Phosphorus 583 suppl

The dimer (PH )2, its monocation, and the protonated species will be covered in the forthcoming Phosphorus Suppl. Vol. C 2. 

Supplement to Mellor s Comprehensive Treatise on Inorganic and Theoretical Chemisty, Vol. VIII, Suppl. Ill, Phosphorus, Longman Group Ltd., London, 1971, pp. 172-173. 

Mcllor s Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. fi. Suppl. 3. Phosphorus, l,ongman, London, l97l, 1467 pp. 

Allcock HR. Controlled synthesis of organic-inorganic polymers that possess a backbone of phosphorus and nitrogen atoms. Makromol Chem, 1981, (Suppl 4), 3-19. 

Mellor, 1941, Vol. 2, 292 1956, Vol. 2, Suppl. 1, 380 1943, Vol. 11, 26 Liquid chlorine at —34°C explodes with white phosphorus, and a solution in heptane at 0°C ignites red phosphorus. Boron, active carbon, silicon and phosphorus all ignite in contact with gaseous chlorine at ambient temperature. Arsenic incandesces on contact with liquid chlorine at —34°C, and the powder ignites when sprinkled into the gas at ambient temperature. Tellurium must be warmed slightly before incandescence occurs. 

Phosphorus tribromide Mellor, 1971, Vol. 8, Suppl. 3, 521 Interaction is vigorously exothermic. 

Melnick, R.L. Tomaszewski, K.E. (1990) Triethanolamine. In Buhler, D.R. Reed, D.J., eds, Ethel Browning s Toxicity and Metabolism ofIndustrial Solvents, Vol. II, Nitrogen and Phosphorus Solvents, Amsterdam, Elsevier, pp. 441-450 Morin, R.J. Lim, C.T (1970) Inhibition in vitro of incorporation of [ P]-phosphate into rabbit and human endometrial phospholipids. J. reprod. Fert., 23, 456-462 Mortelmans, K., Haworth, S., Lawlor, T., Speck, W., Tainer, B. Zeiger, E. (1986) Salmonella mutagenicity tests II. Results from the testing of 270 chemicals. Environ, mol. Mutag., 8 (Suppl. 7), 1-119... 

Ishida M et al Management of calcium, phosphorus, and bone metabolism in dialysis patients using sevalamer hydrochloride and vitamin D therapy. Ther Apher Dial 2005 9(Suppl 1) S16. 

Phosphorus trichloride Mellor, 1956, Vol. 2, Suppl. 1, 502 Reaction is intensely exothermic. 

Frevert, T. 1979. The pe redox concept in natural sediment-water systems its role in controlling phosphorus release from lake sediments. Arch. Hydrobiol. Suppl. 55, 278-297. 

Peterson TC, Isbrucker RA, Martinka M. 1991. Collagen estimation in the yellow phosphorus induced pig model of liver disease. Clin Invest Med 14(4 suppl) A64. 

Song Z, Lu Y, Gu X. 1985. Treatment of yellow phosphorus skin bums with silver nitrate instead of copper sulfate. Scand J Work Environ Health 1 l(Suppl. 4) 33. 

Kolowith, L. C., Ingall, E. D., and Benner, R. (2001). Composition and cycling of marine organic phosphorus. Limnology and Oceanography (Suppl) 309—320. 

J. R. Van Wazer, Phosphorus and Its Compounds, Vol. I Chemistry, Interscience Publishers, New York, 1958 also see J. E. Such, in Mettor s Inorganic and Theoretical Chemistry, Wiley-Interscience, New York, 1971, Vol. VIII, Suppl. Ill, p. 717 and D. C. E. Corbridge, Phosphorus, An Outline of Its Chemistry, Biochemistry and Technology, 2nd ed., Elsevier Scientific Publishing Company, Amsterdam, 1980, Ch. 3. 

Tetrachlorotetramethylphosphonium chloride, (CH2C1)4PC1.— Tetrahydroxytetramethylphosphonium chloride and phosphorus penta-chloride react when boiled together for four hours in carbon tetrachloride solution to give the tetrachloro-compound. It consists of white crystals, M.pt. 192° to 193° C., readily soluble in water, but not hygroscopic. In alcohol it is readily soluble, sparingly soluble in ethyl acetate, chloroform and carbon tetrachloride. The dry compound is Hofmann, Annahn Suppl, 1861, i, 177 Phil Trans., 1860, 150, 449. 

Sodium hydroxide reacts with trichloroethylene, forming explosive mixtures of dichloroacetylene. When heated with phosphorus pentoxide, a violent explosion can result (Mellor 1946, Suppl. 1971). Phosphorus boiled with caustic soda solution can produce phosphine, which ignites spontaneously in air. Amphoteric metals such as aluminum, zinc, and tin react with sodium hydroxide, generating hydrogen, which may form explosive mixtures in air. 

Suppl. 67). Laboratory fires have been reported, cansed by contact of moisture with a potassium bromate, malonic acid, and cerinm ammoninm nitrate mixtnre, setting a high exothermic reaction (Bartmess et al. 1998). Bromates ignite when mixed with concentrated mineral acids, lead acetate, or phospho-ninm iodide, PH4I. Finely divided mixtures of bromates with finely divided metals, phosphorus, sulfur, or metal sulfides can explode when heated or subjected to friction (Mellor 1946). 

Phosphorus particulates in air is adsorbed onto Tenax in a solid sorbent tube, desorbed by xylene. The eluant is injected into a GC equipped with a flame photometric detector using a 3% OV 101 Chromosorb W-HP column (NIOSH 1984, Suppl. 1987, Method 1905). Analysis of phosphorus in flue gases from incineration using a quartz fiber filter and different collecting impingers has... 

Phosphorus pentoxide is a nonflammable compound and does not support combustion. It reacts violently with water and alcohol. Reaction with water produces phosphoric acid, H3PO4. When heated with caustic soda or potash or calcium oxide, the reaction can be extremely violent (Mellor 1946, Suppl. 1971). Explosion may occur when perchloric acid solution in chloroform is added to phosphorus pentoxide (NFPA... 

The heat of reaction may decompose phosphorus acid to phosphine, which may ignite spontaneously or explode. It is decomposed by alcohols, producing alkyl halides. The reactions of phosphorus trichloride with acetic acid, nitric acid, nitrous acid, and chromyl chloride can produce explosions. It may ignite or react violently with dimethyl sulfoxide, lead dioxide, fluorine, hydroxyl amine, and iodine monochloride (Mellor 1946, Suppl. 1948 NFPA 1997). Its vapors bum to incandescence when heated with alkali metals. 

---