Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Perfluoroalkanoic acid

Reduction of perfluoroalkanesulfonyl halides leads to sulfinic acids, which are unstable in aqueous acid and give perfluoroalkanoic acids [75] (equation 16) A variety of reducing agents can be used... [Pg.427]

Esters 8 of perfluoroalkanoic acids and perfluorinated or highly fluorinated alcohols react with the sulfur tetrafluoride/hydrogen fluoride mixture without cleavage to give high yields of perfluorinated or highly fluorinated ethers 9.164-165... [Pg.373]

Iron (23-25). Ultrasound-promoted reactions were also applied to the syntheses and rate enhancements of fluorinated compounds such as perfluoroalkyl iodides in the presence of zinc and carbon dioxide to give perfluoroalkanoic acids (26,27). [Pg.290]

Electrochemical oxidation of perfluoroalkanoic acids can lead to radical derived products, although the same problems apply to such oxidations as applied to the electrochemical reduction processes of perfluoroalkyl iodides. [Pg.109]

Electron transfer from perfluoroalkanoic acids to xenon difluoride was also reported to give perfluoroalkyl radicals which were found to add to benzene derivatives [63]. [Pg.109]

Perfluoroalkanoic acids also undergo Hunsdiecker reactions, with the greatest utility for such methodology being the preparation of perfluoroalkyl iodides, bromides and chlorides [64]. [Pg.110]

Hunsdiecker reactions of salts of perfluoroalkanoic acids are known primarily as perhaps the best way of making perfluoroalkyl halides [58,306,307], but there have been other synthetic uses found for the perfluoroalkyl radicals which are formed by this decarboxylative process [308]. [Pg.151]

In 1957, Anderson found that perfluoroalkanoic acids dehydrocondense with Et3GeH without catalyst to give Et3GeOOCR (R = CF3, C2F5, C3F7), whereas the reaction did... [Pg.20]

Similarly, with perfluoroalkanoic acids or the corresponding anhydrides, perfluoroalkyl groups can be attached to five-membered heterocyclic systems [81JFC( 18)243] (Scheme 42). [Pg.24]

The decarboxylation of perfluoroalkanoic acids may also be achieved via the 0-acyl thiohydtoxa-mates. When carried out in the presence of electron rich alkenes such as ethyl vinyl ether the perfiuoroal-... [Pg.730]

Perfluoroalkylcopper reagents are the most studied perfluoroalkyl organometallic reagents due to their unique combination of thermal stability and chemical reactivity. They are readily prepared by copper metal insertion reactions with perfluoroalkyl halides in a coordinating solvent (e.g., formation of decarboxylation reactions of perfluoroalkanoic acid salts and copper(I) halide (e.g., formation of 2 ), or metathesis reactions (e.g., formation of 4 via 3 ). (Trifluoro-methyl)copper (4) has also been recently accessed by decomposition of methyl 2,2-difluoro-2-(fluorosulfonyl)acetate (5) or methyl perfluoro [2-(fluorosulfonyl)ethoxy]acetate (6) in the presence of copper(I) iodide and by reaction of trimethyl(trifluoromethyl)silane (7) with fluoride and copper(I) iodide. ... [Pg.468]

Reaction of Perfluoroalkanoic Acid Chlorides 14 with TViethyl Phosphite (I) Giving Diethyl (Z)-l l(Di-cthoxyphosphinyl)oxy perfluoroalk-l-enylphosphonates IS General Procedure ... [Pg.675]

A range of normal functional-group chemistry may be carried out with perfluoroalkanoic acids, little modified by the perfluoroalkyl group [2, 25, 26]. Acid chlorides are readily obtained with thionyl chloride or phosphoms chlorides and may be converted to the fluorides using potassium fluoride or, where a volatile product is obtained, by exchange with benzoyl fluoride (see Chapter 3, Section IIB) anhydrides are produced by reaction of the acid with phosphorus pentoxide [27]. To illustrate some of the chemistry of perfluoroalkanoic acids, a selection of reactions is contained in Table 8.3. [Pg.238]

Perfluoroalkanoic acid chlorides 14 react with two equivalents of triethyl phosphite (1) to afford diethyl (Z)-l-[(diethoxyphosphinyl)oxy]perfluoroalk-l-enylphosphonates 15.<,1( 2... [Pg.674]

Watanabe, H., Hashizume, Y. and Uneyama, K. (1992) Homologation of trifluoroacetimidoyl iodides by palladium-catalyzed carbonylation. An approach to a-amino perfluoroalkanoic acids. Tetrahedron Lett., 33, 4333 4336. [Pg.251]

Top antireflection coatings were first proposed by Tanaka and co-workers at Hitachi in 1990. Top antireflection coatings are typically made of perfluorinated compounds such as perfluoroalkanoic acids or PFAA, in particular, perfluoro-octanoic acid or PFOA (II), and perfluoroalkanesulfonic acids or PFAS, in particu-... [Pg.421]

Figure 10, Wettability of condensed mono-layers of perfluoroalkanoic acids by various liquids [53]... Figure 10, Wettability of condensed mono-layers of perfluoroalkanoic acids by various liquids [53]...
Perfluoroalkanoic Acids, Petfluorosulfonic Acids, and Their (Metai) Derivatives... [Pg.62]

Almost all syntheses of fluoroalkylated benzoxazoles are based on the use of ortho-aminophenols. Thus, condensation of perfluoroalkanoic acid imidates with o-aminophenol is a convenient method for preparation of 2-perfluoroalky 1-substituted benzoxazoles. 2-Trifluoromethyl- and 2-(perfluoropropyl)benzoxazoles can be synthesized by heating at 100 °C in dry dioxane, but the yield of benzoxazoles does not exceed 35 0 %. The best results are obtained by reaction of o-aminophenol with... [Pg.432]


See other pages where Perfluoroalkanoic acid is mentioned: [Pg.555]    [Pg.590]    [Pg.97]    [Pg.123]    [Pg.238]    [Pg.238]    [Pg.675]    [Pg.3054]    [Pg.3054]    [Pg.11]    [Pg.67]    [Pg.675]    [Pg.18]    [Pg.555]    [Pg.127]    [Pg.225]    [Pg.158]    [Pg.5]   
See also in sourсe #XX -- [ Pg.123 ]

See also in sourсe #XX -- [ Pg.11 ]




SEARCH



Perfluoroalkanoates

© 2024 chempedia.info