N-Allylthiourea

N-Allylthiourea (thiosinamine) [109-57-9] M 116.2, m 70-73 , 78 . Recrystd from H2O. Soluble in 30 parts of cold H2O, soluble in EtOH but insoluble in C6H6. Also recrystd from acetone, EtOH or ethyl acetate, after decolorising with charcoal. The white crystals have a bitter taste with a slight garlic odour and are TOXIC. [Anal Chem 21 421 7949.]... 

CAS 109-57-9 EINECS/ELINCS 203-683-5 Synonyms Allylthiocarbamide 1-Allylthiourea 1-Allyl-2-thiourea Allyl-2-thiourea N-Allylthiourea... 

Other recent papers report on u.v. spectroscopic studies of 1,5-di-substituted 2,4-dithiobiurets, isatinthiosemicarbazones, 2,4-dihydroxy-dithiobenzoic acid, thiocarbonyl difluoridethiophosgene, 3-substi-tuted 2-thioxo-4-oxo-3,4-dihydro-2H-l,3-benzoxazines, 2- and 4-thioxo-1,3-thiazanes, rhodanine and its S- and N-methyl derivatives, and co-balt(ii) and nickel(ii) complexes of N-allylthiourea. ... 

Table 2. Chalcogenide Precursors. TU thiourea, TA thioacetamide, TC thiocarbazide, TSC thio-semicarbazide, ETU ethylthiourea, ATU allylthiourea, SU selenourea, DSU N,N dimethyl selenourea, TS thiosulfate, SES selenonilfate...

Thiocyclopentane-1,1-dioxide. See Sulfolane Thiocynamine. See Allylthiourea n-Thiodecyl alcohol. See 1-Decanethiol Thiodemeton. See Disulfoton 2,2 -Thiodiacetic acid. See Thiodiglycolic acid, 4,4 -Thiodianiline... 

Urea, allyl-. See Allyl urea Urea, 1-allyl-2-thio-. See Allylthiourea Urea amidohydrolase. See Urease Urea, N-[1,3-bis (hydroxymethyl)-2,5-dioxo-4-imidazolidinyl-N,N -bis (hydroxymethyl)-. See Diazolidinyl urea Urea, butyl-. See N-Butylurea Urea, 1-(5-(t-butyl)-1,3,4-triadiazol-2-yl)-1,3-dimethyl-. See Tebuthiuron Urea, N -(3-chloro-4-methoxyphenyl)-N,N-dimethyl-. See Metoxuron Urea, N-(4-chlorophenyl)-N -[4-chloro-3-(trifluoromethyl) phenyl]-. See Cloflucarban Urea, N-(4-chlorophenyl)-N -(3,4-dichlorophenyl)-. See 3,4,4 -Trichlorocarbanilide... 

Previous studies have shown that the ammonia-oxidizing bacterium N. eumpaea was able to oxidize a broad range of hydrocarbons, including non-aromatic and aromatic compounds, and it is believed that the AMO is participating. The role of the AMO was demonstrated in experiments undertaken with selective inhibitors of the enzyme such as allylthiourea. Table 5 presents some examples of organic substances oxidized by N. eurapaea cultures. In the majority of these studies, kinetic data are missing for ammonium and nitrite oxidation... 

In the thiourea and allylthiourea complexes (46) the co-ordination at the copper atoms is square-bipyramidal the Cu-S distances are rather long. It has, therefore, been suggested that the failure of the thiourea ligands to bind strongly to copper(n) in these compounds explains their stability, which, in view of the known ability of thiourea to reduce copper(ii) to copper(i), is suiprising. ... 

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