Near-infrared spectroscopy diffuse reflectance mode

Also, Fourier transform infrared absorption spectroscopy provides relevant information regarding the specific interactions of different probes within substrates [17], especially in the diffuse-reflectance mode when applied to the study of powdered opaque surfaces that disperse the incident radiation. The extension of this technique to obtain time resolved transient absorption spectra in the IR wavelength range (laser flash-photolysis with IR detection) will certainly play in the near future an important role in terms of clarifying different reaction mechanisms in the surface photochemistry field [17c, 18]. 

The value of computing derivative spectra to correct for non-linear baseline signals is frequently exploited in reflectance spectrometry. Rapid measurement of the chemical composition of materials and products by diffuse reflectance spectroscopy in the near-infrared (NIR) region (800-2600 nm) is routine in many industries. Because most bulk materials are not transparent the mode of measurement is generally reflectance. For powder samples the intensity of... 

Diffuse reflectance spectroscopy (DRS) has been frequently employed in UV-Vis spectroscopy of zeolites (cf. Volume 4, Chapter 4 of the present series). More recently, it became also popular in IR investigations (cf., e.g., [160, 161]). The DRIFT technique is advantageous because it is successfully applicable not only in the mid infrared but also in the near infrared (NIR) region of 4000-10,000 cm where the transmission technique usually fails because of severe scattering through the absorbent particles. The NIR range, however, is very important with respect to the study of overtone and combination modes of vibrations. Moreover, diffuse reflectance IR experiments can be carried out not only with pressed wafers as in transmission spectroscopy, but also with zeolite pow-... 

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