Organic and organometallic compounds

Several chapters in this book are focussed on specific applications of INS spectroscopy. Integral to these studies has been the use of small molecules, usually organic, as reference materials and model compounds. This may give a somewhat misleading impression of INS spectroscopy in that it suggests that the study of organic compounds is almost incidental to the main thrust of work. This is contradicted by the fact that on TOSCA at ISIS more than 50% of the spectra measured are of organic compounds. 

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Molecules in this category contain atoms other that carbon and hydrogen. The distinction is made between organic and organometallic compounds. 

A crystal is a solid with a periodic lattice of microscopic components. This arrangement of atoms is determined primarily by X-ray structure analysis. The smallest unit, called the unit cell, defines the complete crystal, including its symmetry. Characteristic crystallographic 3D structures are available in the fields of inorganic, organic, and organometallic compounds, macromolecules, such as proteins and nucleic adds. 

D. Cox, G. Pilcher, Thermochemistry of Organic and Organometallic Compounds, Aademic Press, London, 1970. J. B. Pedley, R. D. Naylor, S. P. Kirby, Thermochemical Data of Organic Compounds, 2nd edition. Chapman and Hall, London, 1986. 

J.D. Cox, G. Pilcher, Thermochemistry of Organic and Organometallic Compounds, Academic Press, London, 1970. 

This index contains over 40,000 individual entries to the 6200 text pages of Volumes 1-7. The index mainly covers general classes of heterocyclic compound and specific heterocyclic compounds, but also included are natural products, other organic and organometallic compounds where their synthesis or use involves heterocyclic compounds, types of reaction, named reactions, spectroscopic techniques and topics involving heterocyclic compounds. 

The Chemical Thermodynamics of Organic and Organometallic Compounds , AcadPress, NY (1970) 90) O.V. Lukashevich et al, ZhOrg-... 

For values of heats of combustion of large numbers of organic compounds hydrocarbons and others, see Cox, J.D. Pilcher, G. Thermochemistry of Organic and Organometallic Compounds, Academic Press NY, 1970 Domalski, E.S. J. Phys. Chem. Ref. Data, 1972,1, 221. For large numbers of heats of formation values (from which heats of combustion are easily calculated) see Stull, D.R. Westrum Jr., E.F. Sinke, G.C. The Chemical Thermodynamics of Organic Compounds, Wiley NY, 1969. 

Reactions of Elemental Sulfur with Inorganic, Organic and Organometallic Compounds... 

Cox JD, Plicher G (1970) Thermochemistry of organic and organometallic compounds. Academic Press, London... 

Studies of the effects of low frequency ultrasonic waves on a broad range of synthetically useful reactions are summarized. Discussion is centered on the results obtained in our laboratory where we have concentrated on the reactions of metals with functionalized organic and organometallic compounds. Special emphasis is on lithium and zinc with organic and organosilicon halides. 

Pilcher, G. Thermochemistry of organometallic compounds containing metal-carbon linkages. MTP Review of Science. Series 2. Physical chemistry, Vol. 10. Chapter 2. 1975, p. 45 Cox, J. D., Pilcher, G. Thermochemistry of organic and organometallic compounds. London Academic Press 1970... 

M. E. Minas da Piedade. Oxygen Bomb Combustion Calorimetry Principles and Applications to Organic and Organometallic Compounds. In Energetics of Stable Molecules and Reactive Intermediates, M. E. Minas da Piedade, Ed. NATO ASI Series C, Kluwer Dordrecht, 1999. 

J. B. Pedley, J. Rylance. Sussex-N. P. L. Computer Analysed Thermochemical Data Organic and Organometallic Compounds. University of Sussex Brigton, 1977. 

Flash points of organic and organometallic compounds, Stevenson, R. M., New York, Elsevier, 1987... 

Another approach to isolate the catalyst from the products is the application of perfluorinated catalytic systems, dissolved in fluorinated media [63], which are not non-miscible with the products and some commonly used solvents for catalysis like THE or toluene at ambient temperature. Typical fluorinated media include perfluorinated alkanes, trialkylamines and dialkylethers. These systems are able to switch their solubility properties for organic and organometallic compounds based on changes of the solvation ability of the solvent by moving to higher temperatures. This behavior is similar to the above-mentioned thermomorphic multiphasic PEG-modified systems [65-67]. 

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