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Negative deflection

To complete the explanation of why GP effects cancel in the ICS, we need to explain why the 2-TS paths scatter into negative deflection angles. (It is well known that the 1-TS paths scatter into positive deflection angles via a direct recoil mechanism [55, 56].) We can explain this by following classical trajectories, which gives us the opportunity to illustrate a further useful consequence of the theory of Section II. [Pg.27]

Figure 14 shows a representative 2-TS trajectory, which demonstrates that the 2-TS paths follow a direct S-bend insertion mechanism. The trajectory passes through the middle of the molecule, and avoids the Cl this forces the products to scatter into negative deflection angles. The 2-TS QCT total reaction... [Pg.28]

Rebound Response to the dynamic blast load, will cause the window to rebound with a negative (outward) deflection. The outward pane displacement and the stresses produced by the negative deflection must be safely resisted by the window while positive pressures act on the window. Otherwise, the window which safely resists stresses... [Pg.127]

Let us now examine the chromatogram produced by this separation. Starting at the point of injection, we follow the baseline to the first deflection. After about 2min, we see a small positive deflection immediately followed by a small negative deflection, which then returns to the baseline. The center of this peak complex is called the void volume (Vo). It represents the amount of mobile phase contained inside the column, but outside the packing material. It is the mobile phase volume necessary to wash out the sample solvent. [Pg.47]

Do not breathe too close to the sniffing probe or its reference chamber because the C02 from your breath could cause a deflection of the needle. If you are going to use a helium test gas after doing a bubble test, you must wait until the system is completely dry. The water will cause a negative deflection and the helium will cause a positive deflection, providing a combined weaker deflection. If, coincidentally, the water and helium are perfectly balanced, there will be no deflection. [Pg.453]

One day, Jim (Lovelock) poked a hole in one of the tritium foils and the plane parallel detector was ready to test.. .. A mixture of components containing different functional groups along with 2 or 3 hydrocarbons was prepared and injected onto a capillary column. Positive deflections were recorded for the hydrocarbons and a series of negative deflections for the ketones, aldehydes, alcohols and particularly the halogenated substances. The electron capture detector came into being with full force. [Pg.25]

In the FV approach the deflection data are shced and sorted in deflection values that are larger and smaller than some arbitrarily chosen value. Hence, this mode displays the deflection values with respect to a reference point, which is different from true pull-off forces. For instance, f-d curves displaying a large hysteresis may show a strongly negative (deflection = force) value in the FV image, which may erroneously imply large pull-off forces (for an illustrative example see hands-on example 38). [Pg.193]

Warpage is a function of stress distribution within the material. Stress distribution depends, in turn, on the distribution of filler particles. If filler distribution is not uniform (see section 7.2) stress distribution will vary in different sections of the part. Typically, warpage close to the edges has a different direction of deflection than in the center of the part. Also, there is a higher negative deflection in the region of the part remote Irom the injection nozzle because these regions are filler deficient. [Pg.448]

Sion an is revealed by a negative deflection in the analyte signal. [Pg.343]

In Fig. 25, f 2 an(l P3 illustrate trajectories with comparatively large impact parameters showing the influence of the positive portion of the potential with negative deflection angles. ) , in Fig. 25 illustrates a trajectory with a smaller impact parameter which is influenced by the repulsive part of the potential exhibiting a positive deflection angle. PA illustrates the situation for... [Pg.232]

The sorter has been automated under computer control which allows spectra to be obtained much more quickly and with more detail. Figures 12 and 13 show spectra of live and dead yeast, respectively, obtained from the automated sorter while operating in the analyzer mode. The spectra show both positive and negative deflections and can be used to select conditions to separate a mixture of live and dead cells. [Pg.453]

Figure 7.2. Single residue hydrophobicity plots for the a- and P-chains of hemoglobin and for myoglobin. Note the marked decrease in polar residues (the negative deflections) in the plots for the a- and p-... Figure 7.2. Single residue hydrophobicity plots for the a- and P-chains of hemoglobin and for myoglobin. Note the marked decrease in polar residues (the negative deflections) in the plots for the a- and p-...
Fig. 12. The relation between field epsp amplitude and perforant path stimulus intensity in young ( ) and old (O) rats is shown for the in vivo (A) and in vitro (D) preparations. For comparison, stimulus intensity is expressed as the product of current and duration since these two parameters were varied differently in the two preparations. For the in vivo experiment, response wave forms were averaged across animals within the young (B) and old (C) groups. Superimposed traces at the various stimulus levels recorded simultaneously from the granule layer (E) and the molecular layer (F) are shown from a single slice preparation. The dashed lines in B, C, and E indicate the time of measurement of the field epsp (2 msec after stimulus onset). The sharp negative deflections in B, C, and E are population spikes (asterisks), whereas the early negative deflection in F represents the presynaptic fiber response (arrow). (From Barnes and McNaughton, 1980.)... Fig. 12. The relation between field epsp amplitude and perforant path stimulus intensity in young ( ) and old (O) rats is shown for the in vivo (A) and in vitro (D) preparations. For comparison, stimulus intensity is expressed as the product of current and duration since these two parameters were varied differently in the two preparations. For the in vivo experiment, response wave forms were averaged across animals within the young (B) and old (C) groups. Superimposed traces at the various stimulus levels recorded simultaneously from the granule layer (E) and the molecular layer (F) are shown from a single slice preparation. The dashed lines in B, C, and E indicate the time of measurement of the field epsp (2 msec after stimulus onset). The sharp negative deflections in B, C, and E are population spikes (asterisks), whereas the early negative deflection in F represents the presynaptic fiber response (arrow). (From Barnes and McNaughton, 1980.)...

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See also in sourсe #XX -- [ Pg.67 , Pg.123 , Pg.124 ]




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Deflection

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