Oxidation, Reduction, and Related Reactions

Pulegone and menthone formed (175) and (176) respectively on autoxidation in alkaline media.329 Pulegone also underwent a conventional Baeyer-Villiger oxidation 

Liang-Liu and Y. S. Cheng, Proc. Natl. Sci. Courtc. Repub. China, 1980, 5, 21. 

Nomura, Y. Fujihara, and Y. Matsubara, J. Chem. Soc. Jpn., Chem. Ind. Chem., 1979, 305. 323 N. Nomura, Y. Fujihara, and Y. Matsubara, Nipon Nogei Kagaku Kaishi, 1978, 1182, (Chem. 

Katakawa, M. Tomita, and Y. Mizuno, Chem. Lett., 1981, 637. 

Oshima, S. Sasaki, H. Yamamoto, T. Hiyama, and H. Nozaki, Tetrahedron Lett., 1979, 4751. 

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Oxidation-reduction and related reactions of metal-metal bonds. T. J. Meyer, Prog. Inorg. Chem., 1975,19,1-50(381). 

Meyer, T. J., Oxidation-Reduction and Related Reactions of Metal-Metal Bonds 19 1... 

Meyer, T. J., Oxidation-Reduction and Related Reactions of Metal-Metal Bonds Mezaillies, Nicolas, Mathey, Erancois, and Ee Eloch, Pascal, The Coordination Chemistry of Phosphinines Their Polydentate and Macrocyclic Derivatives Michel, Sarah L. J., Hoffman, Brian M., Baum, Sven M., and Barrett, Anthony G. M., Peripherally Functionalized Porphyrazines Novel Metallo-... 

Mn " " also activates several oxidases. The role of manganese in oxidation-reduction processes of plants is its most important function, and is related to the valency change between Mn " " and Mn (Kabata-Pendias and Pendias 2001). Because of its high redox potential, manganese is the main metallic activator of enzymes in the citrate cycle and controls oxidation, reduction, and carboxylation reactions in carbohy-... 

Because the breadth of chemical behavior can be bewildering in its complexity, chemists search for general ways to organize chemical reactivity patterns. Two familiar patterns are Br< )nsted acid-base (proton transfer) and oxidation-reduction (electron transfer) reactions. A related pattern of reactivity can be viewed as the donation of a pair of electrons to form a new bond. One example is the reaction between gaseous ammonia and trimethyl boron, in which the ammonia molecule uses its nonbonding pair of electrons to form a bond between nitrogen and boron ... 

The first seven cycles of an in situ iron removal project in The Netherlands were simulated with the hydrogeochemical transport model PHREEQC (version 2). The concentration changes of CH4, NH/, Mn, Fe , P04 and As are discussed in detail. Arsenic shows concentration jumps in pumped groundwater which are related to oxidation/reduction and sorption/desorption reactions resulting from the water quality variations. 

Creyghton, E. J., Van derWaai, J. 0. Meenwein-Ponndorf-Verley reduction, Oppenauer oxidation, and related reactions. Fine Chemicals through Heterogeneous Catalysis 2001,438-448. 

Meerwein-Ponndorf-Verley Reduction, Oppenauer Oxidation, and Related Reactions... 

Biotransformation is not strictly related to detoxication, because in a number of cases the metabolites are more toxic than the parent pollutants, and in that case, the term of bioactivation or toxication is used. Metabolites may have comparable or greater toxicity in organism than the parent pollutant since during the biotransformation process functional groups are inserted into the pollutant by oxidation, reduction or hydrolysis reactions. 

Oxidative Cleavage, Reductive Coupling, and Related Reactions 1.03.4 Insertion and Elimination Reactions... 

The study aids for this chapter include key terms and concepts (which are hyperlinked to the Glossary from the bold, blue terms in the WileyPLUS version of the book at wileyplus.com) and Synthetic Connections summaries of oxidation, reduction, and carbon—carbon bond-forming reactions related to alcohol and carbonyl compounds. 

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