Nitrogen fluoride sulfide

Thiazyl fluoride (nitrogen fluoride sulfide) is a colorless gas that condenses to a yellow liquid (bp 0.4°, mp —89°). The compound decomposes readily at room temperature and should be stored at —78°, where trimerization occurs slowly. It reacts violently with water. Thiazyl fluoride is very reactive toward electrophiles and nucleophiles. IR (gas) 1372 (s), 641 (vs), 366 (s) cm". F NMR " )(SF) (CFCl, int. ref.) 234 ppm. 

Nickel sulfide (NiS) NijSj(cr) 1628 Nitrogen fluoride oxide (NF3O) Wi< > 1123... 

The Air Force Dispersion Assessment Model (ADAM -1980s) calculates the source term and dispersion of accidental releases of eight specific chemicals chlorine, fluorine, nitrogen tetroji ogen sulfide, hydrogen fluoride, sulfur dioxide, phosgene, and ammonia. It Ut a ... 

D.6 Write the formula of (a) dinitrogen tetroxide (b) hydrogen sulfide (c) dichlorine heptoxide (d) nitrogen triiodide (e) sulfur dioxide (f) hydrogen fluoride (g) diiodine hexachloride. 

Nitrile sulfides (37) have some, admittedly slight, structural affinity with the other nitrogen-sulfur reagents discussed in Section IV. They are unstable reactive intermediates that can be generated by the thermolysis of 1,3,4-oxathiazol-2-ones (38) or of 1,3,4-oxathiazoles (39).41 42 An alternative preparation is by the elimination of 2 moles of hydrogen fluoride from imini-sulfur difluorides (Scheme 5).43 Nitrile sulfides (37) are capable of undergoing... 

Oxygen becomes oxide Nitrogen becomes nitride Fluorine becomes fluoride Chlorine becomes chloride Sulfur becomes sulfide Carbon becomes carbide... 

Inorganic gases Oxides of nitrogen Oxides of sulfur Other inorganics Nitrogen dioxide, nitric oxide Sulfuric acid, sulfur dioxide Carbon monoxide, chlorine, ozone, hydrogen sulfide, hydrogen fluoride, ammonia One of the principal pollutants is sulfur dioxide, which is a corrosive acid gas that combines with water vapor in the atmosphere to produce acid rain. 

Hydrogen Cyanide Sulfur Dioxide Hydrogen Sulfide Nitrogen Dioxide Hydrogen Fluoride Ammonia... 

PROP An atmospheric combination of smoke, fog, and industrial gases. Composition Contents var % but sulfur dioxide, oxides of nitrogen, and ozone are common components others are sulfides, fluorides, chlorides, carbon particles, and various hydrocarbons. 

In 1979 Vedejs and Martinez reported a terse communication on a new concept for the generation of nitrogen, sulfur, and phosphorus ylides. Their method consists of initial alkylation of the heteroatom of amines, imines, sulfides, or phosphines with trimethylsilylmethyl triflate, and subsequent desilylation of the resulting salts with fluoride ion (79JA6452). For the... 

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