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Nitrogen discovery physical

On the basis of a variety of physical and spectroscopic measurements, Nelson and Heal concluded that S Nj is a 6-membered ring with nitrogen atoms in the 1,3-positionsHowever, because of its low melting point (23 °C) and thermal instability, the conformation of the ring has been difficult to ascertain. The discovery that S4N2 can be recrystallized from diethyl ether at —20 °C has enabled the low temperature (—100 °C) X-ray crystal structure to be determined. As indicated... [Pg.125]

Professor of physics at Cavendish Laboratory, Cambridge. He made elaborate investigations of the electrochemical equivalent of silver and of the combining volumes and compressibilities of gases. His observation that nitrogen prepared from the atmosphere is heavier than nitrogen prepared from ammonia led to the discovery of argon, the first noble gas. He also contributed to optics and acoustics. [Pg.780]

Addition of EGA to the analysis of atmospheric aerosol particles has permitted an independent speciation and determination of the nitrogenous component for samples which have not had chemical or physical pretreatment. The discovery from ESCA analyses that a substantial fraction of the particulate nitrogen exists chemically bound to the carbonaceous fraction has been confirmed by EGA. The indication from ESCA and EGA that inorganic sulfate... [Pg.404]

Thus, at present, the task of atmospheric nitrogen fixation has mainly been developed in two directions reduction and oxidation fixation. Chemical fixation of molecular nitrogen by the reduction mechanism on transition metals is a comprehensively studied branch of physical chemistry, displaying several discoveries made in this direction [165],... [Pg.137]

A few informative properties of life come from easy category distinctions, such as the fact that all known life makes essential use of carbon and carbon-oxygen-nitrogen molecules in liquid water solution. The seemingly trivial observation that such carbaquist chemistry is ruled out if astrophysical carbon abundance lies below a certain threshold enabled Hoyle [1] to predict the 7.6 MeV carbon-12 ( C) nuclear resonance with remarkable precision because the discovery of the triple-alpha reaction synthesis of in stars happens to be a bottleneck for stellar nucleosynthesis of all the heavy elements. The pragmatic information in this prediction is easy to measure because it guided experimental characterization of nuclear structure where the existing computational capabilities could not. Similar sensitive dependence of the physical state of water has been used to define a habitable zone in planetary physics [10], which is not predictive in the same sense as carbon abundance (we already knew where the earth s orbit lies), but which creates a useful filter in the search for extraterrestrial life. [Pg.386]


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Nitrogen discovery

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