons will be ejected unless the energy of the photons exceeds some threshold value characteristic of the metal. If the photon energy exceeds this threshold value, electrons will be ejected with kinetic energy given by Equation. An important part of this problem is the conversion of photon frequency to photon energy. [Pg.446]

Fig. 25. Absorption coefficient vs. photon frequency for PITN. The data were obtained in situ during the injection part of the electrochemical doping cycle with (CI04 ) as the dopant. The cell voltages and corresponding dopant concentrations (in mol%) are indicated. Reproduced from [456b],... Fig. 25. Absorption coefficient vs. photon frequency for PITN. The data were obtained in situ during the injection part of the electrochemical doping cycle with (CI04 ) as the dopant. The cell voltages and corresponding dopant concentrations (in mol%) are indicated. Reproduced from [456b],...
Figure 9.6 Energy diagrams for tensors x(2) e, x(2) eOT and jO-),mee por (2). ) input photons (frequency to) are annihilated and output photon (frequency 2co) is created through electric dipole interactions. For x(2) ", one input photon at frequency to is annihilated by a magnetic interaction whereas other interactions occur through electric dipole mechanism. On the other hand, for X(2 ) " output photon is generated through magnetic interaction. Figure 9.6 Energy diagrams for tensors x(2) e, x(2) eOT and jO-),mee por (2). ) input photons (frequency to) are annihilated and output photon (frequency 2co) is created through electric dipole interactions. For x(2) ", one input photon at frequency to is annihilated by a magnetic interaction whereas other interactions occur through electric dipole mechanism. On the other hand, for X(2 ) " output photon is generated through magnetic interaction.
The term that depends on the third power of the frequency shift is known as third-order dispersion (TOD). When a TL pulse acquires a significant amount of TOD, the pulse envelope is distorted and a series of sub-pulses is produced, as shown in Figure 8.1. Unlike a pulse with SOD, a pulse with TOD leads to two-photon excitation with the same efficiency as a TL pulse but only for a particular two-photon frequency. At other frequencies, the amount of excitation is suppressed. The control over TOD would allow for preferential excitation in different spectral regions, while its correction would lead to efficient two-photon excitation over the whole accessed spectral range. Unfortunately, measuring and correcting TOD is not a simple task. [Pg.199]

Figure 7.10 The probability ratio for spontaneous versus stimulated emission as a function of photon frequency. The extreme left curve corresponds to a 100 K case, the extreme right to a 1000 K case, where the two middle traces represent biological range. (See Colour Plate VIII)... Figure 7.10 The probability ratio for spontaneous versus stimulated emission as a function of photon frequency. The extreme left curve corresponds to a 100 K case, the extreme right to a 1000 K case, where the two middle traces represent biological range. (See Colour Plate VIII)...
We present exact calculations of the two-photon transition rates between discrete states of the non relativistic Hydrogen atom and we compare these results with those obtained with various approximation schemes. We plot in Fig. 1 the ls-3s resonant transition amplitude as a function of one of (he photon frequencies [3], where... [Pg.870]

Table 2. Two-photon transition amplitude Dj for ls-3s transitions in Hydrogen for three different values of the incident photon frequency in the length and velocity gauges JQ and J respectively, D[J0, N]... Table 2. Two-photon transition amplitude Dj for ls-3s transitions in Hydrogen for three different values of the incident photon frequency in the length and velocity gauges JQ and J respectively, D[J0, N]...
Indicate reaction conditions and catalysts over and under the arrow in a smaller type size. The Greek capital letter delta indicates heat hv indicates light, where h is Planck s constant and the Greek letter nu is the photon frequency. [Pg.272]

The X-ray singularity problem was originally solved in the asymptotic limit and the complicated many-body problem was turned into an effective one-particle problem (219). For the X-ray photon frequency threshold frequency (o0, the absorption spectrum g(m) for the process in which a deep, structureless core electron is excited to the conduction band by the absorption of an X-ray of frequency w is expressed by the power law... [Pg.214]

In fact, direct reduction of Pb(II) to Pb(0) by a bielectronic process has been reported imder laser irradiation, where due to the high photonic frequency, accumulation of electrons may allow multielectronic injection (Rajh et al., 1996a, b Thumauer et al., 1997). [Pg.56]

The energy carried by a photon is hv = hdX, where h is Planck s constant, v the photon frequency, c the speed of light, and A the photon wavelength. For a photon to just excite an electron across the band gap, this energy must be equal to that band gap energy. Eg = 1.94 X 10 J, where... [Pg.919]

The wavenumber represents radiation energy, as does wavelength. As we know, electromagnetic waves can be considered as photons. The photon energy is related to the photon frequency... [Pg.254]


See other pages where Photon frequency is mentioned: [Pg.393]    [Pg.288]    [Pg.330]    [Pg.523]    [Pg.264]    [Pg.226]    [Pg.203]    [Pg.309]    [Pg.95]    [Pg.31]    [Pg.141]    [Pg.21]    [Pg.214]    [Pg.313]    [Pg.16]    [Pg.33]    [Pg.118]    [Pg.9]    [Pg.77]    [Pg.185]    [Pg.419]    [Pg.420]    [Pg.330]    [Pg.84]    [Pg.50]    [Pg.423]    [Pg.183]    [Pg.156]    [Pg.6332]    [Pg.423]    [Pg.293]    [Pg.301]    [Pg.41]    [Pg.4]    [Pg.2]    [Pg.8]   
See also in sourсe #XX -- [ Pg.473 ]




SEARCH



© 2024 chempedia.info