Oxidation agents organic oxidants

The oxidizing agent (organic peracid) usually attacks the sulfur from the less hindered side of the substrate to produce the less hindered oxidation product as a major isomer139. 

The oxidizing agent (organic peracid) usually attacks the sulfur from the less hindered side of the substrate to produce the less hindered oxidation product as a major isomer Thus, the observed stereoselectivity means the exclusive formation of the rmti-isomer (a). This conclusion was confirmed by NMR analysis (see Section III.B.4.b) and, clearly, can be extended and generalized with respect to larger cyclic sulfoxide systems. 

The probable mechanism of action for all of the stable A -halamines involves direct contact of the microorganism with the combined A -halamine, followed by donation of a Cl" or Br" species to a receptor site within the cell, causing oxidation, and subsequent cell inactivation. Once the halogen content is exhausted through reaction with reducing agents, organic impurities. 

Nitric acid is a strong oxidizing agent. Organic substances may ignite when reacted with the concentrated acid (fuming and anhydrous). Nitric acid vapour irritates the respiratory tracts. If nitric acid gets on one s skin, it causes serious... 

D.J. Trevoy, H. Johnson, J. Phys. Chem. 62 (1958) 833 (a) CB, steel surface, polished and cleaned with oxidizing agent. Organic contaminants virtually absent, (b) SD. 

BIS (AMMONIUM) PEROXO-DISULFATE (7727-54-0) HgN OgSj Aqueous solution is a medium-strong acid reaction with water produces oxygen. A powerful oxidizer. Reacts with combustible materials reducing agents organic materials, finely divided and powdered metals, with risk of fire and explosion. Mixture with sodium peroxide produces a friction-, heat-, and water-sensitive explosive. A mixture with powdered almninum and water may explode . Aqueous solution violently attacks and dissolves iron. In temperatures above 248°F/120°C releases corrosive fumes of ammoiua, nitrogen oxides, and sulfur oxides. 

ALPEROX C (105-74-8) A flammable solid (flash point <127°F/<53°C). A powerful oxidizer and organic peroxide. Violent reaction with reducing agents, organic matter, thiocyanates. May ignite or explode spontaneously when heated, on contact with hot surfaces, when mixed with combustible materials, or otherwise contaminated. Shock- or friction-sensitive when heated. 

AMMONIUM PEROXYDISULFATE (7727-54-0) A strong oxidizer. Reacts with combustibles. reducing agents, organic materials, finely divided and powdered metals with risk of fire and explosion. Mixture with sodium peroxide produces a friction-, heat-, and water-sensitive explosive. 

BICHROMATE of POTASH (7778-50-9). Noncombustible, but many chemical reactions can cause fire and explosions. A powerful oxidizer. Violent reaction with many substances, including combustible materials, reducing agents, organic materials, finely divided metals, ammonium nitrate, ammonium perchlorate, fluorine, hydrazine, hydrazinium nitrate, hydrox-ylamine, iron powder, nitric acid, potassium iodide, sodium borohydride, sodium bromide, sodium tetraborate and its decahydrate, tungsten and zirconium dusts. Mixture with sulfuric acid forms chromic acid. Incompatible with ethylene glycol, iron, tungsten. 

CADOX (110-05-4) Forms explosive mixture with air (flash point, >5°F/12°C). A strong oxidizer and organic peroxide. Heat and hot surfaces cause decomposition, with risk of explosion. May be shock- and friction-sensitive. Violent reaction with reducing agents, organic matter, thiocyanates. Keep away from all other substances. 

CYCLOHEXANONE PEROXIDE (78-18-2) Forms explosive mixture with air (flash point 111 °F/44° cc). A strong oxidizer. May be able to form unstable peroxides in storage and may be sensitive to heat and shock. Reacts violently with combustible materials, reducing agents, organic substances, finely divided metals, caustics, ammonia. Attacks copper and its alloys some plastics. 

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