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Linear alkenes

The reaction can be combined with an alkene isomerization, which requires the use of the more electron-withdrawing XANTPHENOXAPHOS ligand. Thus, starting from internal alkenes, linear amines can be obtained in quite reasonable yields and high n/iso selectivity (Scheme 15) [60]. [Pg.156]

Under appropriate conditions, Mn(0 Ac)3 can be used as a free-radical initiator for the homolytic iddition of acetic anhydride to terminal alkenes. Linear or a-branched carboxylic acids can be jroduced in 70-80% yields based on a-alkenes.507... [Pg.375]

The delocalization of the Jt-electrons is energetically favorable, and this affects the reactivity of aromatic compounds There is a tendency towards restoring aromaticity. This is why aromatic compounds, in contrast to regular alkenes (linear chains of carbon atoms containing at least one double bond), do not easily undergo addition reactions, whereby a double bond is replaced by two single bonds. Aromatic compounds show a preference for substitution reactions, which means that atoms are replaced. [Pg.37]

Scheme 6.16.1 Ethylene oligomerization is the method of choice to produce 1-alkenes (= linear ct-olefins). The worldwide capacity for 1-alkene production was above 3 Mio tons in 2010. Scheme 6.16.1 Ethylene oligomerization is the method of choice to produce 1-alkenes (= linear ct-olefins). The worldwide capacity for 1-alkene production was above 3 Mio tons in 2010.
Several other alkanes and alkenes, linear, branched, and cyclic, were examined with the different techniques mentioned above Sc (Huang et al., 1987 Lech and Preiser, 1988 Seemeyer et al., 1995 SunderUn and Armentrout, 1990 Tolbert and Beauchamp, 1984 Tonkyn et al., 1988), Y" " (Huang et al., 1987), and La -Lu (Comehl et al., 1995 Heinemann et al., 1994 Huang et al., 1987 Schilling and Beauchamp, 1988). For alkanes larger than ethane, increased reactivity was observed, which included also the activation of C—C bonds as indicated by the elimination of methane or other small hydrocarbons. Alkenes were also generally more reactive than alkanes, which... [Pg.40]

The major product of ethylene oligomerization in the presence of Ni-ylide-aluminum alcoxides are linear 1-alkenes with even carbon atom numbers, from C4 to 40- In addition to 1-alkenes, linear alkenes with internal double bonds (trans and cis) are always present in the reaction product. [Pg.40]

Rhodium nanoparticles were used as catalyst precursors for the solventless hydroformylation of 1-alkenes. Linear/branched selectivities up to 25 were achieved by adding xantphos to the catalyst system [46]. [Pg.170]

Intramolecular reaction can be used for polycyclization reaction[275]. In the so-called Pd-catalyzed cascade carbopalladation of the polyalkenyne 392, the first step is the oxidative addition to alkenyl iodide. Then the intramolecular alkyne insertion takes place twice, followed by the alkene insertion twice. The last step is the elimination of/3-hydrogen. In this way, the steroid skeleton 393 is constructed from the linear diynetriene 392(276]. [Pg.181]

Another interesting transformation is the intramolecular metathesis reaction of 1,6-enynes. Depending on the substrates and catalytic species, very different products are formed by the intramolecular enyne metathesis reaction of l,6-enynes[41]. The cyclic 1,3-diene 71 is formed from a linear 1,6-enyne. The bridged tricyclic compound 73 with a bridgehead alkene can be prepared by the enyne metathesis of the cyclic enyne 72. The first step of... [Pg.480]

The cyclohexadiene derivative 130 was obtained by the co-cyclization of DMAD with strained alkenes such as norbornene catalyzed by 75[63], However, the linear 2 1 adduct 131 of an alkene and DMAD was obtained selectively using bis(maleic anhydride)(norbornene)palladium (124)[64] as a cat-alyst[65], A similar reaction of allyl alcohol with DMAD is catalyzed by the catalyst 123 to give the linear adducts 132 and 133[66], Reaction of a vinyl ether with DMAD gives the cyclopentene derivatives 134 and 135 as 2 I adducts, and a cyclooctadiene derivative, although the selectivity is not high[67]. [Pg.487]

Thiirane 1,1-dioxides extrude sulfur dioxide readily (70S393) at temperatures usually in the range 50-100 °C, although some, such as c/s-2,3-diphenylthiirane 1,1-dioxide or 2-p-nitrophenylthiirane 1,1-dioxide, lose sulfur dioxide at room temperature. The extrusion is usually stereospeciflc (Scheme 10) and a concerted, non-linear chelotropic expulsion of sulfur dioxide or a singlet diradical mechanism in which loss of sulfur dioxide occurs faster than bond rotation may be involved. The latter mechanism is likely for episulfones with substituents which can stabilize the intermediate diradical. The Ramberg-Backlund reaction (B-77MI50600) in which a-halosulfones are converted to alkenes in the presence of base, involves formation of an episulfone from which sulfur dioxide is removed either thermally or by base (Scheme 11). A similar conversion of a,a -dihalosulfones to alkenes is effected by triphenylphosphine. Thermolysis of a-thiolactone (5) results in loss of carbon monoxide rather than sulfur (Scheme 12). [Pg.141]

The more recently developed so-called linear low-density polyethylenes are virtually free of long chain branches but do contain short side chains as a result of copolymerising ethylene with a smaller amount of a higher alkene such as oct-1-ene. Such branching interferes with the ability of the polymer to crystallise as with the older low-density polymers and like them have low densities. The word linear in this case is used to imply the absence of long chain branches. [Pg.215]

Comparison of the data for methoxide with those for t-butoxide in Table 6.4 illustrates a second general trend Stronger bases favor formation of the less substituted alkene. " A stronger base leads to an increase in the carbanion character at the transition state and thus shifts the transition state in the Elcb direction. A linear correlation between the strength of the base and the difference in AG for the formation of 1-butene versus 2-butene has been established. Some of the data are given in Table 6.5. [Pg.385]

The production of linear alkyl benzenes (LABs) is carried out on a large scale for the production of surfactants. The reaction involves the reaction between benzene and a long-chain alkene such as dodec-l-ene and often gives a mixture of isomers. Greco et al. have used a chloroaluminate(III) ionic liquid as a catalyst in the preparation of LABs [83] (Scheme 5.1-53). [Pg.200]

The metathesis reaction of alkenes constitutes a major development in the field of hydrocarbon chemistry in recent years. The first examples of the heterogeneously and the homogeneously catalyzed metathesis of linear alkenes have been published by Banks and Bailey (I) and Calderon et al. (2), respectively. By this reaction, linear alkenes are converted with high selectivity into equimolar amounts of two new alkenes, according to ... [Pg.131]

It has been suggested that these polymers are mainly linear, which may be a consequence of intermolecular metathesis reactions with traces of acyclic alkenes, or of other consecutive reactions 19-22). [Pg.135]

Solid catalysts for the metathesis reaction are mainly transition metal oxides, carbonyls, or sulfides deposited on high surface area supports (oxides and phosphates). After activation, a wide variety of solid catalysts is effective, for the metathesis of alkenes. Table I (1, 34 38) gives a survey of the more efficient catalysts which have been reported to convert propene into ethene and linear butenes. The most active ones contain rhenium, molybdenum, or tungsten. An outstanding catalyst is rhenium oxide on alumina, which is active under very mild conditions, viz. room temperature and atmospheric pressure, yielding exclusively the primary metathesis products. [Pg.136]

Bradshaw et al. 67) were the first to propose a reaction pathway that is compatible with a transalkylidenation scheme. They suggested that the reaction proceeds via a quasi-cyclobutane intermediate. Applied to linear alkenes, this is pictured as follows ... [Pg.145]

Of course, even in the case of acyclic alkenes reaction enthalpy is not exactly zero, and therefore the product distribution is never completely statistically determined. Table V gives equilibrium data for the metathesis of some lower alkenes, where deviations of the reaction enthalpy from zero are relatively large. In this table the ratio of the contributions of the reaction enthalpy and the reaction entropy to the free enthalpy of the reaction, expressed as AHr/TASr, is given together with the equilibrium distribution. It can be seen that for the metathesis of the lower linear alkenes the equilibrium distribution is determined predominantly by the reaction entropy, whereas in the case of the lower branched alkenes the reaction enthalpy dominates. If the reaction enthalpy deviates substantially from zero, the influence of the temperature on the equilibrium distribution will be considerable, since the high temperature limit will always be a 2 1 1 distribution. Typical examples of the influence of the temperature are given in Tables VI and VII. [Pg.157]

The preparation and identification of four types of S03-sulfonated products of linear and branched 1-alkenes (C5-C14) are described by Boyer [121]. 13C-and, to a lesser extent, -NMR spectra were used to ascertain the structures of 2-alkenesulfonic acids, p-sultones (as 2-methoxyalkanesulfonic acids), y- and 5-sultones. The mass spectra of some methyl 2-methoxyalkanesulfonates and 4-alkyl-5-sultones were also studied. Sufficiently volatile mixtures were separated by GLC after methylation of the sulfonic groups. [Pg.438]


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See also in sourсe #XX -- [ Pg.46 ]

See also in sourсe #XX -- [ Pg.289 ]

See also in sourсe #XX -- [ Pg.18 , Pg.19 ]

See also in sourсe #XX -- [ Pg.46 ]




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Carboxidation linear alkenes

Epoxidation of Cyclic and Linear Alkenes

Ethylene Oligomerization Processes for Linear 1-Alkene Production

Ethylene linear 1-alkene production

Formation of linear aldehydes starting from internal alkenes

Internal, linear alkenes

Linear selective hydroformylation alkenes

Solvent linear alkenes

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