O-Chlorodiphenyl

O-Chlorodiphenyl, b.p. 154°/12.5 mm., is obtained in 60% yield by a similar procedure. Cuprous chloride [Org, Syntheses Coll. Vol. 1, 170 (1941)] is used in place of the cuprous bromide above. 

Unsymmetrical diaryls may be prepared by treating an aryl diazonium salt solution with sodium hydroxide or sodium acetate in the presence of a liquid aromatic compound. Thus 2-chlorodiphenyl is readily formed from o-chloro phenyl diazonium chloride and sodium hydroxide solution (or sodium acetate solution) in the presence of benzene ... 

Chlorodiphenyl. Diazotise 32 g. of o-chloroaniline (Section IV,34) in the presence of 40 ml. of concentrated hydrochloric acid and 22 -5 ml. of water in the usual manner (compare Section IV,61) with concentrated sodium nitrite solution. Transfer the cold, filtered diazonium solution to a 1 5 htre bolt-head flask surrounded by ice water, introduce 500 ml. of cold benzene, stir vigorously, and add a solution of 80 g. of sodium acetate trihydrate in 200 ml. of water dropwise, maintaining the temperature at 5-10°. Continue the stirring for 48 hours after the first 3 hours, allow the reaction to proceed at room temperature. Separate the benzene layer, wash it with water, and remove the benzene by distillation at atmospheric pressure distil the residue under reduced pressure and collect the 2-chlorodiphenyl at 150-155°/10 mm. The yield is 18 g. Recrystalliae from aqueous ethanol m.p. 34°. 

Chloro-1 -nitropropane Chloroacetaldehyde a-Chloroacetophenone Chlorobenzene (monochlorobenzene) o-Chlorobenzylidine malononitrile Chlorobromomethane Chlorodiphenyl (42% chlorine) Chlorodiphenyl (54% chlorine) 2-Chloroethanol (ethylene chlorohydrin) Chloroform... 

Chloroacetophenone (phenacyl chloride) Chlorbenzene (monochlorobenzene) o-Chlorobenzylidene malononitrile (OCBM) Chlorobromomethane/bromochloromethane 2-Chloro-l, 3-butadiene, see p-Chloroprene Chlorodiphenyl (42% chlorine)... 

Phosphine, (2-bromophenyl)dichloro-, 2,991 Phosphine, (w-chloroalkyl)dichloro-, 2, 991 Phosphine, chlorodimethyl-, 2, 991 Phosphine, chloro(dimethylamino)-, 2, 991 Phosphine, chlorodiphenyl-, 2, 990 Phosphine, cyclohexyl(o-anisyl)methyl-rhodium complexes asymmetric hydrogenation, 6, 251 Phosphine, [(dialkylphosphino)alkyl]diphenyl-, 2, 994 Phosphine, dichloromethyl-, 2, 991 Phosphine, dichlorophenyl-, 2, 990 Phosphine, diethylphenyl-, 2, 992 Phosphine, dimethyl-, 2,992 Phosphine, dimethylphenyl-, 2,992 Phosphine, diphenyl-, 2, 992 Phosphine, ethyldiphenyl-, 2, 992 Phosphine, ethylenebis(diethyl-, 2, 993 Phosphine, ethylenebis(diphenyl-, 2,993 Phosphine, ethylenebis(phenyl-, 2,992 Phosphine, ethylidynetris[methylene(diphenyl-, 2,994 Phosphine, [(ethylphenylphosphino)hexyl]diphenyl-, 2, 994... 

The loss of Cl- from the molecular ion of ortho-chlorodiphenyl sulfoxide (o-ll) has been found to be significantly greater than from the meta- and para-isomers (equation 3)12. This observation is best explained by an ortho effect in accord with a tight activated complex. 

Chlorobutane [109-69-3] 4-Chloro-o-cresol [1570-64-5] Chlorocyclohexane [542-18-7] 4-Chlorodiphenyl ether... 

Benzyl chloride C4H3CH2CI, chlorodiphenyls and derivatives C,2H,o-XC1X, chlorinated benzenes, chlorinated naphthalenes CioHj-xCl... 

Stibine, (o-bromophenyl)dichloro-, 1007 Stibine, chlorodimethyl-, 1007 Stibine, chlorodiphenyl-, 1007 Stibine, ethylenebis(diphenyl-, 1008 Stibine, ethylidynebis(dimethyl-, 1008 Stibine, o-phenylenebis(dimethyl-, 1008 Stibine, triethyl-, 1008 Stibine, trimethyl-, 1008 Stibine, triphenyl-, 1008 sulfide... 

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