Hybrid compounds organic-inorganic

At first, N-heterocyclic carbenes 20 look bizarre to the organic chemist, since they are organic/inorganic hybrid compounds. However, borazines, sometimes called inorganic benzene , are isoelectronic with benzene and are therefore extraordinarily stable heterocycles. Exchange of a borane... 

Niu, J., Zhao, J. Wang, J. et al. (2004) Synthesis, property and crystal structure of a novel two-dimensional network organic-inorganic hybrid compound based on the neodymium center and Keggin-type heteropolyanion of [a- N Journal of Molecular Structure, 699, 85-92. 

Preparation of phosphorus acids of the formula RP(0)(OH)2 may develop the synthesis of the functionalized nano-phosphate materials and also polyoxometalate-based organic/inorganic hybrid compounds in which the phosphorus atom is trapping between... 

PEROXIDES AND PEROXIDE COMPOUNDS - ORGANIC PEROXIDES] pol 18) Organic-inorganic hybrid glass... 

Besides the use of solution-based processing for the deposition of inorganic compounds, major developments are taking place in the field of deposition of organic-inorganic hybrid structures. Already indicated was the use of a combination of structured inorganic QDs and organics in the field of photovoltaics,... 

Various compounds have been prepared by solvothermal reactions metals, metal oxides, chalcogenides, - ° nitrides, - -" phosphides, open-framework structures, - oxometalate clusters, - organic-inorganic hybrid materials, - - and even carbon nanotnbes. - Most of the solvothermal products are nano- or microparticles with well-defined morphologies. The distribution of the particle size of the prodnct is nsnally qnite narrow, and formation of monodispersed particles is freqnently reported. - When the solvent molecules or additives are preferentially adsorbed on (or have a specific interaction with) a certain surface of the products, growth of the surface is prohibited and therefore products with unique morphologies may be formed by the solvothermal reaction. - - Thus nanorods, wires, tnbes, and sheets of various types of products have been obtained solvothermally. 

Intercalation of organic molecules into layered host lattice produces a variety of organic-inorganic hybrid materials. The solvothermal method provides a reaction system that allows application of high temperatures and therefore is a powerful technique for preparation of intercalation compounds. Exfoliation of layers may occur because of applied high temperatures. For example, exfoliated poly-ethylene/montmoriUonite nanocomposites were reported to be prepared by solvothermal reaction of organophilic montmorillonite with polyethylene in toluene at 170°C for 2... 

These results demonstrate the feasibility of the in vivo use of the organic-inorganic hybrid nanoparticles especially due to their extremely low cytotoxicity. Furthermore, this system might have possible apphcation as a carrier for versatile compounds, such as anticancer drugs and proteins, because of the high binding affinity of CaP to these compounds. 

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