N-Nonyl alcohol

Prepare a Grignard reagent from 24 -5 g. of magnesium turnings, 179 g. (157 ml.) of n-heptyl bromide (Section 111,37), and 300 ml. of di-n-butyl ether (1). Cool the solution to 0° and, with vigorous stirring, add an excess of ethylene oxide. Maintain the temperature at 0° for 1 hour after the ethylene oxide has been introduced, then allow the temperature to rise to 40° and maintain the mixture at this temperature for 1 hour. Finally heat the mixture on a water bath for 2 hours. Decompose the addition product and isolate the alcohol according to the procedure for n-hexyl alcohol (Section 111,18) the addition of benzene is unnecessary. Collect the n-nonyl alcohol at 95-100°/12 mm. The yield is 95 g. 

NONOXYNOL-9 see NNB300 NONYL ACETATE see NNB400 NONYL ALCOHOL see NNB500 n-NONYL ALCOHOL see NNB500 sec-NONYL. LCOHOL see DNH800... 

NONYL ALCOHOL or n-NONYL ALCOHOL (143-08-8) Combustible liquid (flash... 

The aldehydes and alcohols produced are a mixture of normal and iso-compounds. This is due not only to the orientation of the hydrogen with respect to the C-CO bonds in the initial reaction complex but also to the isomerization of the olefin under the process conditions. It may be significant that nickel carbonyl does not readily shift the olefin double bond under the 0X0 process conditions, and nickel compoimds are very poor catalysts for the process. From isooctene 32% n-nonyl alcohol, and from propylene 50% n-butyl alcohol are obtained, the remainder of the products being isoalcohols. In general, using a-olefins as raw material, one obtains about 60% isoalcohols. The synthesis will not occur unless a labile hydrogen atom is available in the olefin reactant. With diolefins the reaction takes place at only one double bond. 

CAS-No [143-08-8] alcohol c-9 n-nonyl alcohol octyl carblnol pelargonic alcohol... 

Nonyl alcohol. See 3,5,5-Trimethvlhexan-1-ol n-Nonyl alcohol. See Nonyl alcohol s-Nonyl alcohol. See 2,6-Dimethyl heptanol-4... 

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