Perfluorinated organic

Perfluorinated organic bromides can be oxidatively fluonnated with elemental fluorine to derivatives containing tn- [124] and pentavalent [/25 126 127] bromine in yields up to 42% Perfluoroheptylbromine tetrafluoride has been used to fluonnate double bonds in halogenated alkenes [127]... 

Wissiack et al. 2000), estrogens and metabolites (Rodriguez-Mozaz et al. 2004), and perfluorinated organic acids and amides (Kuklenyik et al. 2005) in surface water, foods, and human sera. 

Kuklenyik Z., Needham L.L., and Calafat A.M., 2005. Measurement of 18 perfluorinated organic acids and amides in human serum using online solid-phase extraction. Anal Chem 77 6085. 

Perfluorinated inert fluids, health and safety factors related to, 11 884 Perfluorinated organic compounds, 9 678-679... 

Figure 7.3.1.8 Instrumental configuration for mass-limited characterization by microcoil NMR. The analyte is bracketed on both sides by plugs of an immiscible perfluorinated organic liquid and sealed with an optically curable glue to prevent dilution during the data-collection period...

Abe T.Nagase S (1982) Electrochemical Fluorination as a Route to Perfluorinated Organic Compounds of Industrial Interest. In Banks RE (ed) Preparation, Properties and Industrial Applications of Organofluorine Compounds. Ellis Horwood, Chichester 1 19... 

A modern development and variation of solid support is fluorous chemistry [137,138]. Fluorous chemistry is an emerging field that takes advantage of the unique physical and solubility properties of perfluorinated organic compounds. Many recent publications have underlined the special properties... 

Physical and chemical properties of perfluorinated organic solvents... 

Taniyasu, S., Kannan, K., Horii, Y., Hanari, N., Yamashita, N. A survey of perfluorooctane sulfonate and related perfluorinated organic compounds in water, fish, birds, and humans from Japan. Environ. Sci. TechnoL, 37 2634-2639 (2003). 

Gumge, K. S., Taniyasu, S., Yamashita, N., Wijeratna, S., Mohotti, K. M., Seneviratne, H. R., et al. Perfluorinated organic compounds in human blood serum and seminal plasma a smdy of urban and rural tea worker populations in Sri Lanka. J. Environ. Monitor, 7 371-377 (2005). 

The term fluorophilic is based on the observations of a fluorous biphase system [14-22], perfluorinated layers found in the liquid crystal phase [25], and a perfluorinated alkyl moiety highly aligned in the crystals of partially perfluorinated molecules. They let us imagine some unknown attraction force among the perfluorinated moieties. However, the origin of the attraction has never been explored. It is natural to understand that the perfluorinated organic molecules would be just cast aside from the van der Waals interacted organic phase. 

Today the primary goal is seeking unique approaches to studies of the effects of the perfluorinated organic moiety on the physical and chemical properties of compounds. At any level of modem development, fundamental research is stimulated by the demand for advanced materials based on new substances possessing improved properties to satisfy consumer requirements and capable of operating in relatively... 

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