N-Hexyl iodide

Nitro-n-hexane. Use 41 g. of dry silver nitrite, 51 g. of n-hexyl iodide (35-5 ml.) and 100 ml. of sodium dried ether. Reflux on a water bath for 8 hours decant the ethereal solution and wash the sohd well with sodium dried ether. Distil the residue, after the removal of the ether from the combined extracts, from 5 g. of dry silver nitrite, and collect the fraction of b.p. 190-192° (13 g.) as 1-nitro -hexane. The pure compound is obtained by distilling under diminished pressure b.p. 81 6°/15 mm. 

Hexanediol, 251,873,879 n-Hexyl alcohol, 247, 253 dehydrogenation of, 322 P n Hexylacrylic acid. 465, 466 n-Hexylbenzene, 510, 516 n-Hexyl bromide. 282 n-Hexyl chloride, 270, 274 n-Hexyl cyanide, 409 n-Hexyl fluoride, 288, 289 n-Hexyl iodide, 288 n-Hexyl magnesium bromide, 237 n-Hexyl mercaptan. 496, 497 n-Hexyl nitrite, 306 1-Hexyne, 896, 899... 

In a thorough study of the effect of reactant ratio, initiator concentration, temperature and time of reaction, it was found that the optimal reaction conditions for 1 1 adduct formation in the reaction of perfluoro-n-hexyl iodide to vinyl acetate are [210] ... 

A sodium fusion test would first be performed on the unknown, breaking it down into its components, and then the unknown would be acidified, mixed with carbon tetrachloride, and shaken with Cl2. A purple color would be indicative of I2/ which would indicate n-hexyl iodide as the unknown. If no purple color is observed, we would add AgNOa. The formation of a white precipitate (AgCl) would point to benzyl chloride as the unknown. 

Synonyms Perfluoro-n-hexyl sulfonic acid Empincal CeHFisOsS Formula CF3(CF2)sS03H Properties M.w. 400.11 Uses Fire extinguishant additives Perfluorohexyl iodide CAS 355-43-1 EINECS/ELINCS 206-586-6 Synonyms Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-6-iodo- 1-lodoperfluorohexane 1-lodotridecafluorohexane Perfluoro-n-hexyl iodide Perfluoro-1-iodohexane Tridecafluorohexyl iodide Tridecafluoro-1-iodohexane 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluroo-6-iodohexane Empirical CeFisI Formula CF3(CF2)4CF2l Properties Colorless liq. which can turn rosy or violet sol. > 250 g/l in ethanol, acetone, ethyl acetate, xylene, hexane, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, trichlorotrifluoroethane, chloroform insol. in water m.w. 445.95 sp.gr. 2.051-2.063 m.p. -45 C b.p. 

Dry hexamethylphosphoramide followed by the startg. hydroxy sulfoxide in tetrahydrofuran added at -40° with stirring under Ng to a soln. of Li-diethyl-amide in dry tetrahydrofuran, stirring continued 0.5 hr., treated with n-hexyl iodide, stirred 0.5 hr. at -40°, aq. 50%-diethylamine added, the cold bath removed, allowed to warm to room temp., and stirred ca. 2 hrs. to effect rearrangement and cleavage l- -hexyl-l-cyclopentene-cw-3,5-diol. Y 50-77%. F. e. s. D. A. Evans et al., J. Org. Chem. 39, 3176 (1974). 

At — 65 °C in THF allylic ethers may be metalated with methyl-lithium in high yield without any Wittig rearrangement With n-hexyl iodide the metalated species (227 M = Li) underwent alkylation preferential y to oxygen. However, with cyclohexanone (227 M = Li) gave ratios the inverse of those predicted from alkylation studies. Thus when (227 R = Bu M = Li) reacted widt cyclohexanone, the product... 

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