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Phenylallyl alcohol

Siloxanes 1 (R = Me, Ph synthesized from 3-phenylallyl alcohol and dimethyl- and diphenyldichlorosilane, respectively) on photolysis afforded one cyclobutane product, the all-p-am-isomer 2, in almost quantitative yield.2 Photolysis of 3-phenylallyl alcohol under the same conditions resulted in very little cyclobutane formation. [Pg.109]

Triflic acid is also efficient in the alkylation of electron-rich aromatics (anisole, 1,3-dimethoxybenzene, 2-methylfurane, pyrrole, benzofurane, indole) with secondary benzylic alcohols and 3-phenylallyl alcohols (50°C, 1-9 h, 66-95% yield).201 Benzene, toluene, and halobenzenes are also alkylated with hydroxy-biindantetraone 53 in triflic acid within 1-2h202 [Eq. (5.78)]. Suprisingly, however, the primary products (with the exception of the 4-methylphenyl-substituted compound) undergo rearrangement upon prolonged treatment to yield alkenes... [Pg.561]

Phenylacetaldehyde dimethyl acetal, d450 yV-Phenylacetamide, al 8 Phenylacetone, pi 44 2-Phenylacetoacetonitrile, a51 cu-Phenylacetophenone, d22 /3-Phenylacrylic acid, c267 y-Phenylallyl alcohol, c270 (9-Phenylanisole, m56... [Pg.337]

SYNS CINNAMIC ALCOHOL CINNAMYL ALCOHOL, SYNTHETIC FEMA No. 2294 y-PHENYLALLYL ALCOHOL 3-PHENYLALLYL ALCOHOL 3-PHENYL-2-PROPEN-1-OL STYRONE STYRYL CARBINOL... [Pg.371]

The reaction is even more efficient for 2-phenylallyl alcohol (eq 51) and particularly its copolymers, yielding the oligomer with a terminal aldehyde, 106. [Pg.547]

Arcus and Strauss sought to convert 1-phenylallyl alcohol (3) into the dibromide (5) by reaction with bromine in chloroform, carbon tetrachloride, or carbon disulfide buf absorption of bromine virtually stopped when 0.6-0.7 equivalent of bromine had been added, and the only product isolated was 1,2,3-tribromo-l-phenylpropane,... [Pg.487]

Beilstein Handbook Reference) AI3-00949 Alkohol skoricovy BRN 1903999 CCRIS 3191 Cinnamic alcohol Cinnamyl alcohol EINECS 203-212-3 FEMA No. 2294 3-Fenyl-2-propen-1-ol HSDB 5011 NSC 8775 Peruvin 3-Phenylallyl alcohol o-Phenylallyl alcohol Phenyl-2-propen-1-ol 1-Phenylprop-1-en-3-ol 3-Phenyl-2-propen-1-ol 3-Phenyl-2-propenol 2-Propen-1-ol, 3-phenyl- 2-Propen-yl-ol, 3-phenyl- Propenoic xid, 3-phenyl-, (trans)- Styrone Styryl alcohol Styryl carbinol Zimtalcohol. Used in perfumery and in deodorants. Crystals mp = 33-35° bp 249-250° dJJ = 1.0397 soluble in H2O, organic solvents. [Pg.148]

Synonyms cas 104-54-1 cinnamic aldehyde cinnamaldehyde 3-phenyl propenal 3-phenylallyl alcohol... [Pg.93]

As mentioned already in the polymerization of meth of-phenylacrylate a steri-cally random pdymer was obtained. However, the fraction of heterotactic triad in the polymer did not exceed 50 % under any polymerization conditions with BuLi Initiator (Table 10). On the other hand, methyl a-(p-bromophenyl)acrylate and methyl ce-(p-chlorophenyl)acrylate gave the polymers whose heterotactic contents were 59 and 61 %, respectively, in THF by BuLi at -78 (Table 10). The tacticity was determined by the C-NMR spectra of poly(2-phenylallyI acetate)s derived from the original polymers via pdy(2-phenylallyl alcohol)s. The bulkiness of the o-substituent seems to be important for the heterotactic propagation in these cases, as pointed out by Nozakuia et al. in the formation of heterotactic poty(vinyl alcohol) derived from poly(vinyl trimethylsilyl ether). However, method o-phenylacrylate formed a heterotactic pdymer whose heterotactic content was 66 %, by octylpotassium in THF (Table 10),... [Pg.28]

Synonyms Cinnamic alcohol 3-Phenylallyl alcohol y-Phenylallyl alcohol 3-Phenyl-2-propenol 3-Phenyl-2-propen-1-ol Styrone Styryl alcohol Styryl carbinol... [Pg.956]

Phenylallyl alcohol y-Phenylallyl alcohol. See Cinnamyl alcohol... [Pg.3308]

Synonyms cinnamyl alcohol 3-phenyl-2-propen-i-ol Styrone y-phenylallyl alcohol Styrylcarbinol phenyl-2-propenol phenylallyl alcohol... [Pg.1204]

Phenylpropanoid Aldehydes (Phenylacryl Aldehydes), Phenylpropanoid Alcohols (Phenylallyl Alcohols), Phenylpropenes... [Pg.278]

Poly(l,4-pentadiene-alt-MA), 343, 348, 586 Poly(phenanthrene-alt-MA), 376, 660 Poly(phenylacetylene), MA grafted, 471 Poly(phenylacetylene-co-MA), 335, 660 Poly(2-phenylallyl alcohol-alt-MA), 331, 660 Poly(4-phenyl-l-butene-alt-MA), 340, 341 Poly(/- 1-phenylethyl methacrylate-co-MA), optically active polymer, 383 Poly(/-1-phenylethyl vinyl ether-alt-MA), optically active polymer, 383 Poly(5-phenyl-l-pentene-alt-MA), 340, 341 Poly( l-phenyl-4-pentene- 1-one-alt-MA), 314 Poly(3-phenyl propene-l-alt-MA), 341 Poly(o-phenylstyrene-alt-MA), 373 Poly(2-phenylvinyl alkyl ethers-alt-MA), 318 Poly(2-phenylvinyl alkyl thioethers-alt-MA), 318 Poly(phenyl vinyl ether-alt-MA), 318, 394 Poly(phenyl-o-vinyl formal-alt-MA), 328 Poly(phenyl vinyl ketone-co-MA), physical properties, 290... [Pg.861]

See other pages where Phenylallyl alcohol is mentioned: [Pg.862]    [Pg.295]    [Pg.648]    [Pg.648]    [Pg.1835]    [Pg.1835]    [Pg.508]    [Pg.559]    [Pg.723]    [Pg.972]    [Pg.155]    [Pg.131]    [Pg.135]    [Pg.136]    [Pg.136]    [Pg.358]    [Pg.433]    [Pg.434]    [Pg.434]    [Pg.434]    [Pg.131]    [Pg.135]    [Pg.136]    [Pg.136]    [Pg.132]    [Pg.132]    [Pg.132]    [Pg.133]    [Pg.134]    [Pg.134]    [Pg.311]   
See also in sourсe #XX -- [ Pg.3 , Pg.93 ]



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