Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

N mode

The Fe-N mode is at 222 in the R state and 207 cnY in the T state for the a subunits, but only shifted to 218 T state for the (3 subunits. This is consistent with the interpretation that the Fe-imidazole interations are weakened more in the T state of the a subunits than p subunits. Time-resolved resonance Raman studies have shown that the R T switch is complete on a 10 ps tuuescale [38]. Finally, UV excitation of the aromatic protein side chains yields... [Pg.1172]

Methyl bonding, methylene scissor, and 7car-N modes occur at 1460 to 1340 cm" . Ring bonding and methyl rocking modes are found at 1040 to 1070 and 980 cm" , respectively. Four bands, at 600 to 700. 550 to 600. [Pg.274]

For 1,2,3-triazole, the Ti (N ), i-ti (N, N ), and Ti fC) carbene coordination modes prevail in organometallic compounds. Benzotriazole has the same general pattern but often operates as a composite unit of benzotriazole and benzotriazolate linked by the hydrogen bond. In some organoosmium compounds, the i-ti (N, ) mode is realized, where the C -center refers to the annulated benzene ring. In some variations, together with the i-ti (N, N ) mode, the Ti fN" ) monodentate coordination occurs. The I-ti (N, N ) mode can also be traced. [Pg.167]

T) (N, N ) mode complexes. Suspected T) -mode of coordination still remains unconfirmed. The organometallic chemistry of pentazole is the challenge for the further developments. [Pg.167]

Figure 2, GC-TEA (N mode) chromatogram of a tire factory air sample. The column was a 5,5 m glass tube, 2mm, i,d, packed with Carbopak B(4% Carbowax 20 M, with 0,8% KOH on charcoal). Carrier gas flow rate was 15 mL/min, Column temperature was held at 40°C for 2 min, and then increased by 8°/min to 180°C, Peak identity 1-dimethylamine, 2-trimethylamine, 3-diethylamine, 4-tri-ethylamine, and 5-morpholine,... Figure 2, GC-TEA (N mode) chromatogram of a tire factory air sample. The column was a 5,5 m glass tube, 2mm, i,d, packed with Carbopak B(4% Carbowax 20 M, with 0,8% KOH on charcoal). Carrier gas flow rate was 15 mL/min, Column temperature was held at 40°C for 2 min, and then increased by 8°/min to 180°C, Peak identity 1-dimethylamine, 2-trimethylamine, 3-diethylamine, 4-tri-ethylamine, and 5-morpholine,...
Biolayer refractive index, n Mode propagation constant, ft... [Pg.185]

The resonance condition for a molecule of n modes is the (n - l)-dimen-sional surface in action space defined by... [Pg.68]

Fish tissue Digestion with NaOH, extraction with benzene, extraction with dilute H2SO4, water removal and volume reduction GPC cleanup. GC/HCD (N mode) <20 ppb 65 (20% RSD) Diachenko 1979... [Pg.140]

For a series of 2,2-diaryl AT-oxides Vc=n and Vn q have been correlated respectively with bands in the ranges 1560-1619 and 1120-1180 cm". Both symmetric (1520cm ) and antisymmetric (1570, 1590cm" ) C=N modes have been assigned in two isomeric 2,2-dimethyl N-oxides the latter were inactive in the laser Raman spectra. ... [Pg.396]

Mulliken derived equations for the variation of overlap integrals with distance between the participating nuclei. For homonuclear diatomic molecules the equations for the overlap of two 2p orbitals in o and n modes are respectively ... [Pg.63]

Alternatively, sample subjected to purge and trap concentration analyte determined by GC-FID, GC-NPD in N-mode, or GC/MS. [Pg.274]

Aqueous samples extracted with methylene chloride extract concentrated and solvent exchanged to hexane florisil cleanup (for dirty samples) extract analyzed on GC using FID or NPD in N-mode or by GC/MS. [Pg.361]

To determine Paraquat in agricultural run-off water Payne [194] separated the sediment from the sample (2L) by adding calcium chloride to aid flocculation, leaving the mixture overnight in a refrigerator for the sediment to settle. A 1L aliquot of the filtrate is extracted with dichloromethane. The dichloromethane extracts are concentrated by evaporation and the Trifluralin and Diphenamid are determined by direct injection, without further purification on to a glass column 1,8x6mm od packed with 10% DC 200 on Gas-Chrom Q and operated at 220°C with helium as carrier gas (lOOmL min-1) and a Coulson electrolytic-conductivity detector (N mode). Paraquat is determined in the filtrate by a modification of a conventional colorimetric method. Recoveries of the three substances were between 82 and 95% from water. [Pg.295]

Fluoridone aquatic herbicide and photolysis product iV-methyl formamide Hall electrolytic detector in N mode [469]... [Pg.317]

No imaginary frequencies were revealed by vibrational analysis and a value of 1663.2 cm 1 was assigned to the C=N mode, close to that already reported by Ugalde <1992JMT167>. [Pg.691]

The stochastic resonance is determined by the longitudinal (with respect to n) modes of the relaxational problem (4.90). Since A is not a self-adjoint operator, it produces, together with the spectrum of eigenvalues ,, two sets of eigenfunctions defined as... [Pg.505]

A fairly detailed study has been made of the 1H NMR, far IR and electronic absorption spectral properties of the complexes ReNX2(PEt2Ph)3 (X = Cl, Br or I).325 The characteristic r(Re=N) modes occur close to 1000 cm-1 in the IR spectra of these and other nitrido-rhenium(V) complexes.399,404... [Pg.189]

The v(C-Pt) stretching frequency is higher for adsorption on the di-a mode than on the n mode, indicating a stronger bond in the former case. The calculated vibrational frequencies for the di-a adsorption mode agree fairly well with the available experimental data [62] but the calculated values for the n-top adsorption mode differ significantly from the experimental data [62], This strengthens the idea that, on a Pt(lOO) surface, at low temperatures, the ethylene molecule adsorbs only as a di-a complex. [Pg.234]


See other pages where N mode is mentioned: [Pg.1172]    [Pg.157]    [Pg.144]    [Pg.208]    [Pg.148]    [Pg.85]    [Pg.160]    [Pg.125]    [Pg.159]    [Pg.160]    [Pg.258]    [Pg.1065]    [Pg.135]    [Pg.525]    [Pg.547]    [Pg.687]    [Pg.460]    [Pg.242]    [Pg.83]    [Pg.421]    [Pg.395]    [Pg.295]    [Pg.111]    [Pg.196]    [Pg.220]    [Pg.196]    [Pg.220]    [Pg.143]    [Pg.147]    [Pg.148]    [Pg.166]    [Pg.197]   
See also in sourсe #XX -- [ Pg.124 ]




SEARCH



General Case of N-Coupled Modes

N-H stretching modes

© 2024 chempedia.info