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Kosugi-Migita-Stille cross-coupling

Similarly, the Migita-Kosugi-Stille cross-coupling reaction (Equation (115)) is important in organic synthesis and has IS 190 302 303, 1... [Pg.840]

Cyclopentadienylstannanes can be used in the Migita-Kosugi-Stille reaction with organic iodides, RI, to give the cross-coupled product Cp-R, for example, Equation (117).310... [Pg.841]

Cross-coupling reactions 5-alkenylboron boron compounds, 9, 208 with alkenylpalladium(II) complexes, 8, 280 5-alkylboron boron, 9, 206 in alkyne C-H activations, 10, 157 5-alkynylboron compounds, 9, 212 5-allylboron compounds, 9, 212 allystannanes, 3, 840 for aryl and alkenyl ethers via copper catalysts, 10, 650 via palladium catalysts, 10, 654 5-arylboron boron compounds, 9, 208 with bis(alkoxide)titanium alkyne complexes, 4, 276 carbonyls and imines, 11, 66 in catalytic C-F activation, 1, 737, 1, 748 for C-C bond formation Cadiot-Chodkiewicz reaction, 11, 19 Hiyama reaction, 11, 23 Kumada-Tamao-Corriu reaction, 11, 20 via Migita-Kosugi-Stille reaction, 11, 12 Negishi coupling, 11, 27 overview, 11, 1-37 via Suzuki-Miyaura reaction, 11, 2 terminal alkyne reactions, 11, 15 for C-H activation, 10, 116-117 for C-N bonds via amination, 10, 706 diborons, 9, 167... [Pg.87]

STILLE CROSS-COUPLING (MIGITA-KOSUGI-STILLE COUPLING)... [Pg.438]

Acid hahdes can also be used in Migita-Kosugi-Stille coupling in this C-C bond formation fhe corresponding ketone is produced. Subjection of a benzoyl chloride derivative prepared in situ to cross-couphng with a vinylstannane provided the desired vinyl ketone which was successfully transformed to a potent COX-2 inhibitor (Scheme 12.99) [201],... [Pg.665]

Scheme 3-215. General catalytic cycle of Kosugi-Migita-Stille cross-coupling. Scheme 3-215. General catalytic cycle of Kosugi-Migita-Stille cross-coupling.
Sechon 12.4 also deals with transmetalation, in which a metal-carbon bond is transferred from tin to palladium 11). The organic residues moved on the palladium are coupled with a variety of electrophiles. This reaction, which was first discovered by Migita-Kosugi [4] and later developed by Stille [5], is now recognized as one of the most useful methods for cross-couphng. [Pg.621]

The palladium-catalyzed cross-coupling of aryl halides with organometalhc reagents is now recognized to be one of the most useful methods for the functionalization of aromatic compounds accompanied by carbon-carbon bond formation [1-3]. The Suzuki-Miyaura and Kosugi-Migita-Stille reactions of... [Pg.55]

See other pages where Kosugi-Migita-Stille cross-coupling is mentioned: [Pg.655]    [Pg.660]    [Pg.655]    [Pg.660]    [Pg.228]    [Pg.217]    [Pg.392]    [Pg.12]    [Pg.121]    [Pg.165]    [Pg.134]    [Pg.217]    [Pg.116]    [Pg.438]    [Pg.658]    [Pg.661]    [Pg.232]    [Pg.208]    [Pg.700]    [Pg.513]    [Pg.310]    [Pg.371]    [Pg.415]    [Pg.117]    [Pg.3]    [Pg.492]    [Pg.421]    [Pg.479]   
See also in sourсe #XX -- [ Pg.660 ]



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Migita

Migita-Kosugi-Stille coupling

Stille coupling

Stille-Kosugi coupling

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