2- phcnyl phenyl

Benzyl-diethoxy- E2, 134 Benzyl-diisopropyloxy- E2, 134 Benzyl-ethyl-phenyl- -tosylimid E2, 113 Benzyl-methyl-phenyl- -tosylimid E2, 113 Benzyloxy-diphenyl- E2, 17, 18 Benzyloxy-ethoxy-hydroxy- E2, 187 Bis-[2-biphenylyl]- E2, 876 [2,6-bis-(2-tetrahydropyranyloxy-methyl)-phenyl]-Bis-[4-brom-anilino]-phenyl- E2, 416 Bis-[2-brom-ethoxy]-(2-brom-ethyl)- E2, 196 Bis-[butylthio]-ethyi- E2, 79, 408 Bis-[2-chlor-cthoxy]-butyl- E2, 196 Bis-[2-chlor-ethoxy]-(2-chlor-ethyl)- E2, 196 Bis-[2-chlor-ethoxy]-methyl- E2, 196 Bis- 2-chlor-ethoxy]-phenyl- E2, 196, 197, 202 Bis- 2-ehlor-ethoxy]-(2-phcnyl-vinyl)- E2, 196 Bis-(2-ehlor-ethoxy]-vinyl- E2, 196 Bis-j 2-chlor-ethyl]-methyl- E2, 205 Bis-[chlormethyl]-dodecyl- E2, 22 Bis-12-cyan-ethyl]- E2, 223 Bis- diethylamino]-butyl- E2, 486 Bis-[ l-cthinyl-butyl]-phenyl- E2, 197 Bis-[ethoxycarbonyl-methyl]-chlor- E2, 251 Bis-[ethylthio]-ethyl- E2, 408 Bis-[4-methoxy-aniliiio]-phenyl- E2, 416 Bis-[4-methyl-phenylJ-phenyl- K2, 105 Bis- 4-methyl-phcnyl]-phenyl- -phenylsulfonvlimid E2, 105... 

In contrast to its reaction with methyllithium, jV,Af-diethyl-5-phcnyl-3//-azepin-2-amine (1) with butylithium undergoes 4,5-addition to give 4-butyl-A, V-diethyl-5-phenyl-4,5-dihydro-3/7-azepin-2-amine (2)38. 

In asymmetric Strecker synthesis ( + )-(45,55 )-5-amino-2,2-dimethyl-4-phenyl-l,3-dioxane has been introduced as an alternative chiral auxiliary47. The compound is readily accessible from (lS,25)-2-amino-l-phcnyl-l,3-propancdioI, an intermediate in the industrial production of chloramphenicol, by acctalization with acetone. This chiral amine reacts smoothly with methyl ketones of the arylalkyl47 or alkyl series48 and sodium cyanide, after addition of acetic acid, to afford a-methyl-a-amino nitriles in high yield and in diastereomerically pure form. 

For reactions with S, specificity is found to decrease in the series cyanoisopropyl mcthyl Fbutoxy>phcnyl>bcnzoyloxy. Cyanoisopropyl (Scheme 3.3),7 f-bntoxy and methyl radicals give exclusively tail addition. Phenyl radicals afford tail addition and ca l% aromatic substitution. Benzoyloxy radicals give tail addition, head addition, and aromatic substitution (Scheme 3.4). ... 

Allyl-(2-methyl-phenyl)-ather AllyI-(2-chlor-phcnyl)-ather Allyl-naphthyl-( l)-ather Benzyl-naphthyl-(2)-ather... 

Benzylchlorid 1-Chlor- l-phenyl-athan Chlor-diphenyl-methan Dichlor-phcnyl-mcthan D ichlor- diphenyl- methan 3-Chlor-2-methyl-propen... 

Phenyl-vinyl)-pyridin bzw. Phcnyl-propargylsaure-methylestcr. 

Phcnyl-3-(2-hydroxylamino-phenyl)- 698 2-Phenyl-3-(4-methyl-phenyl)- 553... 

Brom-l-allyloxy- 401 2-Brom-l-[cyclopenten-(3)-yl]- 401 2-Brom-l-oxo-l-(4-brom-phenyl)- 308, 503, 510 2-Brom-l-oxo-l,2-diphenyI- 569 2-Brom-l-oxo-l-phenyl- 396, 492, 503, 533, 621 2-Brom-l-phcnyl- 389, 520... 

Methyl-phenyIthio)-(4-nitro-phenyl)- 700 (2-Nitro-phcnyl)-(2-hydroxy-5-methyl-phenyl)- 693 (2-Nitro-phenyl)-(4-methoxy-phenyl)- 693 (2-Nitro-phenyl)-(4-methyl-phenyl)- 693 Phenyl-(4-amino-phenyl)- 568 Ph en yl-(4-formyl-phenyl) -... 

N-Diphenylmethylen- 374 N-Diphenylmethylen-O-aminocarbonyl- 612 N-[l,3-Diphenyl-propyl-(2) - 374 N-[l,3-Diphenyl-propyliden-(2)]- 374, 377, 380 N-(4-Halogen-phenyI)- 683 N-Heptyl- 375 N-Heptyl-N-acetyl- 376 N-Heptyliden- 375 N-Hcptyliden-O-acetyl- 376 0-(2-Hydroxy-athyl)-N-athoxycarbonyl- 133 N-(4-Hydroxy-phenyl)- 683 0-(2-Hydroxy-l-phenyl-athyI)-N-athoxycarbonyI-aus 0-(ci-AthoxycarbonyI-benzyl)-N-athoxycar-bonyl-hydroxylamin und Lithiumalanat 133 N-Isopropyl- 682 N-Isopropylidcn- 613 N-Methyl- 133, 682 O-Methyl-N-bcnzyliden- 377 O-Methyl-N-benzyliden- 375 0-Methyl-N-(4-chlor-benzyl)- 375 0-Methyl-N-(4-chlor-benzyliden)- 375 N-Methy -N,0-diacetyI- 682 N-(4-Methyl-phenyl)- 683 0-McthyI-N-( 1 -phenyl-athyliden)- 375 N-(4-Methylthio-phenyl)- 684 N-(4-Nitro-benzyl)- 374 N-[4-Nitro-benzyliden - 374, 377 N-(2-Nitro-phenyl)- 562 N-(4-Nitro-phenyl)- 682 N-Nitroso-N-cyclohexyl- 697 N-Octyl- 374 N-Octyl-(2)-N-acetyl- 376 N-Octyliden- 374 N-0ctyliden-(2)-0-acctyl- 376 N-(Pentafluor-phenyl)-0,N-diacetyl- 697 N-Phenyl- 474, 481, 682, 783 N-Phenylacetyl-O-benzoyl- 265 N-(l-Phenyl-athyl)- 374 N-(l-Phenyl-athyl)-N-acetyl- 376 N-(l-Phenyl-athyliden)-374, 613 N-( l-Phenyl-athyliden)-0-acetyl- 376 N-[ 1 -Phenyl-buten-( 1 )-yl-(3)-iden]- 582 N-f4-Phenyl-butyl-(2)-iden]- 581 N-Phcnyl-N,0-diacetyl- 682 N-(4-Phenylthio-phenyl)- 684 N-Propyl-N-cyclohexyl- 376 N-Propyl-N-isopropyl- 376 O-Sulfonyl- 481 N-(4-Sulfonyl-phenyI)- 683 N-(2-Vinyl-phenyl)- 698... 

Nitro-cyclohexyl- 372 Nitro-phenyl- 372 Phenoxy-phcnyl- 601 Pheny[-(4-benzoylamino-phenyl)-... 

Phenyl-(4-chlor-phenyl)- 542 Phenyl-(4-fluor-phenyI)- 410 PhenyI-[4-(3-hydroxy-butyl)-phenyl]- 296 Phenyl-(2-hydroxymethyI-phcnyl)- 229 Phenyl-(4-hydroxymethyI-phenyl)- 324 PhenyI-(2-hydroxy-phenyl)- 159 Phenyl-(3-methoxy-phenyl)- 410 Phenyl-(4-mcthyl-phenyI)- 410 Phenyl-naphthyl-(l)- 411 Phenyl-[4-(3-oxo-butyl)-phenyl]- 296 Phenyl-pyridyI-(2)- 492 Phenyl-(2,4,6-trimethyI-phenyl)- 411 Triaryl- 561 Trideutero-... 

Phenyl- -methylester 193f. 2-Phcnyl-3-(4-methyI-phenyI)- -nitril 553... 

Brom-397, 400, 402, 510, 512, 520 3-(2-Brom-athoxy)- 401 3-Brom-l-phcnyl- 580 3-Chlor- 512, 672 3-ChIor-2-benzyl- 401 3-Chlor-2-methyl- 401 3-ChIor-2-methyl-l -phenyl- 401... 

AthyI-(4-amino-phcnyl)- 684 Athyl-benzyl- 500 Bis-[4-brom-phenyI]- 572 Bis-[4-chlor-phenyl]- 488 Bis-[4-hydroxy-phenyl]- 572 Bis-14-methoxy-phenyl]- 572 Bis-[4-methyl-phenyl]- 572 Bis-[4-nitro-phenyl]- 572 a-Brom- 534f. 

Chlor-2,4-diamino- -1-oxid 502 6-Chlor-4-dichlormethyl-2-phenyl- 618 6-Chlor-4-mcthoxy-2-phenyl- 595 6-Chlor-4-methyl-2-phcnyl- 595 6-Chlor-4-trichlormethyl-2-phenyl- 618... 

Methoxy-4-methyl-3-oxo-2-phenyl-3,4-dihydro-5,8-quinoxalinequinone 6-Methoxy-1 -methyl-3-phcnyl-2(l //)-quinoxalinone... 

Treatment of an epimeric mixture of 4-substituted 2-(trimethylsilyloxy)-5-phenyl-3-phenylthio-l,4-oxazine 363 with ZnBr2 led to the stereoselective formation of perhydropyrido[2,l-c][l,4]oxazine 365 via the iminium ion 364 the phenyl-bearing stereocenter-directed addition of the olefinic double bond from the P-face of the cyclic moiety <1997SL799, 1998T10309>. Similarly, an epimeric mixture of (4A, 9a.S )-l -tnmcthylsilyloxyM-phcnyl-3,4,6,7-tetra-hydropyrido[2,1 / 1,4]oxazinc was prepared by cyclization of (Z)-5(A)-phenyl-3-phenylsulfanyl-2-trimethylsilyloxy-... 

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