Solid state oxidation states

H. Mizobuchi, T. Kawai, K. Yoshino, Ferromagnetic behavior of self-doping type polyaniline derivatives depending on oxidation state, Solid State Communications 1995, 96, 925. 

Self-propagating reduction reactions Several oxide reduction solid-state reactions have been known for a long time. Starting materials are considered which react together highly exothermically. Once the reaction is initiated, enough heat is produced for very high temperature to be attained, and complete reaction occurs rapidly. The so-called thermite process corresponds to the reactions ... 

Livage, J. 1986. The gel route to transition metal oxides. J. Solid State Chem. 64 322-30. 

Formula HIO3 MW175.93 iodine in -i-5 oxidation state solid acid contains (H0)I02 molecules joined by hydrogen bonding a monoprotic acid... 

Keywords Aluminium, Hydroxide, Oxide, Organooxide, Solid-state, Solution... 

The electrochemical reduction of nitric oxide in solid-state electrochemical cell is an interesting field surveyed in [95]. The working principle of the cells is the cathodic reduction of NO to nitrogen and oxygen anions. In [95], the properties of various types of solid-state electrochemical cells used for NO reduction are presented and discussed. It is shown that the cathode materials with a high redox capacity and oxygen vacancies are most active for the electrochemical reduction of nitric oxide, whereas noble metal-based electrodes show a much lower selectivity. As an alternative route, the promotion of the reduction with a reductive agent is also considered. 

Ratieuville Y, Wu BE, Lincot D, Vedel J, Yu LT (1999) Voltammetric and electrogravimetric study of manganese dioxide thin film electrodes. J Electrochem Soc 146 S-1-17/23. Bakardjieva S, Bezdicka P, Grygar T, Vorm P (2000) Reductive dissolution of microparticulate manganese oxides. J Solid State Electrochem 4 306-313. 

Shannon, R. D., Chenavas, J., and Joubert, J. C. (1975). Bond strength considerations applied to cation coordination in normal and high pressure oxides. J. Solid State Chem. 12, 16-30. 

To prepare the spinel oxide by solid-state reaction of a mixture of the individual metal cation oxides, the following procedure was used [8] a mixture of powdered ZnO (Aldrich >99%) and C CL (Aldrich >99%) (0.5 Zn Cr ratio), was carefully grounded for 10 minutes in order to obtain a good dispersion of the compounds in the solid mixture. This mixture was then heated at 900 °C for 12 hours in a N2 atmosphere. 

Simpson, M. J., and Hatcher, P. G. (2004). Determination of black carbon in natural organic matter by chemical oxidation and solid-state 13C nuclear magnetic resonance spectroscopy. Org. Geochem. 35, 923-935. 

Krivoruchko et al. (2001) C, iron oxide Catalytic solid state transformation, melting transitions + + n.a. Graphitization of amorphous carbon... 

Kosova N.V., Devyatkina E.T., Demsova T.A., Avvakumov E.G. Proton transfer in mechanochemical reactions of hydrated oxides. Zhurn. Neorg. Khimii 1999 44 912-16. Avvakumov E.G., Devyatkina E.T., Kosova N.V. Mechanochemical reactions of hydrated oxides. J. Solid State Chem. 1994 113 379-83. 

Goodenough, J. B. (1971). Metallic oxides. Prog. Solid State Chem. 5, 145-399. 

Wachsman, E.D., Ball, G.R., Jiang, N., and Stevenson, D.A., Structural and defect studies in solid oxide electrolytes. Solid State Ionics, 1992, 52, 213-218. 

Zhang, Y.C., Wang, H., Xu, H.Y. et ah. Low-temperature hydrothermal synthesis of spinel-type lithium manganese oxide nanocrystallites. Solid State Ionics, 158, 113, 2003. 

I. E. Wachs, J. M. Jehng, F. D. Hardcastle, The Interaction of V205 and Nh205 with oxide surfaces. Solid State Ionics, 32/33, (1989), pp. 904-910,... 

H. Deng, M. Zhou and B. Abeles, Diffusion-reaction in porous mixed ionic-electronic solid oxide membranes. Solid State Ionics, 74 (1994) 75-84. 

S. Ling, M.P. Anderson and T.A. Ramanarayanan, Optimization of ionic transport through mixed conducting oxide ceramics. Solid State Ionics, 59 (1993) 33-45. 

M.P. Dijk, K.J. de Vries, A.J. Burggraaf, A.N. Cormack and C.R.A. Catlow, Defect structures and migration mechanisms in oxide pyrochlores. Solid State Ionics, 17 (1985) 159-167. 

Sankar, G., Wright, P. A., Natarajan, S., Thomas, J. M., Greaves, G. N., Dent, A. J., Dobson, B. R., Ramsdale, C. A., and Jones, R. H. (1993). Combined Quexafs-Xrd a new technique in high-temperature materials chemistry—an illustrative in-situ study of the zinc oxide-enhanced solid-state production of Cordierite from a precursor Zeolite. J. Phys. Chem. 91, 9550-9554. 

Fig. 5. Absorption spectrum of the isolated "native" FeS-A/FeS-B protein in the oxidized state (solid curve) and in the reduced state by addition of dithionite (dashed curve). Figure source Oh-oka, Itoh, Saeki, Takahashi and Matsubara (1991) F/JFb protein from spinach photosystem t complex. Isolation In a native state and some properties of the iron-sulfur clusters. Plant Celt Physiol 32 13.

An investigation by NMR of these catalysts shows that when the ligand HONP is bonded to the support previous to the complexation with rhodium, the phosphines become oxidized ( P solid state NMR peak +29 ppm). 

Di Bartolomeo, E., Kaabbuathong, N., Grilli, M. L. and Traversa, E. (2004) Planar electrochemical sensors based on tape-cast YSZ layers and oxide electrodes. Solid State Ionics, 171 (3-4), 173-81. 

Miura, N., Lu, G., Ono, M. and Yamazoe, N. (1999) Selective detection of NO by using an amperometric sensor based on stabilized zirconia and oxide electrode. Solid State Ionics, 117 (3-4), 283—90. 

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