Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Organoaluminum compounds reactions

Organoaluminum compounds, reaction with imino carbocations, 66, 189 Orthoester Claisen rearrangement, 66, 22 Orthoformic acid, triethyl ester, 65, 146 Oxalic acid, diethyl ester, 65, 146... [Pg.255]

Organoaluminum compounds such as triphenylaluminum (527) are used for ketone synthesis[387]. On the other hand, the reaction of /-BuiAl affords the corresponding alcohol 528 by reductive carbonylation[388]. [Pg.201]

Organoaluminum Compounds. Apphcation of aluminum compounds in organic chemistry came of age in the 1950s when the direct synthesis of trialkylalurninum compounds, particularly triethylalurninum and triisobutylalurninum from metallic aluminum, hydrogen, and the olefins ethylene and isobutylene, made available economic organoalurninum raw materials for a wide variety of chemical reactions (see a-BONDED alkyls and aryls). [Pg.137]

I — the filler was activated in the liquid phase via reaction of the organoaluminum compounds fixed on the surface with VOCl3 II — activation of filler by previous securing on the surface of VOCl3 from the gas phase particles of less than 5-10microns in size amount to 96% ... [Pg.48]

Reaction between an oxime sulfonate, an organoaluminum compound, and Mc3SiCN... [Pg.1676]

In order to get reliable information about the yield of organoaluminum compounds formed in a transition metal-catalyzed hydroalumination reaction it is essential to derivatize the organometallic products by quenching the reaction mixture with electrophiles like D2O, O2 or halogens. It is often observed that hydrogenation... [Pg.48]

Early attempts by Asinger to enlarge the scope of hydroalumination by the use of transition metal catalysts included the conversion of mixtures of isomeric linear alkenes into linear alcohols by hydroalumination with BU3AI or BU2AIH at temperatures as high as 110°C and subsequent oxidation of the formed organoaluminum compounds [12]. Simple transition metal salts were used as catalysts, including tita-nium(IV) and zirconium(IV) chlorides and oxochlorides. The role of the transition metal in these reactions is likely limited to the isomerization of internal alkenes to terminal ones since no catalyst is required for the hydroalumination of a terminal alkene under these reaction conditions. [Pg.49]

The asymmetric nickel-catalyzed hydroalumination of prochiral terminal alkenes using adducts of BujAl and chiral amines was reported in 1981 [74], Among the different amines investigated, (-)-N,N-dimethylmenthylamine (DMMA) gave the best enantioselectivities. For example, reaction of 2,3,3-trimethyl-l-butene (39) at room temperature with 0.33 equiv. of the DMMA/iBu3Al adduct in the presence of 0.6 mol% of Ni(mesal)2 gave, after oxidation of the intermediate organoaluminum compounds, 2,3,3-trimethyl-l-butanol 40 in 76% yield and 27% ee (Scheme 2-19). [Pg.64]

The regiochemistry of Al-H addition to unsymmetrically substituted alkynes can be significantly altered by the presence of a catalyst. This was first shown by Eisch and Foxton in the nickel-catalyzed hydroalumination of several disubstituted acetylenes [26, 32]. For example, the product of the uncatalyzed reaction of 1-phenyl-propyne (75) with BujAlH was exclusively ds-[3-methylstyrene (76). Quenching the intermediate organoaluminum compounds with DjO revealed a regioselectivity of 82 18. In the nickel-catalyzed reaction, cis-P-methylstyrene was also the major product (66%), but it was accompanied by 22% of n-propylbenzene (78) and 6% of (E,E)-2,3-dimethyl-l,4-diphenyl-l,3-butadiene (77). The selectivity of Al-H addition was again studied by deuterolytic workup a ratio of 76a 76b = 56 44 was found in this case. Hydroalumination of other unsymmetrical alkynes also showed a decrease in the regioselectivity in the presence of a nickel catalyst (Scheme 2-22). [Pg.66]

Reaction of Imidazolides with Grignard Reagents, Organolithium, and Organoaluminum Compounds... [Pg.315]

Another method for the preparation of ketones is the reaction of imidazolides, ben-zimidazolides, or benzotriazolides with organoaluminum compounds [94]... [Pg.317]

Table VII. Effect of organoaluminum compounds on catalyst activity. Polymerization conditions molar ratio butadiene, propylene is 1.1 monomer concentration, 20 wt % in toluene catalyst, 0.8 mmol VO[OCH2C(CH3)3]2Cl phm, 5 mmol Al compound phm reaction time, 4 h and —45°C. Data from Ref. 19. Table VII. Effect of organoaluminum compounds on catalyst activity. Polymerization conditions molar ratio butadiene, propylene is 1.1 monomer concentration, 20 wt % in toluene catalyst, 0.8 mmol VO[OCH2C(CH3)3]2Cl phm, 5 mmol Al compound phm reaction time, 4 h and —45°C. Data from Ref. 19.
Evidence has been collected over the years which strongly indicates that the active species in the oligomerization reactions are nickel-hydride and nickel-alkyl complexes. [This is not necessarily true for catalysts prepared from nickel(II) compounds and organoaluminum compounds having low Lewis acidity, e.g., (C2H5)2A10C2H5 (44).] The majority of the evidence is circumstantial and is discussed below. [Pg.114]

Asymmetric Diels-Alder reactions. Diels-Alder reactions of aldehydes with silyloxydienes catalyzed by this chiral organoaluminum compound can proceed with high enantioselectivity. Thus reaction of benzaldehyde with the silyloxydiene 2 at... [Pg.46]

The sodium fluoride-water work-up offers an excellent method for large-scale preparations, and is generally applicable, for product isolation in the reaction of organoaluminum compounds. ... [Pg.95]

As mentioned above, the new method Lewis acid promoted living polymerization of methacrylic esters, by using enolatealuminum porphyrin (2) as nucleophilic initiator in conjunction with organoaluminum compounds, such as methylaluminum bis(2,6-di-tert-butyl-4-methylphenolate) (3e), as Lewis acids has enabled us to synthesize poly(methacrylic ester) of narrow molecular-weight distribution [51]. On the other hand, some reactions of aluminum por-... [Pg.71]


See other pages where Organoaluminum compounds reactions is mentioned: [Pg.130]    [Pg.383]    [Pg.383]    [Pg.398]    [Pg.430]    [Pg.430]    [Pg.68]    [Pg.38]    [Pg.840]    [Pg.541]    [Pg.1275]    [Pg.47]    [Pg.48]    [Pg.49]    [Pg.430]    [Pg.511]    [Pg.76]    [Pg.563]    [Pg.28]    [Pg.69]    [Pg.266]    [Pg.266]    [Pg.278]    [Pg.281]    [Pg.812]    [Pg.55]    [Pg.234]    [Pg.62]    [Pg.98]   


SEARCH



Organoaluminum compounds

Organoaluminum compounds reaction with epoxides

Organoaluminum compounds reactions with

Organoaluminum compounds, exchange reactions

Organoaluminum organoaluminums

Organoaluminum reactions

Reactions of Organoaluminum Compounds

© 2024 chempedia.info